The permeability of faults within siliciclastic petroleum reservoirs of the North Sea and Norwegian Continental Shelf

Faulting in Middle Jurassic reservoirs occurred at shallow depth during regional extension. Clean sandstones (<15% clay) deformed without significant grain fracturing and permeability reduction. Faults in impure sandstones (15–40% clay) experienced significant syn-deformation compaction and permeability reduction. Enhanced compaction during deeper burial reduced their permeabilities further from an average of 0.05 mD at <2.5 km to 0.001 mD at >4 km. Clay-rich sediments (>40% clay) deformed to produce clay smears with very low permeabilities (<0.001 mD). Faulting in the Rotliegendes occurred at greater depth during both basin extension and inversion. Extensional faulting produced cataclasites with permeability reductions of <10–>10⁶; their permeabilities range from 0.2 to 0.0001 mD and are inversely related to their maximum burial depth. Faults formed or reactivated during inversion experienced permeability increase. These results can be extrapolated to other hydrocarbon reservoirs if differences in stress and temperature history are taken into account.The permeability of most (>80%) faults is not sufficiently low, compared to their wallrock, to retard single-phase fluid flow on a km-scale. Nevertheless, most faults could retard the flow of a non-wetting phase if present at low saturations. It may be necessary to incorporate the two-phase fluid flow properties of fault rocks into reservoir simulators using upscaling or pseudoisation techniques. Fault property data should be calibrated against production data before it can be used confidently.     

造山带异源浆混花岗岩理论与方法研究

1：5万花岗岩填图方法在区调工作中推广以来,在造山带花岗岩调查实践中,由于造山作用及过程的复杂性,花岗岩浆的多源及多样性,使同源岩浆演化理论及方法遇到了难题。文章在新一轮1：25万造山带试点图幅,在对同源岩浆演化理论及方法的适用性进行探索的同时,提出了异源浆混理论指导造山带内部浆混花岗岩（H型花岗岩）的填图方法。并就异源浆混花岗岩鉴别标志等作了系统总结,提出了浆混组合、浆混单元、浆混体,填图的理论方法体系;给予了浆混花岗岩明确的定义。     

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。     

Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.     

New data on the present-day active fluid regime of fractured zones of crystalline basement and sedimentary cover in the eastern part of Volga-Ural region

The study area is the South Tatarstan Arch located in the Volgo-Ural Region, which is an enigmatic crustal segment occupying one third of the East European Platform. Monitoring studies have shown that fluid discharge processes are still active and time-dependent. This paper presents an integrated review of the geological, geophysical, hydrochemical and geochemical studies of the crystalline basement of Tatarstan. These studies are based on the stratigraphic and compositional schemes within the crystalline basement, the drilling of deep wells, the geodynamic activity of the fractured zones of the crystalline basement and the presence of fluids therein. Furthermore, the changes in the chemical composition of the basement waters are taken into account.     

Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.     

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.     

Postcollisional flow of aqueous fluid within ultrahigh-pressure eclogite in the Dabie orogen

A combined study of chronometric dating and oxygen isotope analysis for minerals from vein and host eclogite as well as regional country-rock gneiss in the Dabie orogen provides a direct constraint on timing of fluid flow in this orogen formed by continental collision. Oxygen isotope ratios of vein minerals are significantly lower than those of the host eclogite, but comparable with those of the regional gneiss. This suggests the veining fluid came from the regional gneiss (i.e. exhumed slab itself) rather than the host eclogite. While zircon U–Pb and phengite Ar–Ar dating yields ages of 214 to 222 Ma for the eclogite and gneiss, the vein gives a quartz–muscovite Rb–Sr isochron age of 181 Ma and a muscovite K–Ar age of 179 Ma. Thus the veining postdates the Triassic ultrahigh pressure metamorphic event, witnessing postcollisional fluid flow after the orogenic cycle of continental collision.     

Tectonically driven fluid flow and associated low-grade metamorphism during the Alpine compression in the eastern Iberian Chain (Spain)

Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation.     

Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.