4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Responses of CO2 in surface water in subtropical West Pacific to El Niño event

In order to investigate the relationships between the change of TCO2, △PCO2 and SST, current, upwelling and biological activities during El Nin(～)o event in the subtropical Pacific, the responses of TCO2 and △PCO2 in surface water in the subtropical Pacific during El Nin(～)o and La Nina have been simulated using a three-dimension carbon cycle model with biota pump. The results of numerical simulations show that TCO2 in sea water increases with reducing of SST during mature phase of El Nin(～)o in the subtropical West Pacific . At the same period , the Kuroshio in this region was weakened , the zonal currents were divergence , the upwelling carried the water with high concentrations of CO2 to the sea surface , so both of TCO2 and △PCO2 in surface water were increased . But TCO2 and △pCO2 were decreased during La Nina period. These simulated results confirmed the observations in 1982/1983 , 1986/1987 ,1991/1995 and 1997/1998 El Nin(～)o events .     

二三维联动的虚拟校园设计与实现

传统的2维地理信息系统技术成熟但缺乏3维可视化和分析的能力,而目前的3维地理信息系统发展可拥有3维可视化分析能力,然而还缺少2维地理信息系统的便捷。以二三维联动为开发思路的地理信息系统能够解决这对矛盾。本文基于二三维联动GIS的设计方案,以虚拟校园设计与实现为应用实例,利用ArcEngine（AE）实现二三维联动GIS系统的开发设计,对GIS系统的开发做出了一种新的、有益的尝试。     

Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.     

Structural evolution of the Bayanhongor region, west-central Mongolia

Most of previous models suggest that the Central Asia Orogenic Belt grew southward in the Phanerozoic. However, in the Bayanhongor region in west-central Mongolia, volcanic arc, accretionary prism, ophiolite, and passive margin complexes accreted northeastward away from the Baydrag micro-continent, and hence the region constitutes the southwestern part of a crustal-scale syntaxis close to the west. The syntaxis should be original, because presumably reorientation due to strike-slip faulting can be ignored. It is reconfirmed that the Baydrag eventually collided with another micro-continent (the Hangai) to the northeast. A thick sedimentary basin developed along the southern passive margin of the Hangai micro-continent. This region is also characterized by an exhumed metamorphosed accretionary complex and a passive margin complex, which are both bounded by detachment faults as well as basal reverse faults which formed simultaneously as extrusion wedges. This part of the Central Asia Orogenic Belt lacks exhumed crystalline rocks as observed in the Himalayas and other major collisional orogenic belts. In addition, we identified two phases of deformation, which occurred at each phase of zonal accretion as D1 through Cambrian and Devonian, and a synchronous phase of final micro-continental collision of Devonian as D2. The pre-collisional ocean was wide enough to be characterized by a mid-ocean ridge and ocean islands. Two different structural trends of D1 and D2 are observed in accretionary complexes formed to the southwest of the late Cambrian mid-ocean ridge. That is, the relative plate motions on both sides of the mid-ocean ridge were different. Accretionary complexes and passive margin sediments to the northeast of the mid-ocean ridge also experienced two periods of deformation but show the same structural trend. Unmetamorphosed cover sediments on the accretionary prism and on the Hangai micro-continent experienced only the D2 event due to micro-continental collision. These unmetamorphosed sediments form the hanging walls of the detachment faults. Moreover, they were at least partly derived from an active volcanic arc formed at the margin of the Baydrag micro-continent.     

Comparison of numerical models of two debris flows in the Cortina d’ Ampezzo area,Dolomites, Italy

The accurate prediction of runout distances, velocities and the knowledge of flow rheology can reduce the casualties and property damage produced by debris flows, providing a means to delineate hazard areas, to estimate hazard intensities for input into risk studies and to provide parameters for the design of protective measures. The application of most of models that describe the propagation and deposition of debris flow requires detailed topography, rheological and hydrological data that are not always available for the debris-flow hazard delineation and estimation. In the Cortina d’Ampezzo area, Eastern Dolomites, Italy, most of the slope instabilities are represented by debris flows; 325 debris-flow prone watersheds have been mapped in the geomorphological hazard map of this area. We compared the results of simulations of two well-documented debris flows in the Cortina d’Ampezzo area, carried on with two different single-phase, non-Newtonian models, the one-dimensional DAN-W and the two-dimensional FLO-2D, to test the possibility to simulate the dynamic behaviour of a debris flow with a model using a limited range of input parameters. FLO-2D model creates a more accurate representation of the hazard area in terms of flooded area, but the results in terms of runout distances and deposits thickness are similar to DAN-W results. Using DAN-W, the most appropriate rheology to describe the debris-flow behaviour is the Voellmy model. When detailed topographical, rheological and hydrological data are not available, DAN-W, which requires less detailed data, is a valuable tool to predict debris-flow hazard. Parameters obtained through back-analysis with both models can be applied to predict hazard in other areas characterized by similar geology, morphology and climate.     

测井仪器的故障分析与排除思路

TYSC-3Q与PSJ-2型数字测井仪是目前煤田测井中常用的二种测井仪器,在使用过程中难免发生诸如测井控制故障、声速探管故障、密度三侧向探管故障、井温、井液电阻率探管故障、电法面板故障、数字测井面板故障、电测井故障等常见故障类型。通过对各类故障因素进行剖析,指出了故障易发生的部位,并详细的介绍了检查的方法及故障的排除步骤。     

Wind variability in intermediate luminosity B supergiants

We discuss wind variability in intermediate luminosity B supergiants. Because these are not the hottest, most luminous or just about other kind of -est stars, they have not attracted much attention. However, since their wind lines are well-developed, but unsaturated, they make ideal diagnostics for time dependent wind studies. We show that their wind profiles undergo large scale variability and that this phenomenon is quite common. We also discuss a time series for the B0.5 Ib HD 64760 which suggests the long sought after connection between wind and photospheric activity. Newly developed analysis techniques needed to extract physical information from the wind lines are discussed, and results are applied to the time series.