Reservoir-induced seismicity in Karun III dam (Southwestern Iran)

Statistical analyses of the Karun III reservoir seismicity reveal a remarkable correlation between seismicity rate and water-level harmonic changes. It seems that seismicity in this dam depends on rapid water-level changes. The three biggest earthquakes of Karun III, measuring 4, 4.1, and 4.3 on the Richter scale (ML), occurred after two stages of rapid filling of the dam on March 22, 2005 and May 12, 2006. These earthquakes happened when the water reached the maximum operational level. Since the beginning of filling the reservoir on November 8, 2004 until March, 2006, most reservoir-induced seismicity has been localized in three main clusters. The majority of the earthquakes occurred in the frontal anticline of Keyf Malek; the second and third clusters happened near Karun Blind Fault (KBF) and Mountain Front Fault (MFF), respectively. Filling Karun III reservoir immediately led to an increase in the occurrence of earthquakes. Further, following abrupt water-level changes, a considerable increase in the number of earthquakes is observed. Finally, in terms of seismicity rate, vertical and horizontal migration, magnitude, and distance, the earthquakes of Karun III behave differently.     

Role of Iron(III) and Aluminum Hydroxides in Concentration/reduction of Au(III) Complexes

Abstract: The adsorption of gold on iron(III) and aluminum hydroxides from solutions containing Au(III) complexes has been studied as a function of pH and chloride concentration at 30C. Iron(III) hydroxide was more effective in adsorbing gold from solution than aluminum hydroxide. However, both hydroxides controlled the behavior of Au(III) complex with very similar manner. The most effective gold adsorption occurred in aqueous solution with near neutral pH and low Cl concentration. In this solution condition, Au(III) complexes were mainly dissolved as AuCl₂(OH)₂^- and AuCl(OH)₃^-, and the surface charge for both hydroxides was positive. In addition, the adsorbed Au(III) complexes were spontaneously reduced to elemental gold in spite of the absence of a specific reducing agent.
The results of this study suggest that adsorption and spontaneous reduction of gold complexes on the surface of hydrous metal oxides with positive charge play an important role in gold precipitation in subsurface environment.     

Lepidocrocite-catalyzed Mn(II) oxygenation by air and its effect on the oxidation and mobilization of As(III)

Manganese (oxy)hydroxides (MnO_X) play important roles in the oxidation and mobilization of toxic As(III) in natural environments. Abiotic oxidation of Mn(II) to MnO_X in the presence of Fe minerals has been proved to be an important pathway in the formation of Mn(III, IV) (oxy)hydroxides. However, interactions between Mn(II) and As(III) in the presence of Fe minerals are still poorly understood. In this study, abiotic oxidation of Mn(II) on lepidocrocite, and its effect on the oxidation and mobilization of As(III) were investigated. The results show that MnO_X species are detected on lepidocrocite and their contents increase with increasing pH values ranging from 7.5 to 8.4. After 10 days, an MnOx component, groutite (α-MnOOH) was found on lepidocrocite. During the simultaneous oxidation of Mn(II) and As(III), and the As(III) pre-adsorbed processes, the presence and oxidation of Mn(II) significantly promotes the removal of soluble As(III). In addition, MnOx formed on lepidocrocite also contributes to the oxidation of soluble and adsorbed As(III) to As(V), the latter being subsequently released into solution. In the process where Mn(II) is pre-adsorbed on lepidocrocite, less As(III) is removed, given that the active sites occupied by MnOx inhibit the adsorption of As(III). In all experiments, the removal percentages of As(III) and the release of As(V) are correlated positively with pH values and initial concentrations of Mn(II), although they are not apparent in the Mn(II) pre-adsorbed system.     

The Geochemical Effects of Microbial Humic Substances Reduction

As part of a study on microbial redox alteration of humic substances we investigated the potential effect of this metabolism on the fate of heavy metals and hydrocarbons as a result of conformational alteration of the humic molecular structure due to microbial reduction. Our studies indicate that the microbial reduction of humic acids (HA) results in significant morphological and geochemical alterations. X‐ray microscopy analysis indicate that the conformational structure of the humic colloids is altered as a result of the redox change. In the reduced state, the HA appeared as small dense particles, on reoxidation, large loose aggregates were formed. In addition, spectrofluorometric studies indicated that the binding capacity of the HA for naphthalene was decreased by 10% when the HA was reduced. Similarly, the reduced HA yielded higher surface tension values at all concentrations tested which is indicative of a more hydrophilic and less hydrophobic solute. On reoxidation, the surface tension values reverted back to values similar to those obtained for the untreated oxidized HA. These data indicate that the hydrophobicity of the HA is altered on biological reduction of the HA and that this alteration is reversible. In contrast the reduced HA demonstrated a 15% higher affinity for heavy metals such as divalent cobalt than the oxidized HA. In addition to increasing the binding capacity of HA for heavy metals, the reduction of the HA also decreased the bioavailability and toxicity of bound heavy metals such as chromium. When incubated in the presence of Cr(III) and HA, cells of Escherichia coli grew much more rapidly in the presence of the reduced HA suggesting that the higher metal binding capacity of the reduced humic substances resulted in a removal of the Cr(III) from solution and hence reduced its bioavailability and toxicity. These studies demonstrate that HA redox state and reduction of humic acids by microorganisms can have a significant effect on the molecular morphology and binding constants of HA for heavy metals and hydrocarbons and also directly affects the bioavailability of these compounds in the environment.     

成都日降水量年极大值的渐近分布

利用1951－1999年成都日降水量年极大值的记录，通过统计推断，找出了成都日降水量年极大值遵循的渐近分布。讨论了两种分布－皮迩逊Ⅲ型分布、对数正态分布，并比较了它们的拟合效果，最后得出成都日降水量年极大值较好地遵循对数正态分布，并讨论了它们的参数估计方法。     

Correlated multiwavelength emission from the X-ray-bright Seyfert galaxy III Zw 2

The X-ray-bright Seyfert 1 galaxy III Zw 2 was observed with XMM–Newton in 2000 July. Its X-ray spectrum can be described by a power law of photon index Γ= 1.7 and an extremely broad (FWHM∼ 140 000 km  s⁻¹  ) Fe Kα line at 6.44 keV. The iron line has an equivalent width of ∼800 eV. To study the long-term X-ray behaviour of the source we have analysed 25 yr of data, from 1975 to 2000. There is no evidence of significant intrinsic absorption within the source or of a soft X-ray excess in the XMM or archival data. We do not detect rapid X-ray variability (a few  × 10³ s  ) during any of the individual observations; however, on longer time-scales (a few years) the X-ray light curve shows 10-fold flux variations. We infer a black hole mass of  ∼10⁹ M_⊙  (from Hβ FWHM) for III Zw 2 which is much higher than some previous estimates.
A comparison of X-ray variability with light curves at other wavelengths over a 25-yr period reveals correlated flux variations from radio to X-ray wavelengths. We interpret the variable radio to optical emission as synchrotron radiation, self-absorbed in the radio/millimetre region, and the X-rays mainly as a result of Compton up-scattering of low-energy photons by the population of high-energy electrons that give rise to the synchrotron radiation.     

Mixing and transport near the shallow-crested Rumble III seamount and the implications for plankton distribution

Vessel-based observations of water column structure and flow near a shallow-crested seamount are used to quantify the physical disturbance induced by that seamount. The implications of this disturbance on the ‘feeding hole’ hypothesis are then examined based on data from moored thermistors and acoustic current profilers, as well as vessel-based acoustic sounding-derived biomass estimates, currents, and conductivity-temperature-depth profiles from a 55 km square grid of stations around the crest. Mean currents in the region of 0.2 m s^?1 are comparable to observations from surface drifters whereas the semidiurnal tidal flow amplitude was one third of this. Thorpe Scale-based estimates of energy dissipation rate were in the range 10^?9 to 2.10^?8 W kg^?1 and vertical diffusivities K_z were in the range 10^?4 to 10^?3 m² s^?1. Turbulence levels were higher upstream of the seamount–likely due to the influence of nearby seamounts Rumble IV and V. There was no evidence of a Taylor Cap in the Rumble III velocity field. The sounder data provide some evidence of a feeding hole and analysis based on diffusivities suggests that this might persist downstream of the seamount for as much as 7 days.     

Environmental flow requirements assessment in the Halda River,Bangladesh

Abstract

Environmental flows have scarcely been considered in river water management in Bangladesh. This study attempts to assess the environmental flow requirements in the Halda River, Bangladesh. Thus, the objectives are to estimate the Halda River flow with different return periods/probabilities, which was done using the log-Pearson Type III distribution (LPIII), and to mitigate the environmental problems in the Halda River using the building block method. The LPIII distribution was used to estimate the expected extreme and satisfactory flows for fish habitat at Panchpukuria station and the expected extreme water levels at Panchpukuria, Narayanhat, Telpari and Enayethat stations. It was found that floods are likely to occur at least once in 2.1, 1.02, 1.75 and 1.25 years at Panchpukuria, Narayanhat, Telpari and Enayethat stations, respectively. The results of flow and water quality analyses suggest that environmental flow requirements cannot be achieved in this river throughout the year. The environmental flow requirements and conservation of fish resources can be achieved by implementing the suggestions provided in conjunction with a comprehensive awareness programme, investigations and trade-off analyses being among the suggestions.

Editor Z.W. Kundzewicz; Associate editor B. Sivakumar

Citation Akter, A. and Ali, Md. H., 2012. Environmental flow requirements assessment in the Halda River, Bangladesh. Hydrological Sciences Journal, 57 (2), 326–343.     

Gold Content in Siliceous Deposits Formed from Acidic and Iron-rich Geothermal Waters at Hatchobaru, Central Kyushu, Japan

Abstract: The gold content in siliceous deposits formed from geothermal waters at the Hatchobaru geothermal power station in central Kyushu, Japan, was determined by inductively coupled plasma quadrupole mass spectrometry (ICP–MS). It ranges from 1.3 to 4.6 mg/kg. The highest gold content was obtained from the siliceous deposit formed from acidic waters. In this siliceous deposit, hydrous iron(III) oxide of amorphous state is a major constituent, suggesting that hydrous iron(III) oxide might play an important role when gold is concentrated into siliceous deposits formed from acidic and iron-rich geothermal waters.