Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.     

Pressure prediction in the Bullwinkle Basin through petrophysics and flow modeling (Green Canyon 65, Gulf of Mexico)

Reservoir pressures within the Bullwinkle minibasin (Green Canyon 65, Gulf of Mexico continental slope) increase at a hydrostatic gradient whereas pressures predicted from porosity within mudstones bounding these reservoirs increase at a lithostatic gradient: they are equal at a depth 1/3 of the way down from the crest of the structure. Two- and three-dimensional steady-state flow models demonstrate that bowl-shaped structures will have lower pressures than equivalent two-dimensional structures and that if a low permeability salt layer underlies the basin, the pressure is reduced. We conclude that at Bullwinkle, pressure is reduced due to an underlying salt body and the bowl-shape of the basin. A geometric approach to predict sandstone pressure is to assume that the reservoir pressure equals the area-weighted average of the mudstone pressure. When the mudstone pressure gradient is constant, as at Bullwinkle, the reservoir pressure equals the mudstone pressure at the average depth (centroid) of the reservoir.     

Long-range underwater photography in the deep ocean

Although the optical properties of seawater at extreme depths are more suitable for underwater photography than those at the surface or on continental shelves, they still impose severe limitations on long-range wide area bottom photography. Additionally, deep ocean operations impose technical limitations on control, power and bandwidth. This chapter reviews the approaches contemplated or made towards improving the camerato-target range in underwater photography in the deep ocean. Further significant improvements await advances in control, power/light sources and bandwidth reduction. With the developments now contemplated, TV and video systems will eventually present a strong challenge to emulsion film techniques.     

Applied hydrodynamic wave-resistance computation by Fourier transform

An applied Fourier transform computation for the hydrodynamic wave-resistance coefficient is shown, oriented to potential flows with a free surface and infinity depth. The presence of a ship-like body is simulated by its equivalent pressure disturbance imposed on the un-perturbed free surface, where a linearized free surface condition is used. The wave-resistance coefficient is obtained from the wave-height downstream. Two examples with closed solutions are considered: a submerged dipole, as a test-case, and a parabolic pressure distribution of compact support. In the three dimensional case, a dispersion relation is included which is a key resource for an inexpensive computation of the wave pattern far downstream like fifteen ship-lengths.     

Design of a 3D Chirp Sub-bottom Imaging System

Chirp sub-bottom profilers are marine acoustic devices that use a known and repeatable source signature (1–24 kHz) to produce decimetre vertical resolution cross-sections of the sub-seabed. Here the design and development of the first true 3D Chirp system is described. When developing the design, critical factors that had to be considered included spatial aliasing, and precise positioning of sources and receivers. Full 3D numerical modelling of the combined source and receiver directivity was completed to determine optimal source and receiver geometries. The design incorporates four source transducers (1.5–13 kHz) that can be arranged into different configurations, including Maltese Cross, a square and two separated pairs. The receive array comprises 240 hydrophones in 60 groups whose group-centres are separated by 25 cm in both horizontal directions, with each hydrophone group containing four individual elements and a pre-amplifier. After careful consideration, it was concluded that the only way to determine with sufficient accuracy the source–receiver geometry, was to fix the sources and receivers within a rigid array. Positional information for the array is given by a Real Time Kinematic GPS and attitude system incorporating four antennas to give position, heading, pitch and roll. It is shown that this system offers vertical positioning accuracy with a root-mean-square (rms) error less than 2.6 cm, while the horizontal positioning rms error was less than 2.0 cm. The system is configured so that the Chirp source signature can be chosen by software aboard the acquisition vessel. The complete system is described and initial navigational and seismic data results are presented. These data demonstrate that the approach of using fixed source-receiver geometry combined with RTK navigation can provide complete 3D imaging of the sub-surface.     

The permeability of faults within siliciclastic petroleum reservoirs of the North Sea and Norwegian Continental Shelf

Faulting in Middle Jurassic reservoirs occurred at shallow depth during regional extension. Clean sandstones (<15% clay) deformed without significant grain fracturing and permeability reduction. Faults in impure sandstones (15–40% clay) experienced significant syn-deformation compaction and permeability reduction. Enhanced compaction during deeper burial reduced their permeabilities further from an average of 0.05 mD at <2.5 km to 0.001 mD at >4 km. Clay-rich sediments (>40% clay) deformed to produce clay smears with very low permeabilities (<0.001 mD). Faulting in the Rotliegendes occurred at greater depth during both basin extension and inversion. Extensional faulting produced cataclasites with permeability reductions of <10–>10⁶; their permeabilities range from 0.2 to 0.0001 mD and are inversely related to their maximum burial depth. Faults formed or reactivated during inversion experienced permeability increase. These results can be extrapolated to other hydrocarbon reservoirs if differences in stress and temperature history are taken into account.The permeability of most (>80%) faults is not sufficiently low, compared to their wallrock, to retard single-phase fluid flow on a km-scale. Nevertheless, most faults could retard the flow of a non-wetting phase if present at low saturations. It may be necessary to incorporate the two-phase fluid flow properties of fault rocks into reservoir simulators using upscaling or pseudoisation techniques. Fault property data should be calibrated against production data before it can be used confidently.     

造山带异源浆混花岗岩理论与方法研究

1：5万花岗岩填图方法在区调工作中推广以来,在造山带花岗岩调查实践中,由于造山作用及过程的复杂性,花岗岩浆的多源及多样性,使同源岩浆演化理论及方法遇到了难题。文章在新一轮1：25万造山带试点图幅,在对同源岩浆演化理论及方法的适用性进行探索的同时,提出了异源浆混理论指导造山带内部浆混花岗岩（H型花岗岩）的填图方法。并就异源浆混花岗岩鉴别标志等作了系统总结,提出了浆混组合、浆混单元、浆混体,填图的理论方法体系;给予了浆混花岗岩明确的定义。     

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。     

Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.