"地球流体力学"电子教案设计的特点及其实现

根据21世纪高等学校教学改革的要求,结合"地球流体力学"课程教学的特点,以Microsoft Office办公软件为开发平台,SmartDraw、Mathtype、Photoshop、Graphmatica等应用软件为多媒体辅助开发工具,在国内率先设计、制作了"地球流体力学"多媒体电子教案.该电子教案内容丰富,表现形式多样,功能强大,使用容易,修改、扩展方便.可利用多媒体技术中的视觉及听觉表现力来调动学生的学习积极性,有效改善理论性较强的专业课的课堂教学氛围,提高教学效率及学习效果.     

Fluid venting activity on the Costa Rica margin: new results from authigenic carbonates

Carbonate precipitates on mounds and along tectonic scarps off the Costa Rica margin are manifestations of subduction-induced dewatering. The long-term dewatering history is recorded in mineralogical, petrological and isotope signals of carbonates recovered from these sites. The carbonates are strongly depleted in ¹³C (–11 to –53 PDB) and enriched in ¹⁸O (+4 to +8 PDB). Thermogenic methane and biogenic methane were identified as sources of the carbon. Chemoherm carbonates and seepage-associated carbonates formed in a focused flow regime have lighter ¹³C values, while others formed in a more diffusive flow regime have slightly enriched C isotope values. Three fluid components were inferred based on the calculation of equilibrium ¹⁸O: clay dehydration water, gas hydrate water and seawater. Calculated equilibrium ¹⁸O values of carbonates from different down-core depths as well as from different precipitation stages show that the ¹⁸O of the precipitating fluid is progressively depleted with time. Dolostones showing a methane-C source and a well constrained O-isotope signature are thought to have formed at depth in the sediment and subsequently became exhumed. Glauconitic sandstones cemented by methane-derived carbonate provide evidence that fluid and solid material have been expelled by the mud volcano.     

Wells turbine with end plates for wave energy conversion

In order to improve the performance of the Wells turbine for wave energy conversion, the effect of end plate on the turbine characteristics has been investigated experimentally by model testing. As a result, it is found that the characteristics of the Wells turbine with end plates are superior to those of the original Wells turbine, i.e., the turbine without end plate and the characteristics are dependent on the size and position of end plate. Furthermore, by using a computational fluid dynamics (CFD), reason of the performance improvement of the turbine has been clarified and the effectiveness of the end plate has been demonstrated.     

An improved model for the calculation of CO2 solubility in aqueous solutions containing Na, K, Ca, Mg, Cl, and SO4

An improved model is presented for the calculation of the solubility of carbon dioxide in aqueous solutions containing Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, and SO₄²⁻ in a wide temperature–pressure–ionic strength range (from 273 to 533 K, from 0 to 2000 bar, and from 0 to 4.5 molality of salts) with experimental accuracy. The improvements over the previous model [Duan, Z. and Sun, R., 2003. An improved model calculating CO₂ solubility in pure water and aqueous NaCl solutions from 273 to 533K and from 0 to 2000 bar. Chemical Geology, 193: 257–271] include: (1) By developing a non-iterative equation to replace the original equation of state in the calculation of CO₂ fugacity coefficients, the new model is at least twenty times computationally faster and can be easily adapted to numerical reaction-flow simulator for such applications as CO₂ sequestration and (2) By fitting to the new solubility data, the new model improved the accuracy below 288 K from 6% to about 3% of uncertainty but still retains the high accuracy of the original model above 288 K. We comprehensively evaluate all experimental CO₂ solubility data. Compared with these data, this model not only reproduces all the reliable data used for the parameterization but also predicts the data that were not used in the parameterization. In order to facilitate the application to CO₂ sequestration, we also predicted CO₂ solubility in seawater at two-phase coexistence (vapor–liquid or liquid–liquid) and at three-phase coexistence (CO₂ hydrate–liquid water–vapor CO₂ [or liquid CO₂]). The improved model is programmed and can be downloaded from the website http://www.geochem-model.org/programs.htm.     

冲绳海槽南部玄武岩中的流体包裹体成分及其意义

用激光拉曼探针分析了冲绳海槽南部橄榄拉斑玄武岩中的流体包裹体成分。结果表明，流体包裹体的主要成分为CO2，此外，还有H2O、H2S、CH4、N2、C2H2、C2H4、C3H8组分。不同宿主矿物，其包裹体成分中CO2、H2O和CH4的相对含量也不同，其中，钙长石中包裹体的CO2含量最高，贵橄榄石中的次之，普通辉石中的最少。CH4和H2O的含量趋势与CO2相反。根据这3种宿主矿物中流体成分及其含量变化特点，推断这3种宿主矿物的结晶顺序为钙长石、贵橄榄石、普通辉石，并认为流体包裹体中的烃类和水可能主要来自熔体上升过程中所接触的沉积地层。     

地震活动中地壳深部流体的作用研究进展

综述了地震深部流体研究的进展并提出了在地震领域应该深入研究的方面。已有大量资料表明岩石圈是一含流体的系统，也是地震发育的主要场所。深部流体赋存相态，运移方式及其与岩石的反应，对震源介质和构造活动有重要影响。     

成矿过程中由流体混合而导致金属沉淀的研究

对成矿流体的研究已成为当前矿床学和地球化学领域重要的前沿课题，其主要进展之一就是确认由不同性质流体的混合导致金属沉淀是矿石形成的重要方式。从流体混合过程的现代自然现象研究出发，以近年来国内外最近研究成果为基础，以岩浆水与大气降水的混合为重点，综述了成矿过程中几种主要的导致金属沉淀的流体混合作用，并对其主要机理─—冷却、稀释、酸碱度改变和氧化还原反应──进行了初步讨论。     

断层带中超压流体及其在地震和成矿中的作用

地震断层带中的局部存在对其力学和化学过程有着重要影响的超压流体，对这种超压流本的证据。超压机制及其在地震活动和成矿中的作用等进行了探讨。流体超压是在断层带中渗透性的构造发生强烈时空变化的前提下产生的，其主要原因是构造加压及深源高压流体的注入，当流体压力升至一临界值时，断层发生灾难性破裂，即地震，增加断层的渗透性，超压流体快速向低压带（室或域）流动，同时因减压流体所携载水溶物各（包括成矿物质）大量沉淀析出，降低断层带的渗透性，地震泵吸和流体超压机制的交替作用使得这一过程得以周期性地进行。     

Origin of the fumarolic fluids of Vulcano Island,Italy and implications for volcanic surveillance

Variations in D and ¹⁸O values with H₂O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The ¹⁸O values of the marine-hydrothermal component of +5 to +7.2 are due to isotopic exchange with the ¹⁸O-rich silicates of the rocks under high-temperature and low-permeability conditions. The ¹⁸O value of the magmatic end-member is generally +3.5 to +4.3, although values as high as +5.5 to +6.5 were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The D values of the end-member were close to -20, typical of andesitic waters. Both the isotopic values and chemical data strongly support a dry model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids. The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions. The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low. A boiling hydrothermal aquifer at 230° C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.     

Retrograde evolution of quartz segregations from the Dos Picos shear zone in the Nevado-Filabride Complex (Betic chains,Spain). Evidence from fluid inclusions and quartz c-axis fabrics

Synkinematic quartz veins are ubiquitous in the shear zone separating the Veleta unit from the Calar Alto unit in the internal part of the Betic Cordilleras. They have been studied with respect to quartz c-axis fabrics, microstructures and fluid inclusions. Veins were probably generated during syn-metamorphic stacking of the units at P = 500 – 600 MPa and T = 400 – 500°C. Quartz displays two groups of microstructures in the shear zone: (1) older coarse-grained mosaics (CGM) resulting from exaggerated grain growth; and (2) younger fine-grained mosaics (FGM) developed at the expense of the former. The fine-grained mosaics show polygonal granoblastic and elongate mosaic microstructures in general, with ribbon microstructures often found near the boundary of the units. Fluids contained in secondary inclusions vary from high salinity brines to different types of CO₂—brine mixtures and low density CO₂ fluids. Differences in composition and P-T trapping conditions are indicated for the different types of inclusions. Some fluid inclusions are older than the FGM, whereas others are younger, thus constraining the P- T conditions at which the two microstructural events took place. Fluid inclusion evidence suggests conditions of P_fluid > 170 MPa and T 370–430°C for the CGM and P_fluid 20–80 MPa and T > 340°C for the FGM.The quartz c-axis fabrics dealt with here correspond to the second recrystallization event, as little evidence of older fabrics is preserved in the shear zone. C-axis patterns vary across the shear zone from slightly asymmetrical type I crossed girdles in the hanging wall and footwall to more asymmetrical crossed girdles at the boundary of the units. This indicates a correlative increase in the magnitude of the heterogeneous shear strain in the same direction. Most of the deformation is concentrated at the top of the Veleta unit. The sense of movement is top to the west, in agreement with other kinematic markers.The quartz c-axis fabrics resulted from dynamic recrystallization during simple shear. The retrograde P-T path inferred from fluid inclusion analysis, along with other geological and geochronological evidence, indicates that this deformation is coeval with a reduction in the crustal overburden.Geochronological and stratigraphic data show that the proposed Dos Picos extensional detachment, separating the Calar Alto and Veleta units, took place during the early Miocene, synchronous with the intense thinning of the Nevado-Filábride Complex and of the whole continental crust underlying the Alborán Basin.