夏季金沙江下游水-气界面CO2、CH4通量特征初探

河流是连接大陆和海洋两大碳库的桥梁,在全球碳循环中的作用举足轻重.金沙江作为长江的上游段,对区域碳循环及区域化学风化的影响非常重要.于2015年8月8-18日对金沙江下游水-气界面CO_2与CH_4通量特征进行监测与分析.采用顶空平衡法结合薄边界层模型估算法计算表层水体CO_2与CH_4的分压以及水-气界面的交换通量,并分析环境变量与其之间的相关性.研究发现,金沙江下游表层水体p(CO_2)平均值为2724.84±477.18μatm,表层水体p(CH_4)平均值为59.96±6.74μatm;水-气界面CO_2通量平均值为2.24±0.50 mmol/(m2·h),CH_4通量平均值为0.000163±0.00009 mmol/(m2·h),通量与分压趋势基本保持一致.表层水体p(CO_2)与溶解性无机碳浓度、碱度均呈显著正相关,而p(CH_4)与水温、叶绿素a浓度均呈显著正相关,CO_2通量与p(CO_2)、溶解性无机碳浓度、碱度均呈正相关,CH_4通量与p(CH_4)、风速均呈正相关,其他环境因素对通量的影响不明显,仍需进一步研究.金沙江下游水-气界面CH_4扩散通量较低,而CO_2扩散通量在世界主要河流中属于中等水平.     

Spatial variation of flow characteristics in a subarctic meandering river in ice-covered and open-channel conditions: A 2D hydrodynamic modelling approach

To be able to understand year-round river channel evolution both at present and in the future, the spatial variation of the flow characteristics and their sediment transport capabilities under ice cover need to be detected. As the measurements done through cross-sectional drill holes cover only a small portion of the river channel area, the numerical simulations give insight into the wider spatial horizontal variation of the flow characteristics. Therefore, we simulate the ice-covered flow with a hydrodynamic two-dimensional (2D) model in a meandering subarctic river (Pulmanki River, Finland) in mid-winter conditions and compare them to the pre-winter open-channel low flow situation. Based on the simulations, which are calibrated with reference measurements, we aim to detect (1) how ice-covered mid-winter flow characteristics vary spatially and (2) the erosion and sedimentation potential of the ice-covered flow compared to open-channel conditions. The 2D hydrodynamic model replicated the observed flow characteristics in both open-channel and ice-covered conditions. During both seasons, the greatest erosional forces locate in the shallow sections. The narrow, freely flowing channel area found in mid-winter cause the main differences in the spatial flow variation between seasons. Despite the causes of the horizontal recirculating flow structures being similar in both seasons, the structures formed in different locations depended on whether the river was open or ice covered. The critical thresholds for particle entrainment are exceeded more often in open-channel conditions than during ice-covered flow. The results indicate spatially extensive sediment transport in open-channel conditions, but that the spatial variability and differences in depositional and erosional locations increase in ice-covered conditions. Asymmetrical bends and straight reaches erode throughout the year, whereas symmetrical, smaller bends mainly erode in open-channel conditions and are prone to deposition in winter. The long ice-covered season can greatly affect the annual morphology of the submerged channel. © 2019 John Wiley & Sons, Ltd.     

Revisiting the morphological method in two-dimensions to quantify bed-material transport in braided rivers

Research in the 1990s showed that bed-material transport rates could be estimated at the reach scale in both one-dimension and, over small spatial scales (10s of m), in two-dimensions. The limit on the latter was the spatial scale over which it was possible to obtain distributed data on morphological change. Here, we revisit the morphological method given progress in both topographical data acquisition and hydraulic modelling. The bed-material transport needed to conserve mass is calculated in both one and two dimensions for a 1600 m × 300 m Alpine braided river “laboratory”. High-resolution topographical data were acquired by laser scanning to quantify Digital Elevation Models (DEMs), and morphological changes caused by the flushing of the water intake were derived from repeated surveys. Based on DEMs of differences, 1D bed-material transport rates were calculated using the morphological method. Then, a 2D hydraulic model was combined with a topographic correction to route sediment through the network of braided channels and to obtain a spatially variable estimate of transport in both downstream and cross-stream directions. Monte Carlo simulation was applied to the routing model parameters, allowing identification of the most probable parameter values needed to minimize negative transport. The results show that within-section spatial compensation of erosion and deposition using the 1D treatment leads to substantial local errors in transport rate estimates, to a degree related to braiding intensity. Even though the 2D application showed that a large proportion of the total transport was actually concentrated into one main channel during the studied low flow event, the proportion of transport in secondary anabranches is substantial when the river starts braiding. Investigations of the effects of DEM resolution, competent flow duration and survey frequency related to ‘travelling bedload’ and sequential erosion-deposition emphasized the critical importance of careful data collection in the application of the morphological method. © 2019 John Wiley & Sons, Ltd.     

CO2 saturation estimates at Sleipner (North Sea) from seismic tomography and rock physics inversion

CO₂ saturations are estimated at Sleipner using a two-step imaging workflow. The workflow combines seismic tomography (full-waveform inversion) and rock physics inversion and is applied to a two-dimensional seismic line located near the injection point at Sleipner. We use baseline data (1994 vintage, before CO₂ injection) and monitor data that was acquired after 12 years of CO₂ injection (2008 vintage). P-wave velocity models are generated using the Full waveform inversion technology and then, we invert selected rock physics parameters using an rock physics inversion methodology. Full waveform inversion provides high-resolution P-wave velocity models both for baseline and monitor data. The physical relations between rock physics properties and acoustic wave velocities in the Utsira unconsolidated sandstone (reservoir formation) are defined using a dynamic rock physics model based on well-known Biot–Gassmann theories. For data prior to injection, rock frame properties (porosity, bulk and shear dry moduli) are estimated using rock physics inversion that allows deriving physically consistent properties with related uncertainty. We show that the uncertainty related to limited input data (only P-wave velocity) is not an issue because the mean values of parameters are correct. These rock frame properties are then used as a priori constraint in the monitor case. For monitor data, the Full waveform inversion results show nicely resolved thin layers of CO₂–brine saturated sandstones under intra-reservoir shale layers. The CO₂ saturation estimation is carried out by plugging an effective fluid phase in the rock physics model. Calculating the effective fluid bulk modulus of the brine–CO₂ mixture (using Brie equation in our study) is shown to be the key factor to link P-wave velocity to CO₂ saturation. The inversion tests are done with several values of Brie/patchiness exponent and show that the CO₂ saturation estimates are varying between 0.30 and 0.90 depending on the rock physics model and the location in the reservoir. The uncertainty in CO₂ saturation estimation is usually lower than 0.20. When the patchiness exponent is considered as unknown, the inversion is less constrained and we end up with values of exponent varying between 5 and 20 and up to 33 in specific reservoir areas. These estimations tend to show that the CO₂–brine mixing is between uniform and patchy mixing and variable throughout the reservoir.     

Analysis of Stock Market Development and CO2 Emissions on OECD Countries via an Empirical Model

Accompanying economic growth, CO₂ emissions have polluted the natural environment worldwide. This study highlights the special problems with stock market development and CO₂ emissions in 25 Organization for Economic Cooperation and Development (OECD) countries during 1971–2007 to trace the trend of CO₂ emissions while countries grow their economies. A panel‐data model is applied to analyze the relationships between stock market (SM) development, energy consumption, gross domestic product (GDP), and CO₂ emissions in 25 OECD countries. Low‐GDP countries show different results from high‐GDP countries in the trends of SM development and CO₂ emissions, and dynamic effects occur in SM development and CO₂ emissions under various GDP conditions. There is a negative relationship between SM development and CO₂ emissions if countries enjoy high economic growth, which means that these countries avoid CO₂ emissions through SM development. However, a positive relationship is found between SM development and CO₂ emissions if countries experience low economic growth, which means that SM development does not show the boycott‐effect relationship with CO₂ emissions when countries experience low levels of economic development. This study shows a correlation between SM development and CO₂ emissions among OECD countries.     

富锂尖晶石锂锰氧化物的电化学性能

以LiOH.H2O和Mn(CH3COO)2.2H2O为原料,通过微波烧结和固相烧结的两段烧结法合成了锂离子电池正极材料Li3.22Na0.569Mn5.78O12尖晶石。研究表明,在380℃的固相烧结温度下,微波处理有利于生成纯尖晶石相。在2.5~4.5V电压区间,样品的初始放电容量高于132 mAh/g。在充放电过程中,40循环的放电容量几乎不衰减。微波烧结使该样品的Mn-O键被加强,晶格结构在充放电过程中保持稳定。     

太湖生态脆弱性特征与消除对策的初步探讨

本文研究了Ｈｇ＾２＋,Ｃｄ＾２＋对痧生经济植物莼菜冬芽茎叶叶绿素含量,叶绿素ａ／ｂ值,可溶性蛋白含量,Ｏ＾－２含量以及活笥氧清除系统活性（ＳＯＤ,ＣＡＴ,ＰＯＤ）的影响,实验结果表明：叶绿素含量,叶绿素ａ／ｂ值、可溶性蛋白含量随着Ｈｇ＾２＋,Ｃｄ＾２＋处理浓度的加大呈下降趋势;     

Using triple oxygen isotopes and oxygen-argon ratio to quantify ecosystem production in the mixed layer of northern South China Sea slope region

Quantifying the gross and net production is an essential component of carbon cycling and marine ecosystem studies.Triple oxygen isotope measurements and the O_2/Ar ratio are powerful indices in quantifying the gross primary production and net community production of the mixed layer zone,respectively.Although there is a substantial advantage in refining the gas exchange term and water column vertical mixing calibration,application of mixed layer depth history to the gas exchange term and its contribution to reducing indices error are unclear.Therefore,two cruises were conducted in the slope regions of the northern South China Sea in October 2014(autumn) and June 2015(spring).Discrete water samples at Station L07 in the upper 150 m depth were collected for the determination of δ~(17)0,δ~(18)O,and the O_2/Ar ratio of dissolved gases.Gross oxygen production(GOP) was estimated using the triple oxygen isotopes of the dissolved O_2,and net oxygen production(NOP) was calculated using O_2/Ar ratio and O_2 concentration.The vertical mixing effect in NOP was calibrated via a N_2O based approach.GOP for autumn and spring was(169±23) mmol/(m~2·d)(by O_2) and(189±26) mmol/(m~2·d)(by O_2),respectively.While NOP was 1.5 mmol/(m~2·d)(by O_2) in autumn and 8.2 mmol/(m~2·d)(by O_2) in spring.Application of mixed layer depth history in the gas flux parametrization reduced up to 9.5% error in the GOP and NOP estimations.A comparison with an independent O_2 budget calculation in the diel observation indicated a26% overestimation in the current GOP,likely due to the vertical mixing effect.Both GOP and NOP in June were higher than those in October.Potential explanations for this include the occurrence of an eddy process in June,which may have exerted a submesoscale upwelling at the sampling station,and also the markedly higher terrestrial impact in June.     

基于Sentinel-2A/B的新疆典型城市不透水面提取及空间差异分析

随着城市化进程加快,自然地表物理结构及属性的变化使得城市不透水面不断增加,进而造成城市土地覆盖类型剧烈变化,极大地影响着其环境质量和生态循环。因此,探讨不透水面的空间变化规律,对建设生态、和谐、宜居城市变得极为重要。本文选取新疆维吾尔自治区（简称新疆）典型城市（乌鲁木齐、喀什、哈密及克拉玛依）主城区为研究区,通过对Sentinel-2A/B影像L2范数归一化处理,结合增强型归一化差值不透水面指数ENDISI（Enhanced Normalized Difference Impervious Surface Index）,采用最大类间方差法（OTSU）自适应确定阈值,提取2017年和2019年新疆典型城市不透水面。结果表明：L2范数归一化处理与ENDISI结合能较好的突显不透水面与非不透水面的差异;OTSU自适应确定的阈值能够很好的区分不透水面,经示例验证（2019年乌鲁木齐主城区）,不透水面提取结果总体精度为86.60%,Kappa系数为0.73。通过对不透水面空间差异分析可知：从剖面线角度分析得出乌鲁木齐北部、喀什中部和北部及哈密中东部和北部ENDISI指数值均显著增加,而克拉玛依北部和中西部区域ENDISI指数值增加较少;从不透水面盒维数分析中得出,新疆典型城市的盒维数值均呈增加趋势,城市结构复杂度不断增强,其中哈密盒维数值最大,乌鲁木齐盒维数值最低,且哈密的盒维数值变化幅度最大,克拉玛依的盒维数值变化最小。本文可为新疆典型城市内涵式发展提供科学指导,为干旱区城市生态环境保护提供理论依据。     

藻型湖区氧化亚氮排放特征及其影响因素

湖泊等内陆水体是大气N₂O潜在的重要排放源,也是全球N₂O收支估算的重要组成部分。目前全球湖泊普遍面临富营养化和蓝藻暴发等问题,明晰藻型湖泊N₂O排放强度及其环境影响因子对准确估算湖泊N₂O排放和预测其未来变化至关重要。本研究选择太湖藻型湖区为研究对象,同时选取人为活动影响较小的湖心区作为对比区域,基于2011年8月至2013年8月为期2年的逐月连续观测,探讨藻型湖区N₂O排放特征及其影响因素。结果表明,藻型湖区呈现极强的N₂O排放,其排放通量为(4.88±3.05) mmol/(m²·d),是参考区域(湖心:(2.10±4.31) mmol/(m²·d))的2倍多。此外,在藻型湖区中不同点位N₂O排放差异显著,受河流外源输入影响,近岸区是N₂O的热点排放区,其年均排放通量高达10.93 mmol/(m²·d)。连续观测表明N₂