The morphologies and genesis of mega-pockmarks near the Xisha Uplift, South China Sea

Pockmarks are normally regarded to be manifestations of fluids escape through the seabed. Kilometer-wide depressions, here called mega-pockmarks occur as widespread features near the Xisha Uplift, northern South China Sea. Most of the pockmarks observed in this area are multi-kilometers and much larger than normal-pockmarks reported worldwide. The maximum diameter observed is 3210 m and the maximum depth observed is 165.2 m based on multibeam data and 2D seismic data. The pockmarks are circular, elliptical and crescentic in plan view. Seismic profiles show that the genesis of pockmarks is related to fluid (gas and/or pore water) escape. According to the fluids pathways, the pockmarks fall into four types: (1) gas chimney-related; (2) depositional boundary-related; (3) gas chimney and inclined structure (fault)-related; (4) inclined structure-related. Bottom currents are strong and complex in the study area. The multibeam data and seismic profiles indicate that they may play an important role on extension, maintenance and shaping of pockmarks. The research of the study area is in its initial stage, and the identification of these features as indicators of fluid flow is probably useful for hydrocarbon exploration.     

Fault system and thermal regime in the vicinity of site NGHP-01-10, Krishna–Godavari basin, Bay of Bengal

Drilling/coring activities onboard JOIDES Resolution for hydrate resource estimation have confirmed gas hydrate in the continental slope of Krishna-Godavari (KG) basin, Bay of Bengal and the expedition recovered fracture filled gas hydrate at the site NGHP-01-10. In this paper we analyze high resolution multi-channel seismic (MCS), high resolution sparker (HRS), bathymetry, and sub-bottom profiler data in the vicinity of site NGHP-01-10 to understand the fault system and thermal regime. We interpreted the large-scale fault system (>5 km) predominantly oriented in NNW-SSE direction near NGHP-01-10 site, which plays an important role in gas hydrate formation and its distribution. The increase in interval velocity from the baseline velocity of 1600 m/s to 1750–1800 m/s within the gas hydrate stability zone (GHSZ) is considered as a proxy for the gas hydrate occurrence, whereas the drop in interval velocity to 1400 m/s suggest the presence of free gas below the GHSZ. The analysis of interval velocity suggests that the high concentration of gas hydrate occurs close to the large-scale fault system. We conclude that the gas hydrate concentration near site NGHP-01-10, and likely in the entire KG Basin, is controlled primarily by the faults and therefore has high spatial variability.We also estimated the heat flow and geothermal gradient (GTG) in the vicinity of NGHP-01-10 site using depth and temperature of the seafloor and the BSR. We observed an abnormal GTG increase from 38 °C/km to 45 °C/km at the top of the mound, which remarkably agrees with the measured temperature gradient at the mound (NGHP-01-10) and away from the mound (NGHP-01-03). We analyze various geological scenarios such as topography, salinity, thermal non-equilibrium of BSR and fluid/gas advection along the fault system to explain the observed increase in GTG. The geophysical data along with the coring results suggest that the fluid advection along the fault system is the primary mechanism that explains the increase in GTG. The approximate advective fluid flux estimated based on the thermal measurement is of the order of few tenths of mm/yr (0.37–0.6 mm/yr).     

Axisymmetric liquid block impact on a solid surface

The hydrodynamic problem of collision of an axisymmetric water block and solid boundary has been analyzed based on the velocity potential theory. The three dimensional axisymmetric hydrodynamic problem is converted to a quasi two dimensional one and is solved in axisymmetric coordinate system using the boundary element method. Numerical simulations are made for collision of a solid cone with a liquid cone or a spheroidal liquid block. The results in the former are compared with those obtained from similarity solution and excellent agreement is found. Numerical results are then presented for the collision between different solid cones and various spheroidal liquid blocks.     

40Ar/39Ar dating,fluid inclusions and S–Pb isotope systematics of the Shabaosi gold deposit,Heilongjiang Province,China

The Shabaosi deposit is the only large lode gold deposit in the northern Great Xing'an Range. The gold ore bodies are hosted by sandstone and siltstone of the Middle Jurassic Ershi'erzhan Formation, and are controlled by three N–S‐trending altered fracture zones. The gold ore bodies are composed of auriferous quartz veinlets and altered rocks. Fluid inclusion studies indicate that the ore‐forming fluids belong to a H₂O–NaCl–CO₂–CH₄ system, with salinities between 0.83 and 8.28 wt% NaCl eq., and homogenization temperatures ranging from 180 to 320 °C. The δ³⁴S values of sulphides show a large variation from −16.9‰ to 8.5‰. The Pb isotope compositions of sulphides are characterized by a narrow range of ratios: 18.289 to 18.517 for ²⁰⁶Pb/²⁰⁴Pb, 15.548 to 15.625 for ²⁰⁷Pb/²⁰⁴Pb, and 38.149 to 38.509 for ²⁰⁸Pb/²⁰⁴Pb. The μ values range from 9.36 to 9.51. These results suggest that the ore‐forming fluids/materials were mainly of magmatic hydrothermal origin, derived from magmas produced by partial melting of the lower crust. The ⁴⁰Ar/³⁹Ar age of auriferous quartz veinlets from the Shabaosi gold deposit is about 130 Ma. The Shabaosi gold deposit has counterparts in similar orogenic gold deposits, and was formed during the post‐collisional setting of the Mongolia–Okhotsk Orogen. Copyright © 2014 John Wiley & Sons, Ltd.     

Impact of wind on the spatial distribution of rain over micro‐scale topography: numerical modelling and experimental verification

The wind‐driven‐rain effect refers to the redistribution of rainfall over micro‐scale topography due to the existence of local perturbed wind‐flow patterns. Rainfall measurements reported in the literature point to the fact that the wind‐driven‐rain distribution can show large variations over micro‐scale topography. These variations should be taken into account in hillslope hydrology, in runoff and erosion studies and in the design of rainfall monitoring networks. In practice, measurements are often not suitable for determining the wind‐driven‐rain distribution. Therefore, a few researchers have employed numerical modelling. In order to provide confidence in using numerical models, experimental verification for a range of different topographic features is imperative. The objective of this study is to investigate the adequacy of a two‐dimensional Computational Fluid Dynamics (CFD) model to predict the wind‐driven‐rain distribution over small‐scale topography. The numerical model is applied to a number of topographic features, including a succession of cliffs, a small isolated hill, a small valley and a field with ridges and furrows. The numerical results are compared with the corresponding measurement results reported in the literature. It is shown that two‐dimensional numerical modelling can provide a good indication of the wind‐driven‐rain distribution over each type of micro‐scale topography that is considered in this study. It is concluded that more detailed verification procedures are currently inhibited due to the lack of available and detailed spatial and temporal rainfall data from field measurements. Copyright © 2005 John Wiley & Sons, Ltd.     

Role of fluids in migmatites: CO2-H2O fluid inclusions in leucosomes from the Deep Freeze Range migmatites (Terra Nova Bay, Antarctica)

ABSTRACT The metasedimentary sequence of the Deep Freeze Range (northern Victoria Land, Antarctica) experienced high-T/low-F metamorphism during the Cambro-Ordovician Ross orogeny. The reaction Bt + Sil + Qtz = Grt + Crd + Kfs + melt was responsible for the formation of migmatites. Peak conditions were c. 700–750° C, c. 3.5–5 kbar and x_H2Oc. 0.5). Distribution of fluid inclusions is controlled by host rock type: (1) CO₂-H₂O fluid inclusions occur only in graphite-free leucosomes; (2) CO₂–CH₄± H₂O fluid inclusions are the most common type in leucosomes, and in graphite-bearing mesosomes and gneiss; and (3) CO₂–N₂–CH₄ fluid inclusions are observed only in the gneiss, and subordinately in mesosomes. CO₂–H₂O mixtures (41% CO₂, 58% H₂O, 1% Nad mol.%) are interpreted as remnants of a synmig-matization fluid; their composition and density are compatible P–T–a_H2O conditions of migmatization (c. 750° C, c. 4 kbar, x_H2Oc. 0.5). CO₂-H₂O fluid in graphite-free leucosomes cannot originate via partial melting of graphite-bearing mesosomes in a closed system; this would have produced a mixed CO₂–CH₄ fluid in the leucosomes by a reaction such as Bt + Sil + Qtz + C ± H₂O = Grt + Crd + Kfs + L + CO₂+ CH₄. We conclude that an externally derived oxidizing CO₂-H₂O fluid was present in the middle crust and initiated anatexis. High-density CO₂-rich fluid with traces of CH₄ characterizes the retrograde evolution of these rocks at high temperatures and support isobaric cooling (P–T anticlockwise path). In unmigmatized gneiss, mixed CO₂–N₂–CH₄ fluid yields isochores compatible with peak metamorphic conditions (c. 700–750° C, c. 4–4.5 kbar); they may represent a peak metamorphic fluid that pre-dated the migmatization.     

Juvenile CO2 in enderbites of Tromøy near Arendal, southern Norway: a fluid inclusion and stable isotope study

The enderbites from Tromøy in the central, granulite facies part of the Proterozoic Bamble sector of southern Norway contain dominantly CO₂ and N₂ fluid inclusions. CO₂ from fluid inclusions in quartz segregations in enderbites was extracted by mechanical (crushing) and thermal decrepitation and the δ¹³C measured. Measurement was also made on samples washed in 10% HCl, oxidized with CuO at high temperatures, and step-wise extracted with progressive heating. Results between the different techniques are systematic. The main results show δ¹³C of -4.5±1.5% for crushing and -7±2% for thermal decrepitation. δ¹³C is about constant for CO₂ extracted at different temperatures and points to a homogeneous isotopic composition. Due to the presence of carbonate particles and/or induced contaminations for the extraction by thermal decrepitation, the results for the crushing experiments are assumed the most reliable for fluid-inclusion CO₂. Very low values of δ¹³C have not been found in enderbite samples and δ¹³C combined with δ¹⁸O of the host quartzes (8-11%) indicates juvenile values. In addition, the fluid inclusions were examined by microthermometry and Raman analysis and host quartz by acoustic emission and cathodoluminescence. CO₂ fluid inclusions have varying densities with a frequency maximum of 0.92 g cm^-3 and generally do not concur with trapping densities at granulite conditions. Textures show that CO₂ must have been trapped in fluid inclusions in one early event, but transformed to different extents during late isothermal uplift without important fractionation of isotope compositions. The present data support a model of intrusion and crystallization of a CO₂-rich enderbitic magma at granuiite conditions.     

Halogen contents of eclogite facies fluid inclusions and minerals: Caledonides,western Norway

Primary multiphase brine fluid inclusions in omphacite and garnet from low‐ to medium‐temperature eclogites have been analysed for Cl, Br, I, F, Li and SO₄. Halogen contents and ratios provide information about trapped lower crustal fluids, even though the major element (Na, K, Ca) contents of inclusion fluids have been modified by fluid–mineral interactions and (step‐) daughter‐crystal formation after trapping. Halogens in the inclusion fluids were analysed with crush–leach techniques. Cl/Br and Cl/I mass ratios of eclogite fluids are in the range 31–395 and 5000–33 000, respectively. Most fluids have a Cl/Br ratio lower than modern seawater and a Cl/I ratio one order of magnitude lower than modern seawater. Fluids with the lowest Cl/Br and highest Cl/I ratios come from an eclogite that formed by hydration of granulite facies rocks, and may indicate that Br and I are fractionated into hydrous minerals. Reconstructions indicate that the inclusion fluids originally contained 500–4000 ppm Br, 1–14 ppm I and 33–438 ppm Li. Electron microprobe analyses of eclogite facies amphibole, biotite, phengite and apatite indicate that F and Cl fractionate most strongly between phengite (F/Cl mass ratio of 1469 ± 1048) and fluid (F/Cl mass ratio of 0.008), and the least between amphibole and fluid. The chemical evolution of Cl and Br in pore fluids during hydration reactions is in many ways analogous to Cl and Br in seawater during evaporation: the Cl/Br ratio remains constant until the a_H2O value is sufficiently lowered for Cl to be removed from solution by incorporation into hydrous minerals.     

2020年新疆于田MS6.4地震温泉水文地球化学异常特征研究

2020年6月26日新疆于田县发生M_S6.4地震, 地震发生前后对震中80 km内的两个温泉在2019年9月至2020年10月的水文地球化学的变化特征进行了研究, 结果表明: ①温泉水的来源为其周围昆仑山的冰川融水, ②克孜勒沙衣温泉补给高程6 km, 水化学类型为Na-HCO₃、 部分平衡水、 温泉循环深度达到1.7 km左右, 其主要气体组分为N₂, 幔源氦占10.6%。 ③乌什开布隆温泉补给高程为3.1 km, Ca·Na-HCO₃·SO₄型, 未成熟水, 可能与浅层冷水发生了混合作用, 循环深度仅达到0.5 km, 该温泉的水化学组分对周围的地震活动有明显的异常响应, 伽师M_S6.4地震前, 区域应力的不断加载使断裂带内裂隙发生明显变化, 从而温泉流体行为发生变化, 使乌什开布隆温泉的离子浓度小幅度上升, 且Cl^-含量在于田M_S6.4地震后16天突增。 因此, 对乌什开布隆温泉及克孜勒沙衣温泉的流体地球化学特征进行连续监测, 可以为未来阿尔金断裂及西昆仑断裂的交会区地震危险性提供有效判断指标。     

油气成藏年代学研究进展及发展趋势

成藏年代学是当代石油地质学的一个前沿领域。80年代以来，随着油藏地球化学、流体包裹体方法、同位素测年法、油气水界面追溯法等多种新方法或新技术的引入，成藏年代学研究取得了重要进展，实现了由传统的间接向直接研究、宏观向微观研究，以及定性向定量（或定期向定年）研究的重要转变。间接研究与直接研究相结合、宏观与微观研究相结合、定性与定量（或定期与定年）研究相结合，已成为现代成藏年代学研究发展的重要趋势，这对于叠合盆地的成藏年代与成藏史研究尤为必要。就各种成藏年代学研究方法的应用及其存在的问题进行了简要分析和讨论。