Potential toxicity of resuspended particulate matter and sediments: Environmental samples from the Bay of Banyuls-sur-Mer and Thermaikos Gulf

This contribution attempts to determine whether, and to what degree, environmental samples of resuspended particulate matter and sediments exert a toxicological impact. Further, an attempt is made also to screen the toxic level of potentially hazardous sites, based upon established sediment toxicity criteria. Therefore, a rapid, cost-effective and highly sensitive biotest (bioluminescence assay, based upon marine bacteria) has been applied on: biological fluid extracts; bottom sediments; and sediment trap samples. Samples were taken either from the Bay of Banyuls-sur-Mer (northwestern Mediterranean, France) or Thermaikos Gulf (northeastern Mediterranean, Greece). Biological fluid extracts and sediment trap samples corresponded to periods of resuspension events, or preceding and following such events.The results have revealed that the sampling strategy and biotest implemented in this study might be a useful tool for screening the toxicity of resuspended matter and sediments. Resuspension events appear to be able to exert an influence on the chemical forms of the micro-pollutants; thus on their bioavailability and toxicity. Nevertheless, based upon chemical analysis combined with the bioassay, the toxic level of the sediment samples could be determined, with the level at potentially hazardous sites being characterised.     

A detailed receiver function image of the sedimentary structure in the Bohai Bay Basin

If the site at which receiver functions are constructed is filled by sediments, then the waveforms from these receiver functions are dominantly controlled by the sedimentary structures within the first few seconds after the direct P arrival. Based on this observation, waveform data collected at 44 temporary seismic stations have been used to image the sedimentary structure of the Bohai Bay Basin, a major continental petroliferous basin in Eastern China. An adapted hybrid global waveform inversion method was applied to the receiver functions to extract structural information beneath each of the stations. The derived S-velocity structure provides for the first time, a basin-scale seismic image of detailed sedimentary stratification. The sedimentary cover of the basin is about 2-12 km thick, consisting of Cenozoic, Mesozoic, and Paleozoic strata from top to bottom. The structural features presented in the S-velocity image coincide quite well with the depression-uplift type of tectonic system in the Bohai Bay Basin. The reconstructed morphology of the sedimentary layers provides seismological evidence for the two-stage evolution of the intracontinental basin that were caused by an intensive tectonic regime transition in late Mesozoic immediately following the lithospheric reforming of the Eastern China continent.     

Effect of the Mahanadi River on the Development of Storm Surge Along the Orissa Coast of India: A Numerical Study

River-ocean coupled models are described for the evaluation of the interaction between river discharge and surge development along the Orissa coast of India. The models are used to study the effect of fresh water discharge from the Mahanadi River on the surge response along the Orissa coast due to the October 1999 super cyclone which led to severe flooding of the coastal and delta regions of Orissa. The so-called 1999 Paradip cyclone was one of the most severe cyclones; causing extensive damage to property and loss of lives. The present study emphasizes the impact of the Mahanadi River on overall surge development along the Orissa coast. Therefore, we have developed a location specific fine resolution model for the Orissa coast and coupled it with a one–dimensional river model. The numerical experiments are carried out, both with and without inclusion of fresh water discharge from the river. The bathymetry for the model has been taken from the naval hydrographic charts extending from the south of Orissa to the south of west Bengal. A simple drying scheme has also been included in the model in order to avoid the exposure of land near the coast due to strong negative sea-surface elevations. The simulations with river-ocean coupled models show that the discharge of fresh water carried by the river may modify the surge height in the Bay, especially in the western Bay of Bengal where one of the largest river systems of the east coast of India, the Mahanadi River, joins with the Bay of Bengal. Another dynamic effect of this inlet is the potentially deep inland penetration of the surge originating in the Bay. The model results are in good agreement with the available observations/estimates.     

Paleogene of the Huanghekou Sag in the Bohai Bay Basin,NE China: deposition–erosion response to a slope break system of rift lacustrine basins

The sequence architecture and depositional systems of the Paleogene lacustrine rift succession in the Huanghekou Sag, Bohai Bay Basin, NE China were investigated based on seismic profiles, combined with well log and core data. Four second‐order or composite sequences and seven third‐order sequences were identified. The depositional systems identified in the basin include: fan delta, braid delta, meander fluvial delta, lacustrine and sublacustrine fan. Identification of the slope break was conducted combining the interpretation of faults of each sequence and the identification of syndepositional faults, based on the subdivision of sequence stratigraphy and analysis of depositional systems. Multiple geomorphologic units were recognized in the Paleogene of the Huanghekou Sag including faults, flexures, depositional slope break belts, ditch‐valleys and sub‐uplifts in the central sag. Using genetic division principles and taking into consideration tectonic features of the Paleogene of the Huanghekou Sag, the study area was divided into the Northern Steep Slope/Fault Slope Break System, the Southern Gentle Slope Break System and T10 Tectonic Slope Break System/T10 Tectonic Belt. Responses of slope break systems to deposition–erosion are shown as: (1) basin marginal slope break is the boundary of the eroded area and provenance area; (2) ditch‐valley formed by different kinds of slope break belts is a good transport bypass for source materials; (3) shape of the slope break belt of the slope break system controls sediments types; (4) the ditch‐valley and sub‐sag of a slope break system is an unloading area for sediments; and (5) due to their different origins, association characteristics and developing patterns, the Paleogene slope break belt systems in the Huanghekou Sag show different controls on depositional systems. The Northern Fault Slope Break system controls the deposition of a fan delta‐lacustrine‐subaqueous fan, the Southern Gentle Slope Break system controls the deposition of a fluvial–deltaic–shallow lacustrine and sublacustrine fan, and the T10 Tectonic Slope Break System controls the deposition of shallow lacustrine beach bar sandbodies. The existence of a slope break system is a necessary but not a sufficient condition for studying sandbody development. The formation of effective sandbodies along the slope break depends on the reasonable coupling of effective provenance, necessary association patterns of slope break belt, adequate unloading space and creation of definite accommodation space. Copyright © 2013 John Wiley & Sons, Ltd.     

广西油麻坡钨钼矿床成岩成矿年代学研究及其地质意义

广西博白_岑溪断裂带位于钦杭成矿带南段,既是一条长期活动的地体边界断裂带,也是一条岩浆活动频繁的W_Mo_Sn_Pb_Zn_Sb_Au_Ag多金属成矿带。文章以该带中的广西博白县油麻坡矽卡岩型钨钼矿床为研究对象,在详细的岩性鉴别和划分的基础上,对矿区内花岗岩类进行了单颗粒锆石LA_ICP_MS锆石U_Pb测年,获得深灰色花岗斑岩的等时线年龄为(479.7±3.9)Ma,灰色黑云母花岗闪长岩为(109.7±1.1)Ma,浅灰色细粒白云母花岗岩为(103.3±1.2)Ma。辉钼矿Re_Os测年获得加权平均年龄为(97.4±1.9)Ma。由此可见,油麻坡岩体为一个复式岩体,由早奥陶世(加里东期)的花岗斑岩和早白垩世(燕山晚期)的黑云母花岗闪长岩和细粒白云母花岗岩组成,其中,黑云母花岗闪长岩构成油麻坡岩体的主体。钨钼矿形成于早白垩世晚期(即燕山晚期),与黑云母花岗闪长岩和白云母花岗岩密切相关。这些高精度测年数据的获得,进一步表明博白断裂带是一条长期活动的断裂,其在加里东期已经活动,并伴有岩浆岩的侵位。燕山晚期,该断裂重新复活,并导致大量的岩浆活动和一定强度的W_Mo_Sn_Pb_Zn_Sb_Au_Ag成矿作用,形成由多个大_中型矿床组成的多金属成矿带。博白_岑溪成矿带属于华南100~80 Ma大规模成矿的一部分,成矿背景与华南地区白垩纪的地壳伸展、钦杭成矿带的再次裂陷有关。     

辽东湾坳陷东部地区走滑双重构造的发育特征 及其石油地质意义

在将构造发育特征与走滑双重构造理论模型进行类比分析的基础上,对辽东湾坳陷东部地区的走滑双重构造的发育特征进行了研究,并结合油气勘探实践成果,就其石油地质意义进行了探讨,研究结果表明:在受控于走滑与拉伸并存的多动力源区域地质背景下,辽东湾坳陷新生代构造演化体现了断陷与拗陷、拉张与走滑的叠加效应,NNE走向的辽中1号断裂、辽中2号断裂及辽东断裂的发育不仅控制了辽东湾坳陷东部地区的凸凹格局,其走滑侧接关系也导致了研究区走滑双重构造的发育;辽东凸起是由于辽中2号断裂、辽东断裂走滑弯曲、右行左阶侧接而形成的挤压走滑双重构造,而辽中凹陷在早期拉张断陷基础上,经历了后期走滑作用的改造,其断裂体系的发育体现了辽中1号断裂与辽中2号断裂的右旋右行侧列所产生的拉张走滑双重构造效应;在走滑双重构造的增压带,断裂侧向封堵性强,有利于形成有效的断层圈闭,是油气藏发育的有利区带。     

莱州湾沿岸寿光、莱州和龙口地下水的稳定同位素与地球化学

依据地下水咸化机理:蒸发、溶解和混合,海水入侵是地下淡水与较之更咸的海水的混合,海水和淡水的混合包括水分子的混合和溶解盐分的混合。只有溶剂水分子和溶质溶解盐分都发生了相同比例的混合,才能确定二种水体发生了混合。地下淡水变咸并不能都归因于海水入侵,也有可能源于蒸发或溶解。鉴定是否存在海水入侵可运用惰性示踪剂和反应示踪剂来共同识别。惰性示踪剂包括δD、δ~(18)O、Cl~-和Br~-,反应示踪剂包括主要化学成分和微量元素。本研究对莱州湾沿岸寿光、莱州和龙口的地下水进行了化学成分形成过程的对比研究。莱州采集样品6件,龙口10件,寿光9件。莱州和龙口的碎屑沉积物以硅酸盐矿物为主,而寿光的沉积物来源于南部鲁中南山地的碳酸盐岩。根据莱州采样点地理条件和样品的稳定同位素δD-δ~(18)O分布域确定了当地降雨入渗的多年平均值,进而明确龙口样品也源于就地降雨入渗补给,根据高程效应和当地水文情况确定寿光样品补给来自南部山区的降水,经河道排入洼地后入渗地下。Cl~--δ~(18)O关系表明盐分都来源于淡水溶解的蒸发盐,而非与海水混合。Br~-/Cl~-比值证实了蒸发盐溶解,还存在人为污染物和海侵沉积物中有机质分解的影响。从三线图可看出龙口样品经历了离子交换反应。主要成分和微量元素(HCO_3~-,H_2SiO_3,F~-,Li~+,Sr~(2+)和Ba~(2+))的含量与样品所处含水层的矿物组成有关,反映出水岩作用。所有样品都没有淡水和海水混合的现象。惰性示踪剂分析提供了区域地下水补给的框架,明确了大气水源因溶解蒸发盐而咸化,排除了淡水和海水混合的可能性。用反应示踪剂中主要化学成分和微量元素来分析水中化学成分的形成过程,在和海洋盐分输入对比基础上,二者偏差值主要源自水-岩相互作用结果,包括溶解、沉淀、离子交换等,以及局部样品的污染物输入。所以沿海地带研究地下水咸化,先要解决溶剂的混合问题,在此基础上辅以水文地球化学分析,利用水化学的多种示踪剂,主要解决溶质混合以及盐分来源问题。