无机盐类对天然矿物低温催化混合酯生烃反应的影响

脂肪酸酯是一类重要的生烃母质。选择了十四烷酸甲酯、十六烷酸甲酯和十八烷酸甲酯的混合酯为模型反应物,以方解石、白云石、伊利石、钙蒙脱石和黄铁矿为催化剂,分别考察了氯化钾、氯化镁、氯化钠、硫酸钠以及混合盐对天然矿物低温催化混合酯生烃反应的影响。结果表明,无机盐类对矿物催化下混合酯的生烃反应均有不同程度的影响,硫酸钠具有反催化作用,其它盐类具有正催化作用。且在各无机盐存在下,不同的矿物表现出不同的催化活性。     

西藏普兰地区拉昂错蛇绿岩中辉绿岩的锆石SHRIMP U—Pb年龄及其地质意义

蛇绿岩中的辉绿岩岩墙是洋脊扩张的产物．其形成年龄代表了扩张事件的时间,也代表了蛇绿岩的形成时代？对雅鲁藏布江缝合带西段拉昂错蛇绿岩中的辉绿岩岩墙进行锆石SHRIMPU—Pb定年,得出加权平均年龄为120．2Ma±2．3Ma,代表辉绿岩的结晶年龄。结合已有的关于雅鲁藏布江蛇绿岩的形成年龄（西段休古嘎布122．3Ma±2．4Ma,中段大竹卡126．0Ma±1．5Ma、吉定123．0Ma＋_1．8Ma,东段罗布莎162．9Ma±2．8Ma）的报道,表明拉昂错地区特提斯洋海底扩张的时代与体古嘎布地区一致．雅鲁藏布江西段与中段地区洋盆的形成时代一致,但晚于东段的发育时代。这意味着整个东提斯洋盆的发育时代存在东早西晚的特点。     

E1 Nio phenomenon in simple ocean data assimilation data

1 IntroductionIt is well known that interaction between the trop-ical ocean and atmosphere produces the largest inter-annual climate signal, El Nino-Southern Oscillation(ENSO). In past decades many efforts have been madein understanding and predicting ENSO: such as the hy-pothesis of Bjerknes (1969) that ENSO arises as aself-sustained cycle in which SSTA in the Pacific O-cean causes the trade winds to strengthen or slackenand that this in turn drives the ocean circulation changesthat …     

Oceanographic influences on seabirds and cetaceans of the eastern tropical Pacific: A review

This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific, the oceanic region centered on the eastern Pacific warm pool, but also including the equatorial cold tongue and equatorial current system, and summarizes what is known about oceanographic influences on seabirds and cetaceans there. The eastern tropical Pacific supports on the order of 50 species of seabirds and 30 species of cetaceans as regular residents; these include four endemic species, the world’s largest populations for several others, three endemic sub-species, and a multi-species community that is relatively unique to this ecosystem. Three of the meso-scale physical features of the region are particularly significant to seabirds and cetaceans: the Costa Rica Dome for blue whales and short-beaked common dolphins, the Equatorial Front for planktivorous seabirds, and the countercurrent thermocline ridge for flocking seabirds that associate with mixed-species schools of spotted and spinner dolphins and yellowfin tuna. A few qualitative studies of meso- to macro-scale distribution patterns have indicated that some seabirds and cetaceans have species-specific preferences for surface currents. More common are associations with distinct water masses; these relationships have been quantified for a number of species using several different analytical methods. The mechanisms underlying tropical species–habitat relationships are not well understood, in contrast to a number of higher-latitude systems. This may be due to the fact that physical variables have been used as proxies for prey abundance and distribution in species–habitat research in the eastern tropical Pacific.Though seasonal and interannual patterns tend to be complex, species–habitat relationships appear to remain relatively stable over time, and distribution patterns co-vary with patterns of preferred habitat for a number of species. The interactions between seasonal and interannual variation in oceanographic conditions with seasonal patterns in the biology of seabirds and cetaceans may account for some of the complexity in species–habitat relationship patterns.Little work has been done to investigate effects of El Niño-Southern Oscillation cycles on cetaceans, and results of the few studies focusing on oceanic seabirds are complex and not easy to interpret. Although much has been made of the detrimental effects of El Niño events on apex predators, more research is needed to understand the magnitude, and even direction, of these effects on seabirds and cetaceans in space and time.     

西太平洋暖池变异及其对西太平洋次表层海温场的影响

应用热带太平洋上层XBT温度资料,分析研究了西太平洋暖池区(0°～16°N,125°～145°E)上层海洋的变化特征以及与西太平洋次表层海温场之间的关系.研究表明,西太平洋暖池区的垂向温度存在显著的年际变化,尤其在次表层(120～200m)的变化最为明显.西太平洋暖池区的次表层冷暖信号明显早于西太平洋次表层的海温异常.分析发现,西太平洋暖池区的海温异常是导致整个西太平洋次表层海温场变异的关键区,当西太平洋暖池区的次表层冷暖信号加强时,3～4个月后西太平洋海温场出现大范围的冷暖异常.     

Bacterial sulphate reduction in sediments of a european salt marsh: Acid-volatile and tin-reducible products

The products of ³⁵S-sulphate reduction by sedimentary bacteria were measured at two sites in a salt marsh on the east coast of England. Non-acid-volatile products were measured, after acid-volatile sulphide was removed, by their reduction to sulphide by digestion with tin. The proportion of the sulphate reduced to tin-reducible products varied between 25% in a salt marsh pan and 61% in creek sediment, over a 0–25 cm depth profile. There were also variations with depth at each site in the proportions of sulphate reduced to tin-reducible products. Further examination revealed differences in the proportions of sulphate which were reduced to free sulphide, acid-volatile sulphide, sulphur or pyrite at the two sites. The data suggest that previous work which did not measure non-acid-volatile products underestimated sulphate reduction rates by three-fold in the creek site, but by only one third in the pan.     

Assessment of spatial variation in carbon utilization by benthic and pelagic invertebrates in a temperate South African estuary using stable isotope signatures

Stable isotope analyses (δ¹³C and δ¹⁵N) were used to evaluate the spatial variations in carbon flow from primary producers to consumers at two sites in the temperate and permanently open Kariega Estuary on the southeastern coast of South Africa during October 2005 and February 2006. One site was located opposite a salt marsh while the second was upstream of the marsh. Except for significantly enriched δ¹³C values of Zostera capensis and surface sediments near the salt marsh, the δ¹³C and δ¹⁵N signatures of the producers were similar between sites. The invertebrates were clustered into groups roughly corresponding to the predominant feeding modes. The suspension feeders showed δ¹³C values closest to the seston, whereas the deposit feeders, detritivores and scavengers/predators had more enriched δ¹³C values reflecting primary carbon sources that were likely a combination of seston, Spartina maritima and Z. capensis at the upstream site, with an increased influence of benthic algae and Z. capensis at the salt marsh site. The δ¹⁵N signatures of the consumers showed a stepwise continuum rather than distinct levels of fractionation, indicating highly complex trophic linkages and significant dietary overlap among the species. Consumers exhibited significantly enriched δ¹³C values at the salt marsh site, an effect that was attributed to enriched Z. capensis detritus in this region in addition to increased phytoplankton biomass in their diets compared with invertebrates living upstream. The data reinforce the concept that between-site variations in the stable isotope ratios of consumers can result not only from dietary shifts, but also from alterations in the isotope ratios of primary producers.     

利用卫星测高技术监测厄尔尼诺和拉尼娜现象

利用美国宇航局和法国空间局联合公布的T／P数据（1993-2000年）和Jason-1数据（2002—2006年），由共线法计算了热带太平洋地区海平面高度的变化。根据T／P和Jason-1数据计算的海面月变化异常图，分别研究了和分析了1997-1998年的厄尔尼诺和拉尼娜现象、2002-2003年厄尔尼诺现象的变化发展过程。     

Artificial Upwelling of Deep Seawater Using the Perpetual Salt Fountain for Cultivation of Ocean Desert

Deep seawater in the ocean contains a great deal of nutrients. Stommel et al. have proposed the notion of a “perpetual salt fountain” (Stommel et al., 1956). They noted the possibility of a permanent upwelling of deep seawater with no additional external energy source. If we can cause deep seawater to upwell extensively, we can achieve an ocean farm. We have succeeded in measuring the upwelling velocity by an experiment in the Mariana Trench area using a special measurement system. A 0.3 m diameter, 280 m long soft pipe made of PVC sheet was used in the experiment. The measured data, a verification experiment, and numerical simulation results, gave an estimate of upwelling velocity of 212 m/day. This revised version was published online in July 2006 with corrections to the Cover Date.     

Analysis, synthesis and modelling of high-resolution observations of salt-marsh eco-geomorphological patterns in the Venice lagoon

The present paper describes observations, analyses and models of salt-marsh channel network and vegetation patterns with the aim of contributing to the development of predictive models of ecological and morphological co-evolution. Existing and new observations are described, with particular emphasis on remote sensing and ancillary field surveys, which are shown to allow reliable, accurate and repeatable quantitative characterizations of landform and vegetation properties over the spatial scales of interest. The observed channel network morphological characters are then used as the basis and validation of models describing the emergence of channel network and vegetation spatial patterns. In particular, with reference to observations performed in the Venice Lagoon, the note describes: (i) new, 2-cm resolution, characterizations of channel network geometry obtained from “proximal sensing” photographic observations; (ii) the reliable quantitative maps of salt-marsh vegetation which may be retrieved from hyperspectral remote sensing data and field ancillary observations; (iii) a synthesis of recent and new analyses of the statistical properties of vegetation and landform spatial organization, that may be inferred from the maps so derived; (iv) recent and new conceptual and quantitative ecological and geomorphic models developed and validated by remote-sensing and field observations. A coherent observational and theoretical eco-morphodynamic framework is then proposed.