海洋纤维增强热塑性立管极限承载拉力预测方法

海洋新型纤维增强热塑性立管因其可盘卷、耐腐蚀、耐疲劳和轻质化等优点,在深水油气开发中应用前景十分广阔。热塑性立管具有复合材料的各向异性、受力耦合效应及复杂的本构关系,且承受浮体运动和复杂海洋环境载荷,其失效模式尚未明确。针对轴对称载荷作用下纤维增强热塑性立管极限承载力问题,进行热塑性管稳态热传导和热应力的理论推导,求解了稳态温度和应力分布,首次给出了在任意温度载荷作用下管体径向位移的解析解,并直接求解其径向、轴向、环向和剪切应力。采用各向同性层Von Mises和各向异性层最大应力（Max Stress）准则或Tsai-Hill准则判定热塑性管的失效,基于应力分布、失效准则和二分法计算了热塑性管的极限载荷。温度载荷、纤维铺设角度和径厚比对管道的应力分布影响显著。不同温度载荷会改变失效指数沿径向的变化趋势,增大轴向拉力将增大热塑性管的失效指数,选用不同的失效准则在管体失效判定上存在一定的差异。热塑性管温度越低、纤维铺设角越小及径厚比越大,管道对轴向拉伸载荷的承载能力越强。     

Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.     

涡旋诱发重联模型（Ⅰ）——动力学特性

本文首先从理论上系统地研究了涡旋诱发重联的基本动力学特性.包括:涡旋诱发重联的物理机制;Kelvin-Helmholtz（K-H）不稳定性和撕裂模不稳定性耦合过程;磁流体涡管的基本特性;不同尺度涡旋间的相互作用,动能和磁能间的转化及准稳态时流线、磁力线、等涡度线和等电流密度线的相似性等.用二维MHD数值模拟方法研究了上述一些特性,并与理论分析结论进行了比较.结果表明,模拟结果证实了理论推论.涡旋诱发重联是产生局部磁场重联的重要机制之一,该模型在磁顶区的应用将另文发表.