胶东大尹格庄金矿床成矿流体组成

大尹格庄金矿床位于胶东半岛西北部招平断裂带中段,产于断裂带下盘绢英岩化带中。矿区内围岩蚀变发育,主要包括钾长石化、硅化、绢云母化、黄铁矿化、绿泥石化和碳酸盐化,其中硅化、绢云母化、黄铁矿化与金矿化密切相关。根据野外脉体穿插关系和矿物共生组合特点,大尹格庄金矿床金成矿作用从早到晚分为三个阶段:金-石英-黄铁矿阶段(早)、金(银)-石英-多金属硫化物阶段(中)、石英-方解石-黄铁矿阶段(晚)。矿石中石英的爆裂峰集中在330~510℃、240~330℃和160~240℃,分别对应成矿作用的早、中、晚三个阶段。成矿流体总体为中温,富CO2,含CH4、C2H6、H2S等挥发分的流体。NaCl-H2O-CO2图解及较高的C2H6含量,表明成矿流体主要来源于变质流体。各阶段成矿流体中气、液相组成相似,而含量规律性变化。早、中阶段成矿流体中N2含量较低,晚阶段升高,表明从早阶段到晚阶段流体系统逐渐开放,后期有大气降水的加入;从成矿早阶段到晚阶段,Cl-/SO2-4和Na+/K+升高,说明成矿流体从早阶段CO2-H2O-K2SO4型逐渐演化为中阶段和晚阶段CO2-H2O-NaCl型;Na+、Cl-、K+和SO2-4浓度逐渐降低,指示成矿流体从成矿早阶段到晚阶段盐度降低;H2O/CO2在晚阶段高于早、中阶段,指示流体有可能在中阶段发生了沸腾作用。成矿早阶段具有较高含量的H2S,表明金硫络合物可能是金的一种运移形式;流体类型的演变和沸腾作用可能是导致大尹各庄金矿床金沉淀的重要因素。     

岩浆通道成矿系统

全球最主要的岩浆铜镍硫化物矿床基本特征是:(1)矿石与围岩边界平直,呈侵入接触关系;(2)"矿浆"在岩浆成矿系统的晚期上侵就位;(3)矿体赋存于岩浆通道中.已有的成矿模型不能同时解释这三个基本特征,暗示必须进一步理解岩浆铜镍硫化物矿床的形成机制.最近几年我们的研究发现岩浆铜镍硫化物矿床中典型矿石具有如下特征:(1)矿石中存在流体晶矿物组合,它们既不同于岩浆岩中的矿物组合,也不同于变质岩中的矿物组合,推测是从流体中直接结晶的产物;(2)铜镍硫化物矿床中不同部位矿体中矿石存在显著的成分变化,前锋端矿石以富Ni为特点,尾端矿石富含Cu、Pt、Pd.据此,本文提出了"岩浆通道成矿系统"的新模型,试图整合解释岩浆铜镍硫化物矿床中的各种观测事实.所谓岩浆通道成矿系统,系指岩浆演化晚期,"矿浆"运移和就位的空间及其相关成矿要素的组合.该模型强调:(1)深部岩浆房在岩浆矿床的形成过程中起着非常重要的作用,"矿浆"定位于岩浆成矿系统演化的晚期;(2)矿浆具有整体的流动性,因而提出了"岩浆通道前进方向"的概念;(3)所谓的"矿浆"实际为富含矿熔体-流体流,后者因失去挥发份而呈"矿浆"状,以大的流体体积和流体/熔体比值为特征.数值模拟表明,往硫化物矿浆加入挥发份流体可以显著提高矿浆的上升能力.当加入的挥发份流体达到30vol.%时,受到质疑的密度问题将不复存在,矿浆具有快速上升到浅部地壳的能力.但是,如此富含挥发份的矿浆也不再是传统概念上的矿浆,而是含矿熔体-流体流.此外,由于流体超压等原因,含矿熔体-流体流利用先存的构造薄弱面快速上升,形成岩浆通道,并在有利的部位卸载成矿金属形成矿体.因此,矿体常常侵入切割围岩.     

Application of Hydrothermal Diamond Anvil Cell to Homogenization Experiments of Silicate Melt Inclusions

The homogenization of silicate melt inclusions （SMIs）,small droplets of silicate melt trapped in magmatic minerals,is an important component of petrogenetic and magmatic research.Conventional homogenization experiments on SMIs use microscope-mounted heating stages capable of producing high temperatures at 1 atm and cold-seal high-pressure vessels.Heating stages are generally used for SMIs with low internal pressures and allow in situ observations of the homogenization processes.In contrast,cold-seal high-pressure vessels are generally used to heat SMIs that have high internal pressures,although the homogenized SMIs can only be observed after quenching in this approach.Here we outline an alternative approach that uses a hydrothermal diamond anvil cell （HDAC） apparatus to homogenize SMIs.This is the only current method wherein phase changes in high-internal-pressure SMIs can be observed in situ during homogenization experiments,which represents an advantage over other conventional methods.Using an HDAC apparatus prevents high-internal-pressure SMIs from decrepitating during heating by elevating their external pressure,in addition to allowing in situ observations of SMIs.The type-V HDAC that is currently being used has a shorter distance between the sample chamber and the observation window than earlier types,potentially enabling continuous observation of the processes involved in heating and SMI homogenization through an objective lens with a long working distance.Homogenization experiments using HDAC require that a number of steps,including HDAC preparation,sample preparation,sample loading,preheating,and formal heating,be carefully followed.Homogenization experiments on SMIs within granite samples from the Jiajika pegmatite deposit （Sichuan,China） are best performed using an HDAC-based approach,because the elevated proper external pressure of these SMIs,combined with a short heating duration,helps to suppress material leakage and any reactions within the SMIs,in addition to allowing in situ observatio     

The homogenization temperature in the fluid inclusions of Ordovician halite and paleoclimatic implication

正1 Introduction The homogenization temperature of fluid inclusions reflects the temperatures of the brines from which halite crystals grew.Therefore,it is a powerful mean to reveal the paleoclimate.Northern Shaanxi Salt Basin is located in the central and eastern of Ordos Basin.We have detail petrographical research and the homogenization     

硅酸盐熔体和流体中金的性质及行为研究进展

岩浆演化过程中岩浆—流体阶段发生的相转变过程控制了元素在两相之间的分配行为。作为与岩浆热液活动有密切成因联系的金矿床,其在硅酸盐熔体和流体中的性状及两相间的分配行为是控制该类矿床成矿的重要物理化学因素。介绍了金在流体、熔体中的性状,论述了其在流体/硅酸盐熔体间的分配行为不仅受温度、压力、氧逸度等物理化学条件的影响,还受流体组分(阴离子、阳离子)、熔体组成(Na2O+K2O/Al2O3,Na/K,SiO2,NBO/T)的制约;最后对目前实验研究存在的问题、改进方法以及今后的研究方向进行了探讨。     

鄂尔多斯盆地中西部长8砂岩的流体包裹体特征与油气成藏期次分析

利用流体包裹体的分析测试技术与研究方法,对鄂尔多斯盆地中西部长8油层组的成藏期次进行了研究。烃类包裹
体及其伴生的盐水包裹体的岩相学特征、均一温度、盐度、密度及成分分析显示,长8储层主要发育两期烃类包裹体,第
一期分布在早期方解石胶结物、石英颗粒表面及其连生的石英加大边中以及未切穿石英颗粒的早期愈合裂缝中,其伴生盐
水包裹体的均一温度峰值为80~90℃;第二期烃类包裹体分布在石英颗粒表面和切穿石英颗粒的裂缝中,其伴生盐水包裹
体的均一温度峰值为100~120℃。储层成岩作用与油气充注微观分析、成岩-烃类充注演化时间序列研究,结合地层埋藏史
和热史分析表明,研究区经历了三期烃类充注事件：第一期（约169~161 Ma） 充注规模小,砂岩中未捕获到这一期适合进
行均一温度与成分测定的烃类包裹体,因此本研究缺乏这期包裹体的温度与成分数据;第二期（约148~135 Ma） 烃类充注
对应前述获得均一温度与成分数据的第一期烃类包裹体;第三期烃类充注规模最大,发生在早白垩世晚期的125.2~105.7 Ma
之间,为主成藏期,对应前述获得均一温度与成分数据的第二期烃类包裹体。     

胶东金矿研究进展及约束金物质来源的新思路

作为全球最主要的金成矿带之一,胶东地区仅占全国国土面积的0．27％,黄金储量却约占全国的25％,特别是胶西北地区的金矿更是星罗棋布,引起了国内外地质学家的广泛关注,进行了大量的生产和科研工作。该文总结了近年来取得的关于胶东金矿在构造、岩浆、流体及成矿物质、富集机制等方面取得的研究进展,并且针对颇具争议的金成矿物质来源问题,提出了新的研究思路,并初步论证了其可行性。以期抛砖引玉,引起广大地学同仁对此科学问题的关注。     

http://www.sciencedirect.com/science/article/pii/S1674987114000218

Fluid infiltration into retrograde granulites of the Southern Marginal Zone(Limpopo high grade terrain)is exemplified by hydration reactions.shear zone hosted metasomatism,and lode gold mineralisation.Hydration reactions include the breakdown of cordierite and orthopyroxene to gedrite kyanite,and anthophyllite,respectively.Metamorphic petrology,fluid inclusions,and field data indicate that a low H_2O-activity carbon-saturated CO_2-rich and a saline aqueous fluid infiltrated the Southern Marginal Zone during exhumation.The formation of anthophyllite after orthopyroxene eslablished a regional retrograde anthophyllite-in isograd and occurred at P-T conditions of- 6 kbar and 610 C,which fixes the minimum mole fraction of II.0 in the CO_2-rich fluid phase at- 0.1.The maximum H_2O mole fraction is hxed by the lower temperature limit(~800℃) for partial melting at ~0.3.C-O-H fluid calculations show that the CO_2-rich fluid had an oxygen fugacity that was 0.6 log10 units higher than that of the fayalite-magnetitequartz buffer and that the CO_2/(CO_2+CH_4) mole ratio of this fluid was 1.The presence of dominantly relatively low density CO_2-rich fluid inclusions in the hydrated granulites indicates that the fluid pressure was less than the lithostatic pressure.This can be explained by strike slip faulting and/or an increase of the rock permeability caused by hydration reactions.     

新疆阿尔泰铁木尔特铅锌矿床流体包裹体研究及地质意义

铁木尔特中型铅锌矿是阿尔泰山南缘克兰盆地内的重要VMS型矿床。矿床赋存于上志留统-下泥盆统康布铁堡组上亚组第二岩性段,容矿岩石为大理岩、绿泥石英片岩、变钙质粉砂岩、夕卡岩。矿体呈似层状和透镜状。矿床的形成经历了喷流沉积期、叠加改造期和表生期。石英、长石、方解石和石榴子石中包裹体类型主要为液体包裹体,在石英中另出现了气体包裹体、纯气体包裹体、含子矿物多相包裹体、含液体CO2的三相包裹体和两相CO2包裹体。喷流沉积期成矿流体均一温度变化于150～330℃,其峰值是165℃和285℃,成矿流体盐度(NaCleq)为4%～16%,流体密度为0.77～0.97g/cm3,流体阳离子主要以Na+为主,次之为K+,阴离子以Cl-为主,其次是SO42-,气相成分主要是H2O和CO2。叠加改造期均一温度范围是150～480℃,峰值为285℃,盐度(NaCleq)为2.2%～17.08%和33.93%～47.2%,流体密度变化于0.61～1.03g/cm3之间,流体阳离子主要以Na+为主,次为K+、Mg2+、Ca2+,阴离子以Cl-为主,其次是SO42-,气相成分主要是H2O和CO2,其次为N2、CH4,含有少量C2H6。     

西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征

西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。