运用H、O同位素资料分析地下热水的补给来源——以鲁西北阳谷-齐河凸起为例

通过对阳谷-齐河凸起地下热水的化学成分、同位素及其地热地质条件的分析,对这一地区的地下热水的补给来源进行了研究。本区地下热水的δD为-65‰～-80.67‰,δ18O为-9.2‰～-10.2‰,均分布在全球雨水线的附近,说明该区地下热水主要为大气降水成因。济南北地热田地下热水的补给高程为256m,此范围大致相当于济南南部山区及其以南的泰山北麓;聊城东地热田地下热水的补给高程为411m,此范围大致相当于泰山山脉及其周边的中山区。聊城东地热田地下热水的2H过量参数d明显低于济南北地热田,说明聊城东地热田地下热水的补给区比后者更远。     

北冰洋西部表层沉积物矿物学特征及其物质来源

对北冰洋西部79个表层沉积物样品进行了全岩X射线衍射矿物组成分析,结合洋流和地质背景,探讨各矿物分区的物质来源。矿物组合分区表明研究区物质来源变化较为复杂:(1)在楚科奇海的中部靠近白令海峡处长石含量很高,主要是阿纳德尔流携带的来自阿纳德尔河的沉积物;在楚科奇海的西侧的长石含量也较高,且与其他矿物组合分区相比,角闪石含量较高,这是因为受阿纳德尔流和东西伯利亚沿岸流的双重影响,沉积物来自西伯利亚陆地的一些高含长石的火山岩及沉积岩等。在楚科奇海的东侧,石英含量很高,来源为阿拉斯加沿岸流携带的育空河及卡斯奎姆河的沉积物。在阿拉斯加北部,碳酸盐岩和石英含量高,这与马更些河搬运的沉积物有关;(2)北冰洋西部深水区中加拿大海盆的南端和中部方解石和白云石的含量较低,说明受波弗特环流携带的加拿大北极群岛的碳酸盐影响相对较小,且与其他矿物组合分区相比,云母含量最高,说明沉积物主要来源为来自拉普捷夫海的海冰沉积物;此外,一些黏土级细粒物质可能由大西洋中层水携带而来。深水区的其他海域以方解石和白云石含量高为特点,主要受波弗特环流的影响,来源主要为加拿大北极群岛的班克斯岛和维多利亚岛;此外,还受来自西伯利亚陆架,主要是拉普捷夫海沉积物的影响。     

基于ECDIS的多数据源支持技术分析

利用多源地理空间数据集成和融合理论,研究了基于ECDIS的多数据源支持技术。介绍了常用的多源海图数据及其使用原则,分析了ECDIS多数据源支持技术的特点及内涵,总结了国内外常用多源海图数据集成方法,从数据可用性角度探讨了提高国产电子海图系统适用性的措施。     

Mud volcanism and fluid geochemistry in the Cheleken peninsula,western Turkmenistan

A geological and geochemical study has been carried out to investigate the relationships between major mud volcano structures and deep fluid migration in the Cheleken peninsula, in the South Caspian Basin. The fluid geochemistry allowed the origin and migration of the saline waters and the hydrocarbons to be deduced along with the regional source and reservoir rocks. The emitted waters formed by the mixing of deep highly saline water from the main source rocks of the Maykop Fm with the Caspian-like pore water contained in the Pliocene reservoirs. The water composition is very similar to that emitted by the mud volcanoes in Azerbaijan, allowing comparisons to be done between the reservoirs in the western and eastern sides of the South Caspian Basin. The associated oil is derived from a mixed type II/III kerogen deposited in a sub-oxic marine environment and generated during the early oil window. The oil biomarkers indicate that the source rock is the Maykop Fm., as previously determined for the other areas of the South Caspian Basin.The spontaneous emissions, showing different morphologies, are mainly aligned along normal and transtensive fault systems, which provide effective pathways for rapid fluid ascent from deep reservoirs to the surface.     

桑沟湾及附近海域表层沉积物碳氮同位素分析及有机质来源

Naturally existing stable carbon and nitrogen isotopes are important in the study of sedimentary organic matter sources. To identify the sources of sedimentary organic matter in Sanggou Bay and its adjacent areas, which is characterized by high-density shellfish and seaweed aquaculture, the grain size, organic carbon(OC), total nitrogen(TN), carbon and nitrogen isotopic composition(δ13C and δ15N) of organic matter in the surface sediment were determined. The results showed that, in August, sedimentary OC and TN ranged from 0.17% to 0.76% and 0.04% to 0.14%, respectively. In November, OC and TN ranged from 0.23% to 0.87% and 0.05% to 0.14%, respectively. There was a significant positive correlation between OC and TN(R=0.98, P0.0001), indicating that OC and TN were homologous. In August, the δ13C and δ15N of organic matter varied from-23.06‰ to-21.59‰ and 5.10‰ to 6.31‰, respectively. In November, δ13C and δ15N ranged from-22.87‰ to-21.34‰ and 5.13‰ to 7.31‰, respectively. This study found that the major sources of sedimentary organic matter were marine shellfish biodeposition, seaweed farming, and soil organic matter. Using a three-end-member mixed model, we estimated that the dominant source of sedimentary organic matter was shellfish biodeposition, with an average contribution rate of 65.53% in August and 43.00% in November. Thus, shellfish farming had a significant influence on the coastal carbon cycle.     

荣成天鹅湖越冬大天鹅粪便的重金属水平

为对大天鹅(Cygnus cygnus)保护及湖区管理提供基础数据,作者于2011年11月~2012年3月研究了山东荣成天鹅湖越冬大天鹅食物来源及其粪便的重金属水平。结果表明:所选择的食物来源中,Zn、As和Cr在硬毛藻(Chaetomorpha linum)中含量最高,Cd在大叶藻(Zostera marina L.)叶片中含量最高,Pb在大叶藻根茎中含量最高,Cu在石莼(Ulva pertusa)中含量最高,Hg在小麦(Triticum aestivum)中含量最高;水生植物来源的粪便中Cd含量极显著高于陆地植物来源的粪便,陆地植物来源的粪便中Cr,Pb和Hg含量显著高于水生植物来源的粪便;摄食小麦苗可能造成大天鹅对Cd和Hg的积累。     

Geochronology and fluid inclusion study of the Yinjiagou porphyry–skarn Mo–Cu–pyrite deposit in the East Qinling orogenic belt,China

The Yinjiagou Mo–Cu–pyrite deposit of Henan Province is located in the Huaxiong block on the southern margin of the North China craton. It differs from other Mo deposits in the East Qingling area because of its large pyrite resource and complex associated elements. The deposit’s mineralization process can be divided into skarn, sulfide, and supergene episodes with five stages, marking formation of magnetite in the skarn episode, quartz–molybdenite, quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite, and calcite–galena–sphalerite in the sulfide episode, and chalcedony–limonite in the supergene episode. Re–Os and ⁴⁰Ar–³⁹Ar dating indicates that both the skarn-type and porphyry-type orebodies of the Yinjiagou deposit formed approximately 143 Ma ago during the Early Cretaceous. Four types of fluid inclusions (FIs) have been distinguished in quartz phenocryst, various quartz veins, and calcite vein. Based on petrographic observations and microthermometric criteria the FIs include liquid-rich, gas-rich, H₂O–CO₂, and daughter mineral-bearing inclusions. The homogenization temperature of FIs in quartz phenocrysts of K-feldspar granite porphyry ranges from 341 °C to >550 °C, and the salinity is 0.4–44.0 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite veins is 382–416 °C, and the salinity is 3.6–40.8 wt% NaCl eqv. The homogenization temperature of FIs in quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite ranges from 318 °C to 436 °C, and the salinity is 5.6–42.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite stockworks is in a range of 321–411 °C, and the salinity is 6.3–16.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–sericite–pyrite is in a range of 326–419 °C, and the salinity is 4.7–49.4 wt% NaCl eqv. The ore-forming fluids of the Yinjiagou deposit are mainly high-temperature, high-salinity fluids, generally with affinities to an H₂O–NaCl–KCl ± CO₂ system. The δ¹⁸O_H2O values of ore-forming hydrothermal fluids are 4.0–8.6‰, and the δD_V-SMOW values are between −64‰ and −52‰, indicating that the ore-forming fluids were primarily magmatic. The δ³⁴S_V-CDT values of sulfides range between −0.2‰ and 6.3‰ with a mean of 1.6‰, sharing similar features with deeply sourced sulfur, implying that the sulfur mainly came from the lower crust composed of poorly differentiated igneous materials, but part of the heavy sulfur came from the Guandaokou Group dolostone. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb values of sulfides are in the range of 17.331–18.043, 15.444–15.575, and 37.783–38.236, respectively, which is generally consistent with the Pb isotopic signature of the Yinjiagou intrusion, suggesting that the Pb chiefly originated from the felsic–intermediate intrusive rocks in the mine area, with a small amount of lead from strata. The Yinjiagou deposit is a porphyry–skarn deposit formed during the Mesozoic transition of a tectonic regime that is EW-trending to NNE-trending, and the multiepisode boiling of ore-forming fluids was the primary mechanism for mineral deposition.     

Jump conditions and dynamic surface tension at permeable interfaces such as the inner core boundary

We consider a fluid crossing a zone of rapid density change, so thin that it can be considered as a density jump interface. In this case, the normal velocity undergoes a jump. For a Newtonian viscous fluid with low Reynolds number (creeping flow) that keeps its rheological properties within the interface, we show that this implies that the traction cannot be continuous across the density jump because the tangential stress is singular. The appropriate jump conditions are established by using the calculus of distributions, taking into account the curvature of the interface as well as the density and viscosity changes. Independently of any intrinsic surface tension, a dynamic surface tension appears and turns out to be proportional to the mass transfer across the interface and to a coefficient related to the variations of density and viscosity within the interface. Explicit solutions are exhibited to illustrate the importance of these new jump conditions. The example of the Earth's inner core crystallisation is questioned.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

Complex vein systems as a data source in tectonics: An example from the Ugab Valley,NW Namibia

Neoproterozoic metaturbidites in the Lower Ugab Domain, Namibia, contain a complex network of four sets of quartz-calcite veins, overprinted by km-scale folds associated with four regional foliations. The veins formed by fluid overpressure predating the main deformation. Deformation structures developed at the junction of two mobile belts during the assembly of Gondwana, the NS Kaoko Belt, and the EW trending Damara Belt. Km-scale NS trending folds were initiated during EW constriction in the Kaoko Belt, while their further development and all subsequent events are related to constriction in the EW-Damara Belt, with coeval sinistral strike slip in the Kaoko Belt. Deformation of the veins, and development of four orthogonal foliations are due to gradual changes in the bulk tectonic framework rather than separate orogenic events. The veins are deformed in a complex manner allowing a full 3D reconstruction of regional sequence of events. The local complex tectonics could be reconstructed because of the perfect local exposure and the multitude of veins: it illustrates the potential complexity of tectonic events and structural evolution in apparently simple slate belts.