Genetic algorithm for fitting a mixed Bingham distribution to 3D orientations: a tool for the statistical and paleostress analyses of fracture orientations

The clustering of fracture orientations is important for tectonic studies and for geotechnical engineering. In this study, a real‐coded genetic algorithm was adopted to fitting a mixed Bingham distribution to orientation data by maximizing the log‐likelihood function of the distribution. The maximization is a difficult problem, because the function has multimodality and singularity. It was found that the algorithm was effective for this problem. Given the orientations of dilational fractures, the present method determines not only the stress axes and stress ratio of each of the fracture groups but also the maximum non‐dimensionalized fluid pressure at the time of their formation. In addition, the software calculates the 95 % error ellipses of the concentration axes. The present method found that the orientations of ore veins of the Akenobe Mine, SW Japan, should be partitioned into three clusters. It is shown that two of the groups had distinctive Zn and Sn contents, and that the ore fluids had overpressures only slightly greater than the minimum principal stress at the time of the deposition of Zn‐ and Sn‐rich veins.     

广南堂上金矿多种金矿化的发现

在不到10km^2的范围内，集中发现了滇黔桂金三角地区常见的多种矿化类型：微细粒浸染型金矿、不整合面上金矿（大厂层）、基性火山岩金矿、火山碎屑沉积型金矿、石英脉型金矿、现代河流沉积中的砂金，且存在不同的找矿标志。     

不纯碳酸盐岩的变质作用

不纯碳酸盐岩中的矿物共生组合与变质时的总压和二氧化碳分压密切相关。总压增高促使透闪石、透辉石和橄榄石等矿物生成温度增高。变质过程中岩石中流体成分的变化有两种极端情况,即渗滤作用和缓冲作用。渗滤作用下变质反应,变质矿物界线和变质矿物特征等均与缓冲作用下有所差异,以此可以区别它们。湖北宿松群和河北红旗营子群不纯大理岩是在渗滤作用下变质的。山西五台群板峪口组不纯大理岩是在缓冲加渗滤作用下变质的。     

2D Self-Potential tomographies for studying groundwater flows in the Varco d''Izzo landslide (Basilicata, southern Italy)

A geoelectrical monitoring activity has been carried out to improve the geological and hydrogeological knowledge about the Varco d'Izzo landslide (Potenza, Basilicata, Southern Apennine, Italy), an active rotational–translational slide evolved in earth-flow. In this work we have focused on the Self-Potential (SP) method by applying three different SP measuring techniques and combining modern technologies for data acquisition and new methods for tomographic inversion. A SP map and three static SP tomographies have been carried out to better analyse the groundwater circulation system and to better reconstruct the geometry of the landslide body. In the accumulation zone, which is the area more exposed to the geomorphological activity, a new SP measuring strategy has been applied. This strategy, based on time-continuous 2D SP tomographies, helps identify water flow changes in subsurface by studying the time series of SP tomographic images. The analysis of time-dependent changes of water infiltration in near surface is the key to better understand the hydrogeological processes underlying the ground instability phenomena. The time-lapse analysis of tomographic images has allowed us not only to investigate the correlation between the temporal changes of SP signals and rainfall events, but also to quantify the range of these changes. The modification of the distribution of the SP source accumulation zones is associated with the dynamics of the groundwater flows. These preliminary results allow us to consider the SP tomographic method as a tool for geophysical monitoring of landslide areas and encourage to develop new measuring systems for near-real time applications.     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

Water quality evaluation in Tidal River reaches of Liaohe River Estuary, China using a revised QUAL2K model

Rivers in the Liaohe River Estuary area have been seriously polluted by discharges of wastewater containing petroleum pollutants and nutrients. In this paper, The Enhanced Stream Water Quality Model (QUAL2K) and its revised model as well as One-dimensional Tide Mean Model (1D model) were applied to predict and assess the water quality of the tidal river reach of the Liaohe River Estuary. Dissolved oxygen (DO), biochemical oxygen demand (BOD₅), ammonia nitrogen (NH₃-N) and total phosphorus (TP) were chosen as water quality indices in the two model simulations. The modelled results show that the major reasons for degraded rivers remain petroleum and non-point source pollution. Tidal water also has a critical effect on the variation of water quality. The sensitivity analysis identifies that flow rate, point load and diffuse load are the most sensitive parameters for the four water quality indices in the revised QUAL2K simulation. Uncertainty analysis based on a Monte Carlo simulation gives the probability distribution of the four water quality indices at two locations (6.50 km and 44.84 km from the river mouth). The statistical outcomes indicate that the observed data fall within the 90% confidence intervals at all sites measured, and show that the revised QUAL2K gives better results in simulating the water quality of a tidal river.     

Continuous Gradations among Primary Carbonatitic, Kimberlitic, Melilititic, Basaltic, Picritic, and Komatiitic Melts in Equilibrium with Garnet Lherzolite at 3-8 GPa

Multianvil melting experiments in the system CaO–MgO–Al₂O₃–SiO₂–CO₂(CMAS–CO₂) at 3–8 GPa, 1340–1800°C, involvingthe garnet lherzolite phase assemblage in equilibrium with CO₂-bearingmelts, yield continuous gradations in melt composition betweencarbonatite, kimberlite, melilitite, komatiite, picrite, andbasalt melts. The phase relations encompass a divariant surfacein P–T space. Comparison of the carbonatitic melts producedat the low-temperature side of this surface with naturally occurringcarbonatites indicates that natural magnesiocarbonatites couldbe generated over a wide range of pressures >2·5 GPa.Melts analogous to kimberlites form at higher temperatures alongthe divariant surface, which suggests that kimberlite genesisrequires more elevated geotherms. However, the amount of waterfound in some kimberlites has the potential to lower temperaturesfor the generation of kimberlitic melts by up to 150°C,provided no hydrous phases are present. Compositions resemblinggroup IB and IA kimberlites are produced at pressures around5–6 GPa and 10 GPa, respectively, whereas the compositionsof some other kimberlites suggest generation at higher pressuresstill. At pressures <4 GPa, an elevated geotherm producesmelilitite-like melt in the CMAS–CO₂ system rather thankimberlite. Even when a relatively CO₂-rich mantle compositioncontaining 0·15 wt % CO₂ is assumed, kimberlites andmelilitites are produced by <1% melting and carbonatitesare generated by even smaller degrees of melting of <0·5%. KEY WORDS: carbonatite; CO₂; kimberlite; melilitite; melt generation     

珲春市草帽顶子矿泉水评价

草帽顶子矿泉水为偏硅酸矿泉水．含有钴、锶等多种人体必需的微量元素,是一处优质天然矿泉水。起源于大气降水．矿化时间约15年．流量较大,具有重要的开发利用价值．     

CO2地质埋存渗漏风险及补救对策

目前,将CO2埋存于地下深部地质构造（如油气藏、煤层、地下含水层及岩溶盐腔）的减排方案能有效地减缓温室效应而备受关注。无论什么储集体,我们都希望CO2在地下埋存的时间越长越好。然而,对于一项具体工程的实施,必然存在一些客观和主观因素造成CO2渗漏,比如废弃井的不完善或不合理处理、地层断裂系统和水动力系统以及地震所造成的渗漏等等。存在渗漏就可能会对周围人和生态环境造成危害。因此,进行CO2地质埋存的风险评估是相当有必要的,是我们能长期有效安全地进行该项减排方案必不可少的基础和保证。本文即想从建立一套完整的风险评估、管理和监测体系的角度并以加拿大Weyburn油田为例,深入分析CO2地质埋存中可能存在的渗漏风险和途径,建立CO2渗漏风险评估机制,并针对具体的渗漏可能性提出相应的补救对策,为全球范围内,尤其对我国刚刚开展CO2地质埋存研究工作提供一些有益的思路。     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.