Kinetic study of the hydrocarbon generation from Upper Paleozoic coals in Ordos Basin

When organic matter during geological processes is affected by a variety of factors such as paleotemperature, and time, complicated chemical reactions will occur, finally resulting in the generation of petroleum and natural gas. These reactions leading to…     

生烃动力学、同位素动力学方法在烃源岩研究中的应用

生烃动力学、同位素动力学常用于烃源岩评价、油气源对比研究中。生烃动力学参数结合盆地热史,可恢复烃源岩在任一时代的生烃史,对构造复杂盆地的二次生烃研究具有独特的优势。利用生烃动力学方法可以实现有机质总量的恢复,在此基础上对高—过成熟样品原始有机质丰度是否有必要恢复进行了讨论;而基于生烃动力学的油气源对比综合考虑热史、成藏期次、成藏过程等各种地质参数对烃源岩生烃的影响,是一种动态的研究方法。     

二连盆地侏罗系地层热演化史研究

本文应用磷灰石裂变径迹,镜质体动力学模型等方法恢复二连盆地侏罗系地层的热演化史,二连盆地图参１井磷灰石退火浓度为１６００－２７７４ｍ,对应的退火温度为６４－１０２．７℃,图参１井现今温度小于最高古地温,这是由于二连盆地地温梯度逐渐降低及地层发生抬升和剥蚀所致。根据磷灰石裂变径迹分析和镜质体动力学模型模拟图参１井的热演化史,在晚侏罗世时其经受的最高地温梯度分别为７℃／ｈｍ和６℃／ｈｍ。侏罗系地层在晚     

河西内陆河春季流量变化特征的分析和预测

利用昌马、莺落峡、九条岭３个水文站四十余年的月平均流量资料,分析河西地区３条主要内陆河春季流量的长期变化特征,并用均生函数模型对流量进行了预报,为河西地区水资源的研究和利用提供参考依据     

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H2O

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.     

丁二酸桥联双核铜Cu(C_3N_2H_4)_2(C_4H_5O_4)_2晶体的超分子结构及形貌特征

用XRD,SEM和TEM研究新型配合物Cu(C3N2H4)2(C4H5O4)2的超分子结构和微观形貌,并对新型晶体的平衡外形进行模拟计算,结果表明:该配合物分子具有丁二酸桥联的双核铜结构,中心铜离子处在2个咪唑和4个丁二酸以单齿配位组成的八面体中心,在ab平面,分子中有十四元大环,环内Cu(1)-Cu(2)原子间距为0.8031nm,C(2)-C(2′)为0.4183nm;在ac平面,沿着[010]方向分子内呈现凹的六边形纳米级孔洞;沿[100]方向分子依靠弱的氢键作用,层状堆积成三维超分子结构。此外,随着丁二酸的碳链沿[001]方向无限延伸,形成以铜离子为交叉中心的带状拓扑构型。SEM观察到晶体表面形成有明显的凹坑,区域呈现层状阶梯,说明晶体在(100)面遵照台阶-扭折模型呈层状生长结晶。TEM微区形貌像显示晶体存在条纹和缺陷结构,整体保持柱状构型,这与模拟的晶体平衡外形呈柱状一致。模拟结果表明晶体最易外显晶面为(100)面,外显比例达41.247%,这与晶体超分子层沿[100]方向通过氢键作用堆积,键作用力较弱密切相关。     

主流海表风场资料在舟山群岛近海的性能评估

再分析风场资料已广泛应用于我国舟山群岛海域可再生能源评估、海洋灾害预防决策以及港口运维和船舶运输等涉海发展领域,然而不同业务机构所提供的再分析数据在舟山近海的性能表现不一,严重阻碍了此类数据的有效应用。基于2018年全年单点浮标观测资料,综合评价了舟山群岛近海面(10 m)风场的长期变化趋势,并利用误差分析和风玫瑰图等统计工具对6种主流海表风场再分析资料,包括:ECMWF第五代全球大气再分析数据(the 5th generation ECMWF atmospheric reanalysis,ERA5)、NECP第二版全球高分辨率再分析数据(climate forecast system version 2,CFSv2)、美国宇航局物理海洋学分布存档中心的多卫星融合资料(cross-calibrated multi-platform,CCMP)、日本55年再分析数据(Japanese 55-year reanalysis,JRA-55)、第二版现代研究与应用回顾性分析数据(modern-era retrospective analysis for research and applications version 2,MERRA-2)和ECMWF哥白尼大气监测服务再分析数据(the Copernicus Atmosphere Monitoring Service,CAMS)在时间变化特征上进行了对比与评估。研究表明:在综合性能方面,ERA5对风场的再现能力最优,其次为JRA-55;在要素可信度方面,ERA5对风速的再现情况相对较优,而CFSv2的风向再现情况较好;风场产品在不同季节的模拟能力有所差异;不同风场产品在不同风速区间的重构能力也有所不同;在全年风向分布方面,各再分析资料都存在显著的东向偏差。研究结果为不同应用场景下风场资料的选取提供评估依据,并为进一步开发适用于舟山群岛近海的高精度长周期风场数据产品奠定基础。     

Lacustrine basin unconventional resource plays: Key differences

There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.     

准噶尔盆地陆东-五彩湾石炭系烃源岩特征及生烃动力学研究

准噶尔盆地陆东-五彩湾地区石炭系具有良好的勘探前景,该地区石炭系烃源岩有机质丰度较高,成熟度范围宽,主要处于成熟-高成熟演化阶段,主要由Ⅲ型有机质组成。在对烃源岩样品进行常规评价的基础上,用开放体系进行了热解实验和动力学模拟,对陆东-五彩湾地区的生烃特征进行了研究,尝试了高成熟烃源岩生烃过程研究及Ⅲ型干酪根液态烃排烃时间的估计,并对石炭系地层产烃率进行了计算。结果显示,陆东-五彩湾地区石炭系最早在二叠纪（距今264 Ma左右）开始生烃,后期由于地层抬升,在古近纪早期（距今61 Ma左右）结束生烃。下石炭统产烃率大,液态烃排出时间估计在距今232~196 Ma之间;上石炭统产烃率较小,液态烃排出时间估计在距今196~178 Ma 之间,但天然气生成相对较晚,有利于天然气的保存。天然气可能主要来源于上石炭统烃源岩。     

羟基磷灰石对水溶液中Fe3+的吸附动力学及热力学研究

研究了羟基磷灰石(HAP)对水溶液中Fe3+的吸附动力学及热力学。研究表明,HAP对水溶液中Fe3+的吸附符合Langmiur等温吸附,ct/q=0.006 4 ct+0.018 3;该吸附反应符合一级反应动力学方程,ln CR=-0.043 5 t+4.324 4;吸附反应活化能为Ea=36.26 k J/mol;标准摩尔反应焓为正值表明反应过程吸热;当温度大于285.7 K时,吉布斯自由能小于0,反应可自发进行。