华北陆块2.56～2.52 Ga增氧事件对成矿和生命演化的影响

地球表层大气氧浓度的显著增高是地球史上最重大的地质事件之一,它不仅改变了地球表层环境,促进了生命演化,而且加速了表生地质过程,形成一系列适应环境突变的岩石和重要矿床。地球在前寒武纪时期曾发生过两次大气快速增氧事件,分别为大氧化事件(GOE)和新元古代氧化事件(NOE)。本文主要论述华北陆块新太古代晚期增氧事件的时限及其对成矿和生命演化的影响。华北陆块新太古代晚期形成千余个氧化物相BIF型铁矿床和矿点,属于阿尔戈马型,累计查明资源储量约335.36亿t,占全国铁矿总资源储量46%。该类矿床和矿点形成于弱碱性氧化环境,成矿时代主要介于2.56～2.52 Ga,并经历了2.51～2.50 Ga的变质作用。通过对BIF型铁矿床中矿石的Ce异常、铁同位素组成和硫同位素非质量分馏效应(MIF-S)等特征研究,显示在2.56～2.52 Ga期间大气圈的氧浓度大幅度升高,并由缺氧还原环境变为具一定氧浓度(1%～10%PAL)的氧化环境,暗示华北陆块在此期间曾出现过一次显著的增氧事件。其对华北陆块的成矿作用产生了重要影响,主要表现在以下三个方面:(1)形成大量氧化物相BIF型铁矿床,这是中国最重要的铁矿...     

Dissolved major ions,Sr and 87Sr/86Sr of coastal lakes from Larsemann hills,East Antarctica: Solute sources and chemical weathering in a polar environment

Dissolved major ions, Sr concentrations and ⁸⁷Sr/⁸⁶Sr ratios of 10 coastal lakes from the Larsemann Hills, East Antarctica have been studied to constrain their solute sources, transport and glacial weathering patterns in their catchments. In absence of perennial river/streams, lakes serve as only reliable archive to study land surface processes in these low-temperature regions. The lake water chemistry is mostly Na-Cl type and it does not show any significant depth variations. Sr isotope compositions of these lakes vary from 0.7110 to 0.7211 with an average value of 0.7145, which is higher than modern seawater value. In addition to oceanic sources, major ions and Sr isotopic data show appreciable amount of solute supply from chemical weathering of silicate rocks in lake catchments and dissolution of Ca-Mg rich salts produced during the freezing of seawaters. The role of sulphide oxidation and carbonate weathering are found to be minimal on lake hydro-chemistry in this part of Antarctica. Inverse model calculations using this chemical dataset provide first-order estimates of dissolved cations and Sr; they are mostly derived from oceanic (seawater + snow) sources (cations approximately 76%) and (Sr approximately 92%) with minimal supplies from weathering of silicates (cations approximately 15%); (Sr approximately 2%) and Ca-rich minerals (cations approximately 9%); (Sr approximately 7%). The silicate weathering rate and its corresponding atmospheric CO₂ consumption rate estimates for Scandrett lake catchment (3.6 ± 0.3 tons/km²/year and 0.5 × 10⁵ moles/km²/year), are lower than that of reported values for the average global river basins (5.4 tons/km²/year and 0.9 × 10⁵ tons/km²/year) respectively. The present study provides a comprehensive report of chemical weathering intensity and its role in atmospheric CO₂ consumption in low-temperature pristine environment of Antarctica. These estimates underscore the importance of Antarctica weathering on atmospheric CO₂ budget, particularly during the past warmer periods when the large area was exposed and available for intense chemical weathering.     

Influences of the Great Whirl on surface chlorophyll a concentra-tion off the Somali Coast in 2017

The general features of the Great Whirl (GW) off the Somali Coast in 2017 and its influences on chlorophyll a (Chl a) concentration were studied by using satellite data and model outputs. Results show that GW, which initiated at 7°N, 53°E on June 13, had a lifetime of 153 d with an average amplitude of 16 cm and an average radius of 205 km. After the formation of GW, the concentration of Chl a in the interior of GW showed a downward trend throughout its life cycle, except in early July and mid-October. In early July, the Chl a blooms in the interior of GW were attributed to the combined effect of three processes. They are eddy horizontal transportation, the deepening of the mixed layer caused by the monsoon and eddy pumping, and the upward transportation of nutrients caused by eddy-induced Ekman pumping. In October, the Chl a blooms were probably due to the weakening of GW. During the period, water exchange occurred more frequently across the eddy, thus phytoplanktons were imported into the interior of GW.     

Mixing processes relevant to phytoplankton dynamics in lakes

Active turbulence in lakes is confined to the surface mixed layer, to boundary layers on the lake sides and bottom, and to turbulent patches in the interior. The density stratification present in most lakes fundamentally alters the pathways connecting external mechanical energy inputs, for example by wind, with its ultimate fate as dissipation to heat; the density stratification supports internal waves and intrusions that distribute the input energy throughout the lake. Intrusions may be viewed as internal waves with zero horizontal wavenumber and are formed each time localised mixing occurs in a stratified fluid. Intrusions are also formed in the epilimnion by differential heating or cooling and by differential deepening. The fraction of lake volume below the diurnal mixed layer that is subject to active turbulence is very small, probably of the order of 1% or less in small to medium‐sized lakes. By contrast, in the surface mixed layer, turbulence is less intermittent and maintains phytoplankton in suspension and controls their exposure to the underwater solar flux. Nutrient transport to individual cells depends not only on the cell Reynolds number but also on the Peclet number, which, if large, implies enhanced mass transfer above purely diffusive values.     

喜马拉雅山地区冰湖信息的遥感自动化提取

在“全域—局部”分步迭代水体信息提取方法的基础上, 通过对水体信息提取指标——水体指数的物理特性的分析实现了算法中全域阈值的自动选择与局部阈值的自适应调整, 并结合DEM 生成的山体坡度和阴影信息,减少局部迭代过程中对其他地表特征与水体信息的误判。在此基础上, 建立一种适合于高山地区冰川湖泊的自动化提取方案。试验采用Landsat 数据对喜马拉雅山地区的冰川湖泊进行信息提取, 结果表明该方法能够快速准确地完 成大区域范围内的冰川湖泊制图, 并能最大程度地消除高山地区湖泊水体识别中冰川和山体阴影的影响。     

Anatomy of a large Ag–Pb–Zn deposit in the Great Xing'an Range,northeast China: metallogeny associated with Early Cretaceous magmatism

The Bairendaba vein-type Ag–Pb–Zn deposit, hosted in a Carboniferous quartz diorite, is one of the largest polymetallic deposits in the southern Great Xing'an Range. Reserves exceeding 8000 tonnes of Ag and 3 million tonnes of Pb?+?Zn with grades of 30 g/t and 4.5% have been estimated. We identify three distinct mineralization stages in this deposit: a barren pre-ore stage (stage 1), a main-ore stage with economic Ag–Pb–Zn mineralization (stage 2), and a post-ore stage with barren mineralization (stage 3). Stage 1 is characterized by abundant arsenopyrite?+?quartz and minor pyrite. Stage 2 is represented by abundant Fe–Zn–Pb–Ag sulphides and is further subdivided into three substages comprising the calcite–polymetallic sulphide stage (substage 1), the fluorite–polymetallic sulphide stage (substage 2), and the quartz–polymetallic sulphide stage (substage 3). Stage 3 involves an assemblage dominated by calcite with variable pyrite, galena, quartz, fluorite, illite, and chlorite. Fluid inclusion analysis and mineral thermometry indicate that the three stages of mineralization were formed at temperatures of 320–350°C, 200–340°C, and 180–240°C, respectively. Stage 1 early mineralization is characterized by low-salinity fluids (5.86–8.81 wt.% NaCl equiv.) with an isotopic signature of magmatic origin (δ¹⁸O_fluid = 10.45–10.65‰). The main ore minerals of stage 2 precipitated from aqueous–carbonic fluids (4.34–8.81 wt.% NaCl equiv.). The calculated and measured oxygen and hydrogen isotopic compositions of the ore-forming aqueous fluids (δ¹⁸O_fluid = 3.31–8.59‰, δD_fluid?=??132.00‰ to??104.00‰) indicate that they were derived from a magmatic source and mixed with meteoric water. Measured and calculated sulphur isotope compositions of hydrothermal fluids (δ³⁴S_∑S?=??1.2–3.8‰) indicate that the ore sulphur was derived mainly from a magmatic source. The calculated carbon isotope compositions of hydrothermal fluids (δ¹³C_fluid?=??26.52‰ to??25.82‰) suggest a possible contribution of carbon sourced from the basement gneisses. The stage 3 late mineralization is dominated (1.40–8.81 wt.% NaCl equiv.) by aqueous fluids. The fluids show lower δ¹⁸O_fluid (?16.06‰ to??0.70‰) and higher δD_fluid (?90.10‰ to??74.50‰) values, indicating a heated meteoric water signature. The calculated carbon isotope compositions (δ¹³C_fluid?=??12.82‰ to??6.62‰) of the hydrothermal fluids in stage 3 also suggest a possible contribution of gneiss-sourced carbon. The isotopic compositions and fluid chemistry indicate that the ore mineralization in the Bairendaba deposit was related to Early Cretaceous magmatism.     

Nature and significance of the late Mesozoic granitoids in the southern Great Xing’an range,eastern Central Asian Orogenic Belt

ABSTRACT

Abundant late Mesozoic granitic rocks are widespread in the southern Great Xing’an Range (GXAR), which have attracted much attention due to its significance for the Mesozoic tectonic evolution in the eastern Central Asian Orogenic Belt. However, controversy has still surrounded the late Mesozoic geodynamic switching in the continental margin of east China, especially the spatial and temporal extent of the influence of the Mongol-Okhotsk and Palaeo-Pacific tectonic regimes. In order to better understand the Late Mesozoic evolutionary history of the southern GXAR, a number of geochemical, geochronological, and isotopic data of the granitoids in this region are collected. Magmatism in the southern GXAR can be divided into six phases: Late Carboniferous (325–303 Ma), Early-Middle Permian (287–260 Ma), Triassic (252–220 Ma), Early Jurassic (182–176 Ma), Late Jurassic (154–146 Ma), and Early Cretaceous (145–111 Ma). Mesozoic magmatic activities in the southern GXAR peaked during the Late Jurassic to Early Cretaceous, accompanied by large-scale mineralization. Sr–Nd–Hf isotopic evidence of these granitic rocks suggested they were likely originated from a mixed source composed of lower crust and newly underplated basaltic crust. Assimilation-fractional crystallization (AFC) or crustal contamination possibly occurred in the magma evolution, and a much more addition of juvenile component to the source of the Early Cretaceous granitoids than that of Late Jurassic. The closure of Mongol-Okhotsk ocean and the break-off of the Mongol-Okhotsk oceanic slab at depth in the Jurassic triggered extensive magmatism and related mineralization in this region. The Jurassic intrusive activities was affected by both the subduction of the Palaeo-Pacific plate and the closure of Mongol-Okhotsk ocean. Less influence of the Mongol-Okhotsk tectonic regime on the Early Cretaceous magmatism, whereas, in contrast the Palaeo-Pacific tectonic regime possibly continued into the Cenozoic.     

Petrogenesis of Early Cretaceous volcanic rocks of the Manketouebo Formation in the Wuchagou region,central Great Xing’an Range,NE China,and tectonic implications: geochronological,geochemical, and Hf isotopic evidence

ABSTRACT

This study presents new whole-rock major and trace element geochemistry, zircon U–Pb ages, and Hf-isotope compositions for volcanic rocks from the Manketouebo Formation of the central Great Xing’an Range, NE China. These data provide precise ages and information on the petrogenesis and source of the magmas that formed this formation, furthering our understanding of the geodynamic setting of the large-scale late Mesozoic magmatism in the Great Xing’an Range and other areas in NE China. The Manketouebo Formation in the study area is dominated by rhyolites and rhyolitic tuffs with minor trachydacites. The LA-ICP-MS zircon U–Pb dating indicates that these volcanic rocks formed between 143 and 139 Ma. The volcanic rocks contain high silica (66.70–79.91 wt.%) and total alkali (5.93–9.72 wt.%) concentrations, and low concentrations of MgO (0.08–1.15 wt.%), total FeO (0.68–4.50 wt.%), and CaO (0.10–2.56 wt.%). They are enriched in large-ion lithophile elements (LILEs; e.g. Rb, Th, and U) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs; e.g. Nb, Ta, Ti, and P) and heavy rare earth elements (HREEs), indicating that they are similar to highly fractionated I-type igneous rocks. All of the magmatic zircons from the analysed samples have high initial ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282900–0.283093), positive ε_Hf(t) values (7.48–14.19), and young Hf two-stage model ages (954–344 Ma) that suggest the primary magma that formed the volcanic rocks of the Manketouebo Formation was derived from the partial melting of Neoproterozoic to Phanerozoic juvenile crustal material, indicating in turn that significant crustal growth occurred at this time within the Xing’an Terrane. These data, combined with previous research into the spatial–temporal distribution of Mesozoic volcanic rocks in NE China, suggest that the Early Cretaceous magmatism in the Great Xing’an Range was influenced by both the subduction of the Palaeo-Pacific Plate and the closure of the Mongol–Okhotsk Ocean. This was a crucial period in the transformation from the Mongol–Okhotsk Ocean to the Palaeo-Pacific tectonic regimes. In summary, the early stages of Early Cretaceous magmatism in this area were related to the closure of the Mongol–Okhotsk Ocean, whereas the later stages of magmatism in this area and elsewhere in NE China were related to the subduction of the Palaeo-Pacific Plate.     

Variability of cold‐water coral mounds in a high sediment input and tidal current regime,Straits of Florida

Cold‐water coral mound morphology and development are thought to be controlled primarily by current regime. This study, however, reveals a general lack of correlation between prevailing bottom current direction and mound morphology (i.e. footprint shape and orientation), as well as current strength and mound size (i.e. footprint area and height). These findings are based on quantitative analyses of a high‐resolution geophysical dataset collected with an Autonomous Underwater Vehicle from three cold‐water coral mound sites at the toe of slope of Great Bahama Bank. The three sites (80 km² total) have an average of 14 mounds km^?2, indicating that the Great Bahama Bank slope is a major coral mound region. At all three sites living coral colonies are observed on the surface of the mounds, documenting active mound growth. Morphometric analysis shows that mounds at these sites vary significantly in height (1 to 83 m), area (81 to 6 00 000 m²), shape (mound aspect ratio 0·1 to 1) and orientation (mound longest axis 0 to 180°). The Autonomous Underwater Vehicle measured bottom current data depict a north–south flowing current that reverses approximately every six hours. The tidal nature of this current and its intermittent deviations during reversals are interpreted to contribute to the observed mound complexity. An additional factor contributing to the variability in mound morphometrics is the sediment deposition rate that varies among and within sites. At most locations sedimentation rate lags slightly behind mound growth rate, causing mounds to develop into large structures. Where sedimentation rates are higher than mound growth rates, sediment partially or completely buries mounds. The spatial distribution and alignment of mounds can also be related to gravity mass deposits, as indicated by geomorphological features (for example, slope failure and linear topographic highs) in the three‐dimensional bathymetry. In summary, variability in sedimentation rates, current regime and underlying topography produce extraordinarily high variability in the distribution, development and morphology of coral mounds on the Great Bahama Bank slope.     

河北省“长城式”金矿矿床地质特征简介

＂长城式＂金矿是产于中元古界长城系碳酸盐岩地层中的一种新类型金矿。含矿带长约50 km,宽4~5km,由多个矿区,几十个矿体构成,一般单个矿体规模较小,矿体厚度变化系数26%,品位变化系数74%,矿体产出受地层和构造控制明显。