Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,     

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.     

Karst groundwater protection in the Kupa River catchment area and sustainable development

One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km²) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about 6 m³/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway and that many settlements and a highly developed wood industry are present. The combination of protecting water resources with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment before the water passes into the karst underground system.     

Subsurface dams to harvest rainwater— a case study of the Swarnamukhi River basin, Southern India

Declining water level trends and yields of wells, deterioration of groundwater quality and drying up of shallow wells are common in many parts of India. This is mainly attributed to the recurrence of drought years, over exploitation of groundwater, increase in the number of groundwater structures and explosion of population. In this subcontinent, the saving of water has to be done on the days it rains. India receives much of its rainfall in just 100 h in a year mostly during the monsoon period. If this water is not captured or stored, the rest of the year experiences a precarious situation manifest in water scarcity. The main objective behind the construction of subsurface dams in the Swarnamukhi River basin was to harvest the base flow infiltrating into sandy alluvium as waste to the sea and thereby to increase groundwater potential for meeting future water demands. An analysis of hydrographs of piezometers of four subsurface dams, monitored during October 2001–December 2002, reveals that there is an average rise of 1.44 m in post-monsoon and 1.80 m in the pre-monsoon period after the subsurface dams were constructed. Further, during the pre-monsoon month of June, much before construction of subsurface dams in October 2001, the water level was found fluctuating in the range of 3.1–10 m, in contrast to the fluctuation ranging from 0.4 to 3.1 m during the period following the construction of dams. Hence, the planning of rainwater harvesting structures entails thorough scientific investigations for identifying the most suitable locations for subsurface dams.     

长江口水域多光谱遥感水深反演模型研究

利用Landsat-7 ETM 遥感影像反射率和实测水深值之间的相关性可以探测水深。该文介绍单波段、双波段比值和多波段3种线性回归模型以及动量BP人工神经网络水深反演模型。选择长江口北港河道上段作为研究区,利用上述模型,分两种情况进行水深反演:一是以河道全部历史样本建模;二是将河道按自然水深划分为浅水区和深水区分别建模。结果表明:神经网络模型预测精度高于线性回归模型;水深分区后线性回归和神经网络模型预测误差均有所减小。     

A heuristic model for potential geomorphic influences on trophic interactions in streams

Whereas certain linkages between stream channel morphology and stream ecology are fairly well-understood, how geomorphology influences trophic interactions remains largely unknown. As a first step, a simple, heuristic model is developed that couples reach-scale geomorphic morphology with trophic dynamics between vegetation, detritus, herbivores, and predators. Predation is assumed to increase with depth beyond a threshold depth, and herbivory is assumed to decrease with velocity beyond a threshold velocity. Results show that the modeled food chain is sensitive to channel geometry, particularly around the threshold conditions for predators and herbivores. Importantly, geomorphic influences are not isolated to a particular trophic level, but rather are transferred through the food chain via top-down and bottom-up effects. The modeled system is particularly sensitive to changes in the end-members of the food chain: vegetation and predators. Results illustrate that geomorphic disturbances, known to affect a single trophic level (e.g., fish), likely impact multiple trophic levels in the stream ecosystem via trophic interactions. Such impacts at the multiple trophic level are poorly understood. While limited by the lack of empirical long-term data for testing and calibration, this simple model provides a structure for generating hypotheses, collecting targeted data, and assessing the potential impacts of stream disturbance or restoration on entire stream ecosystems. Further, the model illustrates the potential for future coupled stream models to explore spatial and temporal linkages.     

Constructal view of scaling laws of river basins

River basins are examples of naturally organized flow architectures whose scaling properties have been noticed long ago. Based on data of geometric characteristics, Horton [Horton, R.E., 1932. Drainage basin characteristics. EOS Trans. AGU 13, 350–361.], Hack [Hack, J.T., 1957. Studies of longitudinal profiles in Virginia and Maryland. USGS Professional Papers 294-B, Washington DC, pp. 46–97.], and Melton [Melton, M.A, 1958. Correlation structure of morphometric properties of drainage systems and their controlling agents. J. of Geology 66, 35–56.] proposed scaling laws that are considered to describe rather accurately the actual river basins. What we show here is that these scaling laws can be anticipated based on Constructal Theory, which views the pathways by which drainage networks develop in a basin not as the result of chance but as flow architectures that originate naturally as the result of minimization of the overall resistance to flow (Constructal Law).     

Modelling net erosion responses to enviroclimatic changes recorded upon multisecular timescales

Land use change has been recognized throughout the Earth as one of the most important factors influencing the occurrence of rainfall-driven geomorphological processes. However, relating the occurrence of historical soil erosion rates is difficult because of the lack of long-term research projects in river basins. Also, complex models are not adequate to reconstruct erosion rate changes because they require significant input data not always available on long timescales. Given the problems with assessing sediment yield using complex erosion models, the objective of this study is to explore a parsimonious scale-adapted erosion model (ADT) from the original Thornes and Douglas algorithms, which aims at reconstruction of annual net erosion (ANE) upon multisecular timescales. As a test site, the Calore River basin (3015 km² in southern Italy) provides a peculiar and unique opportunity for modelling erosion responses to climate and land cover changes, where input-data generation and interpretation results were also supported by documented hydrogeomorphological events that occurred before and after land deforestation. In this way, ANE_ADT-values were reconstructed for the period 1675–2004 by using precipitation indexes, complemented by recent instrumental records, and by using land cover statistics from documented agrarian sources. Pulses of natural sedimentation in the predeforestation period have been related to Vesuvius volcanic activity and changes in rainstorm frequency. After deforestation, the basin system became unstable with sudden fluctuations in the hydrogeomorphological regime contributing significantly to increased erosion and, in turn, sediment transport sequences via river drainage towards the Tyrrhenian coast.     

New typologies for estuarine morphology

New theories to explain how tides and river flow determine estuarine bathymetries have been developed. The range of validity of these theories has been subsequently assessed against a recently available observational data set.Success in reproducing the evolution of estuarine bathymetries that has occurred over the last 10 000 years provides the basis for the translation, here, of these theories into new typologies. These then provide reference frameworks to enhance our perspective on existing morphologies and identify ‘anomalous’ estuaries. Further refinement of these new theories requires analyses of causal factors responsible for such anomalies drawing on classical morphological experience. These frameworks can also be used for calculating likely future bathymetric adjustments for prescribed changes in mean sea level, tidal amplitudes, river flow and sediment supply.     

Morphometric analysis of a subtropical Andean basin (Tucumán, Argentina)

A morphometric analysis was done to determine the drainage characteristics of Lules River basin using land-sat imageries and topographical maps. This catchment was divided into seven sub-basins for the analysis: Liquimayo, Hoyada, Ciénaga, De Las Tablas, Siambón, Potrerillo and San Javier. Yungas ecoregion covers almost all the watershed. The drainage patterns of the sub-basins are dendritic and parallel. The basin includes seventh order stream and lower streams order mostly dominate the basin. The development of stream segments is affected by slope and local relief. The mean bifurcation ratio indicates that the drainage pattern is not much influenced by geological structures. The shape parameters also reveal the elongation of the basin and sub-basins.