基岩水的壁间运动及基本特征

本文通过对基岩水与孔隙水的比较分析，介绍了基岩水的分布、水动力学和水化学特征，指出了基岩水运动具有均位趋势、选择流动及汇流特性，得出了渗流理论不宜用于基岩水的结论。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

Flexible membranes anchored to the ground for slope stabilisation: Numerical modelling of soil slopes using SPH

An alternative modelling for flexible membranes anchored to the ground for soil slope stabilisation is presented using Smoothed-Particle Hydrodynamics to model the unstable ground mass in a soil slope, employing a dynamic solve engine. A regression model of pressure normal to the ground, q_sim, and also membrane deflection, f_sim, have been developed using Design of Experiment. Finally, a comparison between the pressure obtained from numerical simulation and from a limit equilibrium analysis considering infinite slope has been carried out, showing differences in the results, mainly due to the membrane stiffness.     

结合空间信息选取最优端元组合的混合像元分解

传统的混合像元分解算法认为每个像元都包含图像中所能提取的全部端元组分,但这并不符合实际情况。实际上图像中大多数混合像元仅由少部分端元混合而成。由于端元提取精度及噪声的影响,采用全部端元对混合像元进行分解,会使得混合像元中实际并不存在的端元的丰度估计值不为零,分解结果存在较大误差。由于混合像元大多存在于不同地物的交界处,基于此,本文提出了一种结合图像的空间信息选取混合像元最优端元子集的方法。利用一个空间结构元素,从混合像元的附近邻域开始搜索,将搜索到的纯净像元光谱与所提取的图像端元光谱进行对比,并确定混合像元的端元子集进行分解。根据RMSE大小和变化情况,逐步扩大结构元素的大小,不断调整搜索范围,直至得到最优端元组合。模拟数据和真实数据的试验结果表明,该方法相比传统的全端元光谱分解方法,在总体上获得了更好的分解效果。     

Bragg reflection of water waves by multiple floating horizontal flexible membranes with submerged rectangular bars on the seabed

Bragg reflection of water waves by multiple floating horizontal flexible membranes is investigated based on the linear wave theory and the assumption of small membrane response. Under the floating horizontal membranes, periodical submerged rectangular bars are arranged on the flat seabed. The total reflection and transmission coefficients are obtained by using the eigenfunction expansion method and the wide spacing approximation. The calculated coefficients are validated with the results available in the literature, which shows that the present method is applicable. The characteristics of Bragg reflection are systematically investigated by changing various parameters including the height of the rectangular bars, the number, the tension, the spacing, and the length of the flexible membranes. The results can help designing multiple floating horizontal flexible membranes as effective floating breakwaters by taking advantage of Bragg reflection.     

裙带菜配子体基因工程选择标记的研究

研究了裙带菜(Undaria pinnatifida)配子体对除草剂草丁膦的敏感性以及温度对草丁膦处理效果的影响。结果表明,裙带菜配子体对草丁膦敏感;统计学分析得出了草丁膦在不同温度条件下处理裙带菜配子体的半致死浓度(LD50)及95%可信限;温差达到10℃时,相同处理时间各组内不同处理温度样品的LD50之间呈现显著差异,第6天的LD50由10℃组的15.78 mg/L降为20℃组的11.56 mg/L和25℃组的10.33 mg/L。研究发现可以尝试采用草丁膦作为裙带菜配子体遗传转化的选择试剂。     

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

离子色谱法测定矿物包裹体中阴离子

本文介绍了用离子色谱法同时测定矿物包裹体中F~-、Cl~-、PO_4~(3-)、Br~-、NO_3~-、SO_4~(2-)6种阴离子的新方法。研究了流动相浓度对保留时间的影响以及消除负峰干扰的方法。     

离子色谱法测定岩石,土壤,水系沉积物等样品中的氯,溴,碘

本文采用碳酸钠一氧化锌烧结法分解样品,利用DIONEX2020i离子色谱仪,电导、电化学检测器,建立了一测定岩石等样品中氯、溴、碘的分析流程。实验表明,本方法选择性好,灵敏度高,检出限分别为:氯1.03×10~(-6)、溴0.012×10~(-6)、碘0.014×10~(-6)。     

碳棒涂膜式PVC膜铯离子选择电极的研制和应用

本文作者研制成功以四苯硼铯为活性物质的碳棒涂膜式PVC膜铯离子选择性电极。电极最佳膜组成:四苯硼铯5mg,邻苯二甲酸二丁酯0.4ml,硝基苯0.2ml,PVC粉0.2g。电极性能优良,制作简单,操作方便。结合大粒度磷钼酸铵和结晶形锑酸分离K~+,Na~+,巳将此电极用于卤水样中铯的测定,结果令人满意。