The Chalukou deposit in the North Great Xing’an Range of China: A protracted porphyry Mo ore-forming system in a long-lived magmatic evolution cycle

The Chalukou deposit is located in the North Great Xing’an Range of the Xing’an-Mongolia Orogen bordering and to the northeast of the North China Craton. The deposit is a high-F-type porphyry Mo deposit hosted by the Chalukou composite igneous body containing small intrusive bodies genetically related to Mo mineralization. The composite igneous body includes pre-mineralization dolerite, monzogranite and syenogranite, syn-mineralization rhyolitic porphyry, granitic porphyry and fine-grained monzogranite, and post-mineralization rhyolitic porphyry, quartz porphyry, dioritic porphyry and andesitic porphyry. Detailed laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon dating of the igneous components of the composite igneous body was carried out to determine the temporal framework for magmatism in the Chalukou region. The new LA-ICP-MS U-Pb ages constraint documented here, together with the published ages, indicate that there was a protracted porphyry Mo ore-forming event of approximately 7 million years between ca. 152 when the ore related rhyolitic porphyry was emplaced and ca.145 Ma when molybdenite ceased being deposited. The dating reveals that the mineralization is a part of relatively long-lived magmatic cycle involving the emplacement of small doleritic stocks at ca. 165 Ma that progressively evolved into extensive granitic intrusions at ca. 164 Ma, and then diminished with the emplacement of mineralization-related porphyries to ca. 152 Ma. The emplacement of barren Early Cretaceous magmatism, represented by volcanic units in the ca. 136 Ma Guanghua Formation and porphyries, followed the mineralized magmatism.The syn-mineralization porphyry units associated with Mo contain zircons assaying ∼15 times higher in U and Th than the pre-mineralization magmatic phases. This indicates that there was a significant enrichment of Mo, U and Th in the magma, and directly associated with ore fluid exsolution. The return to their normal levels in the three elements in the post-mineralization magmatic phases indicates that they were exhausted from the magma chamber in the later phases. A genetic model is proposed for the enormous introduction of ore metals and enrichment at the Chalukou deposit. The protracted and multiphase igneous activity during the long-lived magmatism reflects a multistage enrichment of metal, and may play a crucial role in the formation of a volatile-enriched, fertile and large-volume magma chamber beneath the Chalukou deposit. Such a chamber is envisaged to be required for the formation of porphyry Mo deposits in general.     

Urban locations and Black Metropolis resilience in the Great Depression

Motivated by theoretical arguments about ethnicity and economics and by historical research on urban black communities in the United States, this paper investigates the resilience of the early twentieth-century Black Metropolis. The study tests hypotheses about changes during the Great Depression (1930–1940) in the advantages of various cities as locations of black communities’ ethnic economies, analyzing Census data on blacks’ representation in occupations reflecting the Black Metropolis’s professional, entrepreneurial, and cultural media pursuits. There is mixed support for the hypothesis that the nationally dominant urban centers of New York, Chicago, and Philadelphia had the most resilient Black Metropolises, a finding that casts doubt on claims that black communities in such key places enjoyed exceptionally favorable locational advantages. Yet, the results support the hypothesis that northern cities were, overall, more resilient locations than southern cities, particularly for black professionals and entrepreneurs, affirming the argument that the urban North’s Black Metropolises were vital economic opportunity centers for these black communities’ upper- and middle-classes.     

大兴安岭北段富林矽卡岩铜矿床成因:印支期含矿岩浆源区特征、蚀变矿物学及勘查意义

新近发现的印支期富林矽卡岩铜矿床位于大兴安岭北段新林区新林镇东约90km。矿区发育与成矿直接相关的花岗岩和侵入花岗岩中的花岗斑岩,矿体主要赋存于花岗岩与古元古代兴安桥组大理岩和早奥陶世黄斑脊山组钙质粉砂岩接触带内。富林矿床矿化与矽卡岩密切相关,整个矿化过程可分为两期:矽卡岩期和石英-硫化物期,5个阶段:早期矽卡岩阶段、退化蚀变阶段、氧化物阶段、早期硫化物阶段和晚期硫化物阶段,其中铜矿化主要发生在早期硫化物阶段。硫化物主要包括黄铜矿和黄铁矿,并含少量闪锌矿、方铅矿、斑铜矿等。蚀变类型包括石榴子石-透辉石矽卡岩化、阳起石-透闪石矽卡岩化、绿帘石矽卡岩化、绿泥石化、绢云母-粘土化、钾长石化和局部角岩化。电子探针分析(EMPA)结果表明:矿区内的石榴子石属钙铝-钙铁榴石系列,主要为钙铁榴石,辉石为透辉石-钙铁辉石系列,以透辉石为主,闪石主要为透闪石、阳起石以及少量镁绿钙闪石和铁浅闪石,帘石为黝帘石-绿帘石系列。黑云母以镁铁黑云母和铁叶云母为主,绿泥石主要为密绿泥石和铁叶绿泥石,长石以正长石和钠长石为主。石榴子石成分剖面显示从核部到边部,石榴子石呈现出钙铝榴石和钙铁榴石交替变化的环带特征,且Fe~(3+)含量的逐渐升高暗示后期成矿流体氧逸度升高,结合黑云母Mg-Fe~(3+)-Fe~(2+)图解,说明富林矽卡岩型铜矿床形成于较强的氧化环境。锆石LA-ICP-MS U-Pb测年结果显示花岗岩形成于~253Ma,花岗斑岩形成于~244Ma,为大兴安岭地区一期新的成矿事件。锆石原位Hf同位素测试结果表明,花岗岩εHf(t)介于-1.60~2.23,花岗斑岩εHf(t)介于-3.53~1.90,二者均具有古老的两阶段模式年龄,结合前人对区域构造背景的研究,认为富林花岗质岩石可能来自于松辽地块和兴安地块后碰撞背景下俯冲板片断离软溜圈上涌导致古老下地壳的部分熔融并卷入少量地幔物质而形成的岩浆。花岗斑岩及与斑岩有关的脉状矿化和蚀变的出现暗示富林地区可能存在印支期的斑岩型矿床,此外结合石榴子石、辉石成分特征以及辉石Mn/Fe比值与世界矽卡岩矿床对比,指出富林矿区外围找矿应综合考虑铜、钼、铁、金、铅、锌等矿化组合。     

青藏高原湖泊面积动态监测

高原湖泊的动态变化对区域水循环具有重要影响。受全球气候变化的影响,青藏高原湖泊自20世纪90年代开始呈现剧烈扩张趋势。为揭示近年来青藏高原湖泊面积的时空变化规律,本文提出了一种改进的半自动湖泊提取算法,结合环境减灾卫星（HJ-1A/1B）和Landsat系列卫星影像数据,对青藏高原内流流域中面积大于50 km²的127个湖泊进行了连续6年的动态监测,并分析了该区域2009-2014年湖泊面积时空变化特征。研究结果表明,该区域湖泊整体呈现显著扩张趋势,年均变化速率为231.89 km²yr^-1（0.87 %yr^-1）,6年间湖泊面积扩张速率有所减缓。其中,扩张湖泊有104个,收缩湖泊有23个,变化速率分别为271.08 km²yr^-1（1.02 % yr^-1）和-39.19 km²yr^-1（-0.15 %yr^-1）。不同区域湖泊面积变化具有明显差异,主要表现为东部及北部大部分区域湖泊扩张,南部地区大部分湖泊面积稳定,萎缩湖泊主要分布于研究区四周。最后,本文通过分析冰川融水补给对湖泊面积变化的影响,发现存在冰川融水补给的湖泊面积变化率远大于不存在冰川融水补给的湖泊。由此可见,近年来冰川融水的增加是促进青藏高原内流流域湖泊扩张的主要因素之一。     

巴丹吉林沙漠湖泊及地下水化学特征

通过对巴丹吉林沙漠丘间湖泊和古日乃、雅布赖、阿拉善右旗等地及其周围浅层地下水离子化学成分分析,探讨了沙漠地区湖水与地下水化学成分特点、水化学类型、空间变化和湖水补给来源。结果显示,巴丹吉林沙漠湖泊水的pH、盐度、TDS和电导率均远远大于地下水。湖水样品中Na⁺和Cl^-含量占绝对优势,大多数盐度较高的湖泊属于Na(K)-Cl-(SO₄) 型,个别盐度较低的微咸湖属于Na-(Mg)-(Ca)-Cl-(SO₄)-(HCO₃) 型。地下水的化学类型多数为Na-(Ca)-(Mg)-Cl-(SO₄)-(HCO₃)型,属微咸水,个别为Na-Cl-SO4型的咸水。沙漠东南部湖群水的pH值、盐度、TDS和电导率比较低,呈微碱性,属微咸湖;而北部湖群水的pH、盐度、TDS和电导率远远大于东南部湖群,呈中等碱性,为盐水湖。湖水离子化学特征显示沙漠东南部湖群自南向北的演化趋势为：微咸湖→咸水湖→盐水湖。湖水离子化学成分短时间序列变化指示,近9 年宝日陶勒盖、巴丹东湖、巴丹西湖、诺尔图、呼和吉林湖水中的大多数离子的含量有所降低,表明其近9 年来淡水补给量增多。湖水化学成分与湖水位高度显示,巴丹吉林沙漠湖群湖水流向是由东南流向西北。水化学成分和水位分布高度表明,该区沙漠湖水主要来自当地降水补给和来自沙漠东南缘雅布赖山和南缘的黑山头山地降水的补给,而来自祁连山区来水补给的可能性很小。     

Hydrochemical regime of saline lakes in the Southeastern Transbaikalia

Results from hydrochemical investigations into macrocomponent composition of some of the lakes in the Southeastern Transbaikalia are presented. The region's saline lakes, as a rule, are soda-chloride or chloride-soda lakes according to their chemical composition. The lakes hydrochemistry is determined by a combination of evaporative concentration of salt composition, intra-water body hydrobiological processes, especially by the production of organic matter and reduction of sulfates as well as by hydrogenic sedimentation.     

青藏高原冰湖研究进展及趋势

冰湖是由于冰川活动或者退缩产生的融水在冰川前部或者侧部汇集而成的,可分为冰川终碛湖(冰碛阻塞湖)、冰川阻塞湖、冰斗湖和冰蚀槽谷湖。其中分布数量较多、规模较大,且灾害风险较高的是冰川终碛湖。因此,冰川终碛湖是研究冰湖的主要对象。受全球气候变暖的影响,冰湖溃决产生的洪水、泥石流等重大冰川灾害的发生频率有所升高,灾害的影响程度以及范围也有所加大,引起了冰川山地国家的广泛关注。青藏高原内部发育着36793条现代冰川,冰川面积49873.44km2,分别占中国冰川总条数、总面积和冰储量的79.5%、84%和81.6%。在全球气候变暖的大背景下,多数冰川呈加速消融及退缩的态势,导致了冰湖溃决洪水和冰川泥石流等重大冰川灾害发生频率的加剧和影响程度的加大。本文围绕冰湖溃决条件、冰湖稳定性评价、冰湖溃决洪水模拟等几个研究方面,对青藏高原冰湖研究的现状及进展进行了较为系统的总结,并对未来研究趋势进行了展望。     

青藏高原湖泊Mg~(2+)、Ca~(2+)和Mg/Ca盐度指示意义的初步分析

总结了青藏高原地区400多个湖泊湖水的Mg2+、Ca2+和Mg/Ca等水化指标与湖水盐度的相关关系,以及这种关系随着湖水变化(不同采样时间和采样点以及自然蒸发)而产生的变化规律.结果表明:青藏高原湖泊湖水的Mg2+浓度与盐度具有较为稳定的正相关关系,而Ca2+和Mg/Ca与盐度的相关性较弱.在对于某一特定水化学类型的湖泊,一般碳酸盐型湖泊的Mg2+、Ca2+以及Mg/Ca等指标与盐度均没有明显的相关性;硫酸盐型湖泊中Mg2+浓度和盐度呈现较高的正相关关系,而Ca2+以及Mg/Ca与盐度的相关性仍很弱;而在氯化物型湖泊中,Mg2+浓度与盐度呈更高的正相关性,Ca2+浓度也与盐度呈一定的正相关性,Mg/Ca这一指标与盐度的相关性依然很弱.而对某一特定湖泊,在不同演化阶段或不同的采样地点,Mg2+浓度与盐度仍然保持明显的正相关关系,而Ca2+以及Mg/Ca与盐度的相关性仍然不稳定或很弱.在青藏高原作古环境重建应用的时候,湖水Mg2+浓度是古盐度一个较好的转换指标,而Ca2+以及Mg/Ca的古盐度指示意义相对较弱.     

The climate background and synoptic situation of fog at Great Wall Station, Antarctica

Based on the observed and NCEP reanalysis data from 1985 to 2006,the climate background and synoptic situation of fog at Great Wall Station were analyzed. It is shown that the seasonal variation of fog is controlled by the change of general circulation and local pressure field. Three favorable typical synoptic situations for fog development are found, the Front-of-A-Depression type, the Saddle-Shaped-Field type and the Passing-Weak-Cyclone type. The first one is the most important situation. Advection cooling fog is dominant at Great Wall Station, but there are other kinds of fog as well. As a result, some helpful principles for local fog forecasting are given.     

南极长城站区土壤重金属含量特征及来源分析

频繁的人类活动对南极生态环境的影响越来越受到关注,在南极长城站周边人类活动密集区对土壤进行采样的基础上,分析长城站周边地区表层土壤中重金属含量特征,并结合近20年来长城站周边土壤中主要重金属含量的分布,展开对比研究,探讨长城站区主要重金属元素的来源。结果表明,8种主要重金属在长城站表层土壤中都有不同程度的富集,站区频繁的车辆活动使得汽车尾气排放及汽车轮胎磨损产生大量含重金属的有害气体和粉尘,这些物质沉降在站区土壤表层或许是南极长城站区土壤重金属富集的重要原因之一。