江西广丰地区中奥陶统层序地层分析

本文通过对广丰县周家坞中奥陶统露头剖面层序、体系域、副层序的研究，识别出了三个不同性质的Ⅱ型层序界面和二个三级层序，确认这三个层序界面为符合实际又易于野外识别的自然界面，并对ＳＱ２中反映最大海泛期的高分辨异旋回驱动机制事件，提出可能受米兰柯维奇频率的春分点和秋分点间约２万年间隔的控制。     

陕西渭北东部寒武纪-奥陶纪岩相古地理与岩溶水赋存关系

在系统研究大量野外实测剖面和钻孔资料的基础上，认为本区寒武纪-奥陶纪岩相古地理演化可分为3个海侵海退旋回，构成了一套独特的、完整的沉积序列。沉积层的岩溶发育程度与沉积环境密切相关，从开阔海、潮下、高能、滩环境沉积层，到开阔海、低能、间歇高能环境沉积层，再到滨海、潮上、泥云坪和泥灰坪环境沉积层，岩溶发育程度逐渐降低，富水程度逐渐减弱。     

Tidal effect on dynamics of pore water nitrate in intertidal sediment of a eutrophic Estuary

To evaluate the effect of the tidal cycle on the pore water nitrate dynamics in intertidal sediment, concentrations of inorganic nitrogen in water and sediment were monitored during tidal cycles in the mud flat of Tama Estuary, Japan. During submergence, nitrate concentration was highest in the overlying water and decreased monotonically with increasing depth in the sediment, suggesting that the primary source of nitrate in the sediment was nitrate transported from the overlying water. Pore water nitrate decreased remarkably during the initial 3–4 hours after the onset of exposure. Thereafter, it was constant or slightly increased until tidal flooding.In situ accumulation of nitrate at the end of exposure, however, did not exceed the nitrate concentrations in the overlying water. The inhibition of nitrate reduction and the stimulation of nitrification would explain the change of nitrate concentration, both consistent with the input of oxygen into the sediment following a 10 mm drop of the water table. In Tama Estuary sediments, the effect of the tidal cycle on the removal of combined nitrogen is rather negative, because high nitrate concentrations in the overlying water canceled the positive effect of nitrate accumulation by nitrification during exposure, while tidal oxygen intrusion have an inhibitory effection sedimentary denitrification.     

干湿循环下原状黄土抗压强度试验研究

黄土是干旱、半干旱条件下形成的,具有特殊结构的土,季节性的降雨和蒸发作用必将引起其力学性质和结构改变,从而造成其强度降低和变形增大的问题。通过单轴抗压强度试验探讨了黄土抗压强度与含水率、干湿循环次数的变化规律,借助SEM图像定性和定量分析了其强度变化的微观机制。试验结果表明：黄土单轴抗压强度随含水率的减小表现为非线性的增大;随干湿循环次数的增加而减小,经历多次干湿循环后趋于稳定;含水率增大和干湿循环次数的增加不仅仅会使得粗颗粒的接触方式改变与胶体物质和腐殖质数量减少,还会使得土体孔隙直径增大,大、中孔隙所占百分比之和明显增多,进而从微观结构阐述了土体宏观强度的变化规律。     

海洋贝类利用模式生命周期评价方法研究

首次将产品生命周期评价方法(LCA)应用于海洋贝类利用模式上。根据海洋贝类利用技术产业发展的特性和趋势,设计构建了由确定目标和范围、清单分析、影响评价3个步骤组成的评价体系,挑选了具有典型代表的2种扇贝利用模式进行评价,对其生产过程中的资源消耗、固体废弃物、富营养化、温室效应、酸化影响和潜在影响进行对比评价。评价结果显示其中资源消耗、温室效应、酸化影响、潜在健康影响的影响潜值模式2(产品模式为扇贝柱、复合氨基酸、鱼虾饵料和贝壳工艺品)比模式1(产品模式为扇贝柱、食用贝边、鱼虾鲜饵料和饲料添加剂)低;而固体废弃物、富营养化的影响潜值,模式2比模式1高。本评价方法可用于选择和优化海洋贝类的绿色化高值利用模式。研究表明,利用文章提出的海洋贝类利用评价方法可以有效掌握贝类利用的整个过程的环境行为,确定其中优化资源、节省能源和减少污染的关键步骤,为优化利用模式提供基础数据支持。     

Grazing suppression of dimethylsulphoniopropionate (DMSP) accumulation in iron-fertilised, sub-Antarctic waters

The impact of in situ iron fertilisation on the production of particulate dimethylsulphoniopropionate (DMSPp) and its breakdown product dimethyl sulphide (DMS) was monitored during the SOLAS air-sea gas exchange experiment (SAGE). The experiment was conducted in the high nitrate, low chlorophyll (HNLC) waters of the sub-Antarctic Southern Ocean (46.7°S 172.5°E) to the south-east of New Zealand, during March-April, 2004. In addition to monitoring net changes in the standing stocks of DMSPp and DMS, a series of dilution experiments were used to determine the DMSPp production and consumption rates in relation to increased iron availability. In contrast to previous experiments in the Southern Ocean, DMS concentrations decreased over the course of the 15-d iron-fertilisation experiment, from an integrated volume-specific concentration in the mixed layer on day 0 of 0.78 nM (measured values 0.65-0.91 nM) to 0.46 nM (measured values 0.42-0.47 nM) by day 15, in parallel with the surrounding waters. DMSPp, chlorophyll a and the abundance of photosynthetic picoeukaryotes exhibited indiscernible or only moderate increases in response to the raised iron availability, despite an obvious physiological response by the phytoplankton. High specific growth rates of DMSPp, equivalent to 0.8-1.2 doublings d⁻¹, occurred at the simulated 60% light level of the dilution experiments. Despite the high production rates, DMSPp accumulation was suppressed in part by microzooplankton grazers who consumed between 61% d⁻¹ and 126% d⁻¹ of the DMSPp production. Temporal trends in the rates of production and consumption illustrated a close coupling between the DMSP-producing phytoplankton and their microzooplankton grazers. Similar grazing and production rates were observed for the eukaryotic picophytoplankton that dominated the phytoplankton biomass, partial evidence that picoeukaryotes contributed a substantial proportion of the DMSP synthesis. These rates for DMSPp and picoeukaryotes were considerably higher than for chlorophyll a, indicating higher cycling rates of the DMSP-producing taxa than for the bulk phytoplankton community. When compared to the total phytoplankton community, there was no evidence of selection against the DMSP-containing phytoplankton by the microzooplankton grazers; the opposite appeared to be the case. SAGE demonstrated that increased iron availability in the HNLC waters of the Southern Ocean does not invariably lead to enhanced DMS sea-air flux. The potential suppression of DMSPp accumulation by grazers needs to be taken into account in future attempts to elevate DMS emission through in situ iron fertilisation and in understanding the hypothesised link between levels of Aeolian iron deposition in the Southern Ocean, DMS emission and global albedo.     

A preliminary study of carbon system in the East China Sea

In the central part of the East China Sea, the activity of CO₂ in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993. The activity of CO₂ in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption of about 40 gC/m²/yr of atmospheric CO₂ in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is about 70 gC/m²/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate of 30 gC/m²/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial organic carbon decomposed on the continental shelf.     

大西洋经向翻转环流对岁差响应的气候背景依赖性

大西洋经向翻转环流（Atlantic Meridional Overturning Circulation,AMOC）是气候系统重要的组成部分,其强度变化可直接影响南北半球的热量分配,厘清其变化机理对全球变暖背景下的未来预估至关重要。海洋沉积物记录发现,在晚更新世,AMOC的变化与地球岁差周期有紧密联系,但其物理机理尚不清楚。本文利用海洋−大气耦合气候模型—COSMOS（ECHAM5/JSBACH/MPIOM）模型,通过敏感试验,分析在冰盛期冷期和间冰期暖期气候背景下,AMOC对地球岁差变化的响应机理。结果表明：岁差降低引起的北半球夏季太阳辐射增强,会导致间冰期暖期背景下的AMOC显著减弱,但对冰盛期AMOC的影响并不明显。通过进一步分析发现,在间冰期暖期,夏季太阳辐射增强,造成高低纬大西洋海表的升温,同时促进北大西洋高纬度地区的局地降水,两者导致北大西洋表层海水密度降低,共同削弱大西洋深层水生成。而在冰盛期冷期,大西洋高低纬度地区的响应对AMOC的影响反向—副热带升温触发的海盆尺度低压异常,通过其南侧的西风异常削弱大西洋向太平洋的水汽输送,导致净降水增多,海表盐度下降;同时,高纬度升温造成的海冰减少,促进了海洋热丧失,海表失热变重,有利于大西洋深层水的生成,最终两者的共同作用导致AMOC对岁差变化的响应偏弱。本文系统揭示了不同气候背景下,岁差尺度AMOC变化的控制机理,对理解晚更新世AMOC重建记录中持续存在的岁差周期具有重要启示意义。     

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).     

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.