Provenance and tectonic significance of late Mesoproterozoic detrital zircons from the Tonian system,northern margin of the North China Craton

The involvement of the North China Craton (NCC) in the assembly or breakup of Rodinia has long been debated. Studies of palaeomagnetism, mafic sills (dikes), igneous events, and sedimentary records have led to contrasting opinions on this topic. No igneous events related to the late Mesoproterozoic assembly of Rodinia have been reported in the NCC. However, the authors found numerous late Mesoproterozoic zircons in the Tonian system on the northern margin of the NCC. The Tonian Zhulazhagamaodao formation is composed of meta-sandstone, siltstone, slate, carbonate, and dolomine of the littoral to neritic facies and occurs mainly in the western part of the Bayan Obo–Zhaertai–Langshan rift. U–Pb dating of detrital zircons from the Tonian system reveals age peaks at 1079 ± 23 Ma, 1092 ± 22 Ma, 1175 ± 50 Ma, 1175 ± 18 Ma, 1260 ± 45 Ma, 1266 ± 16 Ma, and 1270 ± 26 Ma, which correspond to the timing of Rodinia assembly. Considering that coeval igneous rocks and orogenic belts developed mostly in the Laurentia–Baltica cratons, we propose that these cratons supplied clastic material to the northern margin of the NCC and that they had a close spatial relationship between each other during the Tonian.     

Pyrite Re–Os and muscovite 40Ar/39Ar dating of the Beizhan iron deposit in the Chinese Tianshan Orogen and its geological significance

The Awulale iron metallogenic belt (AIMB) hosts the majority of rich iron ores in Tianshan Orogen and has attracted much attention. However, a hot debate exists about the genesis of these iron deposits. Geochronological data are among the few critical evidences to solve the dispute. This study chooses the Beizhan iron deposit to carry out a geochronological research. The Beizhan magnetite deposit, with total iron ore reserves of 468 Mt at an average grade of 41% TFe, is the largest iron deposit in the AIMB. The orebodies of the Beizhan deposit are hosted in Carboniferous dacite and crystal tuff. Four stages of mineral formation can be recognized: an early skarn mineral stage, followed by the magnetite stage, the sulphide stage, and the carbonate stage in order. Pyrite separated from pyrite-rich ore samples yields an isochron age of 302.5 ± 8.2 Ma. Muscovite separated from muscovite-rich ore samples yields ⁴⁰Ar/³⁹Ar plateau ages of 304.7 ± 1.8 Ma, 304.5 ± 1.9 Ma, 308.1 ± 1.9 Ma, and 307.2 ± 1.8 Ma, and isochron ages of 306.1 ± 3.5Ma, 304.0 ± 3.0Ma, 308.2 ± 3.1Ma, and 308.7 ± 3.1Ma, respectively. These ages are consistent within the error range and are interpreted as the age of the Beizhan iron deposit. The results, combined with the other latest precise dating and geologically inferred ages, demonstrate that the iron deposits in the AIMB were formed in the Late Carboniferous. These iron deposits are considered to be iron skarn or medium–low -temperature hydrothermal origin and have genetic linkages between each other. They may be different mineralizing manifestations proximal to or distal from a pluton. The Late Carboniferous iron ores and the related magmatic rocks in the AIMB were produced when upwelling of the asthenosphere causes the partial melting of various sources and the formation of a narrow linear extension in the upper crust. The upwelling of the asthenosphere may be triggered by the detachment of an orogenic root zone.     

Formation process of mid-Neoproterozoic mafic rocks from the western Jiangnan Orogen,South China: insights from SHRIMP U–Pb dating and geochemical analysis

The mid-Neoproterozoic tectonic setting of the Jiangnan Orogen (JO) is uncertain due to the ongoing debate regarding the history of interactions between the Yangtze and Cathaysia Blocks. Extensive magmatic rocks with ages >830 Ma are observed in the eastern JO and are reported to indicate their formation conditions; however, such magmatic rocks are rare in the western JO. This paper presents data from samples collected from two ultramafic intrusions in northern Guangxi province that yield SHRIMP U–Pb ages of 848 ± 7 and 836 ± 5 Ma. These two intrusions have similar geochemical compositions; are enriched in LILE (Rb, Ba, Th, and Pb) relative to HFSE (Hf, Zr, Nb, Ta, and Y), reflecting an arc-like signature; and are derived from the same source. The intrusions have positive εNd(t) and εHf(t) values, implying a depleted mantle source. Comparing the Neoproterozoic mafic–ultramafic rocks of the JO, differences exist between the rocks that formed at 860–830, 830–800, and 800–740 Ma in terms of their mantle sources and formation conditions. Considering the geochemical composition and ages of formation of the strata and the deep structure of the western JO, we speculate that the western JO was a back-arc foreland basin, which experienced shallow subduction-related and arc-like magmatism during the period between 860 and 830 million years. In contrast to the western JO, the eastern JO may have been a back-arc basin with oceanic crustal basement during that time. The JO formed between 830 and 800 million years in association with subduction-related collisional magmatism due to the amalgamation of the Yangtze and Cathaysia Blocks. Subsequently, magmatism occurred in the JO that resulted from the post-orogenic extension.     

Cretaceous A-type volcanic–intrusive rocks and simultaneous mafic rocks along the Gan-Hang Tectonic Belt,Southeast China: petrogenesis and implications for the transition of crust–mantle interaction

ABSTRACT

Abundant evidence points to the Cretaceous crust–mantle interaction and plate subduction in the Gan-Hang Tectonic Belt (GHTB), southeastern China, but the evolutionary process remains poorly constrained. Here we conduct a comprehensive study on Daqiaowu granitic porphyry and diabase dikes in the eastern GHTB, in conjunction with previous studies on simultaneous felsic and mafic rocks along the GHTB, to demonstrate their petrogenesis and geodynamic evolutionary process. The Daqiaowu granitic porphyry (125 Ma), as well as the coeval granitic rocks, exhibits high zircon saturation temperatures, alkalis, 10⁴*Ga/Al ratios, and Zr + Nb + Ce + Y contents, concluding a distinctive belt of the Early Cretaceous (~137–125 Ma) A-type volcanic–intrusive rocks in the GHTB. Their ε_Nd(t) and zircon ε_Hf(t) values gradually increased through time from approximately ?9.0 to ?1.0 and ?10.0 to +4.0, respectively, implying increasing contribution of mantle-derived components to their formation, and hence progressively intensified crust–mantle interaction in an intra-arc rift environment (a geodynamic transition stage from continental arc to back-arc) during the Early Cretaceous. This plausibility is further supported by the Early Cretaceous Daqiaowu diabase dikes and coeval mafic rocks which exhibit arc-like magmatic signatures and were derived from mantle wedge. In contrast, the Late Cretaceous mafic rocks show ocean island basalt-like geochemical characteristics, reflecting a depleted asthenosphere mantle source. This discrepancy of mantle sources concludes that the geodynamic setting in the GHTB may have basically transferred to back-arc regime in the Late Cretaceous. Thus, the Cretaceous geodynamic evolutionary process in the GHTB can be defined as the Early Cretaceous gradually intensified crust–mantle interaction in a geodynamic transition stage (from continental arc to back-arc extension) and the Late Cretaceous back-arc extensional setting.     

Genesis of the Archean–Paleoproterozoic Tabletop Domain,Rudall Province,and its endemic relationship to the West Australian Craton

The Tabletop Domain of the Rudall Province has been long thought an exotic entity to the West Australian Craton. Recent re-evaluation of this interpretation suggests otherwise, but is founded on limited data. This study presents the first comprehensive, integrated U–Pb geochronology and Hf-isotope analysis of igneous and metasedimentary rocks from the Tabletop Domain of the eastern Rudall Province. Field observations, geochronology and isotope results confirm an endemic relationship between the Tabletop Domain and the West Australian Craton (WAC), and show that the Tabletop Domain underwent a similar Archean–Paleoproterozoic history to the western Rudall Province. The central Tabletop Domain comprises Archean–Paleoproterozoic gneissic rocks with three main age components. Paleo–Neoarchean (ca 3400–2800 Ma) detritus is observed in metasedimentary rocks and was likely sourced from the East Pilbara Craton. Protoliths to mafic gneiss and metasedimentary rocks are interpreted to have been emplaced and deposited during the early Paleoproterozoic (ca 2400–2300 Ma), and exhibit age and isotopic affinities to the Capricorn Orogen basement (Glenburgh Terrane). Mid–late Paleoproterozoic mafic and felsic magmatism (ca 1880–1750 Ma) is assigned to the Kalkan Supersuite, which is exposed in the western Rudall Province. The Kalkan Supersuite provided the main source of detritus for mid–late Paleoproterozoic metasedimentary rocks in the Tabletop Domain. Similarities in the age and Hf-isotope compositions of detrital zircon from these metasedimentary rocks and Capricorn Orogeny basin sediments suggests that a regionally extensive, linked basin system may have spanned the northern WAC at this time. The Tabletop Domain records evidence for two metamorphic events. Mid–late Paleoproterozoic deformation (ca 1770–1750 Ma) was high-grade, regional and involved the development of gneissic fabrics. In contrast, early Mesoproterozoic (ca 1580 Ma) high-grade deformation was localised and associated with more widespread, late-stage, greenschist facies alteration. These new findings highlight that the Tabletop Domain experienced a much higher grade of deformation than previously assumed, with a Paleoproterozoic metamorphic history similar to that of the western Rudall Province.     

Diversities in biomarker compositions of Carboniferous–Permian humic coals in the Ordos Basin,China

The molecular composition of Carboniferous–Permian coals in the maturity range from 0.66 to 1.63% vitrinite reflectance has been analysed using organic geochemistry to investigate the factors influencing the biomarker compositions of humic coals. The Carboniferous–Permian coal has a variable organofacies and is mainly humic-prone. There is a significant difference in the distribution of saturated and aromatic hydrocarbons in these coals, which can be divided into three types. The Group A coals have biomarker compositions typical of humic coal, characterised by high Pr/Ph ratios, a lower abundance of tricyclic terpanes with a decreasing distribution from C₁₉ tricyclic terpane to C₂₄ tricyclic terpane and a high number of terrigenous-related biomarkers, such as C₂₄ tetracyclic terpane and C₂₉ steranes. The biomarker composition of Group B coals, which were deposited in a suboxic environment, have a higher abundance of rearranged hopanes than observed in Group A coals. In contrast, in Group C coals, the Pr/Ph ratio is less than 1.0, and the sterane and terpane distributions are very different from those in groups A and B. Group C coals generally have abnormally abundant tricyclic terpanes with a normal distribution maximising at the C₂₃ peak; C₂₇ steranes predominates in the m/z 217 mass fragmentograms. The relationships between biomarker compositions, thermal maturity, Pr/Ph ratios and depositional environments, indicate that the biomarker compositions of Carboniferous–Permian coals in Ordos Basin are mainly related to their depositional environment. This leads to the conclusion that the biomarker compositions of groups A and B coals collected from Shanxi and Taiyuan formations in the northern Ordos Basin are mainly related to their marine–terrigenous transitional environment, whereas the biomarker compositions for the Group C coals from Carboniferous strata and Shanxi Formation in the eastern Ordos Basin are associated with marine incursions.     

U–Pb–Hf isotopes and trace elements of metasomatic zircon delimit the evolution of neoproterozoic Capané ophiolite in the southern Brasiliano Orogen

The Capané ophiolite is a fragment of oceanic lithosphere obducted into the Ediacaran Porongos fold and thrust belt, southern Brasiliano Orogen. A studied rodingite blackwall contained in serpentinite has metasomatic zircon that displays multiple U–Pb ages from Tonian to Cryogenian (793 ± 0.9, 757 ± 2.1, 715 ± 2.2 Ma). The ages are interpreted as corresponding to multiple alteration events in the mantle. Multiple U–Pb–Hf isotopes and trace element analyses on the same crystals by laser ablation were controlled by backscatered electron images. Hf isotopes indicate zircon origin from a depleted mantle (εHf = +15 to +10.7), and trace elements point to an oceanic origin. The Capané ophiolite thus marks the evolution of the Adamastor ocean during the Tonian and Cryogenian, a significant result for the reconstruction of Rodinia and Gondwana supercontinents.     

An example of post-collisional appinitic magmatism with an arc-like signature: the Wadi Nasb mafic intrusion,north Arabian–Nubian Shield,south Sinai,Egypt

We present new data for the Neoproterozoic mafic intrusion exposed in Wadi Nasb, south Sinai, Egypt (northernmost Arabian–Nubian Shield; ANS). The Nasb mafic intrusion (NMI) intrudes metasediments, Rutig volcanics, and diorite/granodiorite, and is intruded in turn by younger monzogranite and quartz-monzonite. Available geochronological data for the country rocks of the NMI provide a tight constraint on its age, between 619 and 610 Ma, during the hiatus between the lower and upper Rutig volcanics. The NMI is neither deformed nor metamorphosed, indicating post-collisional emplacement, and uralitization by late-magmatic and sub-solidus alteration is restricted to the margins of the intrusion. A quantitative fractionation model indicates a fractionating assemblage of 61% primary amphibole, 10% clinopyroxene, 28% plagioclase, 1% biotite, 0.4% apatite, and 0.15% Fe-Ti oxide. Contrary to the recent studies, we find that the nearby diorite of Gebel Sheikh El-Arab is not co-genetic with the appinitic gabbro of the NMI. Although there are volcanic xenoliths in the NMI, we find no chemical evidence requiring contamination by continental crust. A subduction-related signature in a post-orogenic intrusion requires the inheritance of geochemical tendencies from a previous subduction phase. Given that the fine-grained gabbro of the NMI is consistent with a near-primary mantle melt, we attribute this inheritance to persistence and later melting of the slab-modified mantle domains, as opposed to partial melting and assimilation of the juvenile continental crust. The fine-grained gabbro composition indicates derivation at temperature and pressure conditions similar to the sources of mid-ocean ridge basalts: mantle potential temperature near 1350°C and extent of melting about 7%. Such temperatures, neither so high as to require a plume nor so low as to be consistent with small degrees of melting of a volatile-rich source, are most consistent with a lithospheric delamination scenario, allowing the upwelling of fertile, subduction-modified asthenosphere to depths ≤50 km.     

Petrogenesis and tectonic implications of early Devonian mafic dike–granite association in the northern West Junggar,NW China

Mafic dike–granite associations are common in extensional tectonic settings and important and pivotal in reconstructing crust–mantle geodynamic processes. We report results of zircon U–Pb and hornblende ⁴⁰Ar-³⁹Ar ages and major-element and trace-element data for mafic dike–granite association from the northern West Junggar, in order to constrain their ages, petrogenesis, and geodynamic process. The mafic dike–granite association was emplaced in the early Devonian. The Xiemisitai monzogranites have high SiO₂ contents and low MgO, Cr, and Ni concentrations, suggesting that they were mainly derived from crustal sources and were probably generated by partial melt of the juvenile mid-lower crust. The mafic dikes have low Mg^# and Cr and Ni abundances, suggesting that they have experienced significant fractional crystallization. The Xiemisitai mafic dikes contain hornblende and biotite and display negative Nb–Ta–Ti anomalies, enrichment of LREEs and LILEs, and depletion of HREEs and HFSEs, consistent with an origin from a lithospheric mantle metasomatized by subducted slab-derived fluids. In addition, the Xiemisitai mafic dikes are plotted within melting trends with little to no garnet (Cpx: Grt = 6:1) in their source. The La/Yb versus Tb/Yb plot also indicates the presence of less than 1% residual garnet in the source region for the Xiemisitai mafic dikes. Therefore, it can be inferred that the Xiemisitai mafic dikes were generated at a correspondingly shallow depth, mostly within the spinel stability field. The Xiemisitai mafic dikes were most probably generated by the partial melting of the metasomatized lithospheric mantle at relatively shallow depths (<80 km). The Xiemisitai mafic dike–granite association could have been triggered by asthenospheric upwelling as a result of the rollback of the subducted Irtysh–Zaysan oceanic lithosphere.     

Early Carboniferous anorogenic magmatism in the Levant: implications for rifting in northern Gondwana

The Variscan orogenesis in Europe peaked during the Late Devonian–Early Carboniferous times when Gondwanan terranes collided with Laurasia. Hitherto it has been thought that Carboniferous tectonics in northern Arabia and the adjacent parts of NE Africa were broad swells (‘arches’) and depressions (‘basins’) that formed as a far-field contractional effect of the Variscan compression. The discovery of a 351 ± 3 Ma (U–Pb in zircon) within-plate felsic volcanism in the Helez borehole, southern coastal Israel, suggests that the Levant Arch is, instead, extensional in origin. Felsic volcanism was associated with gabbro underplating of the crust, an extreme (~50°C/km) crustal thermal gradient, major uplift, and truncation of the ≥2.5 km section. Taken together with the recent discovery of the ~340 Ma oceanic crust in the Eastern Mediterranean, the Levant Arch is interpreted as an uplifted shoulder of a rift, preceding ocean spreading.