Geology,fluid inclusion and stable isotope study of the Yueyang Ag-Au-Cu deposit,Zijinshan orefield,Fujian Province,China

The large Yueyang Ag-Au-Cu deposit is commonly regarded as a low-sulfidation epithermal deposit in the Zijinshan orefield, Fujian Province, southeastern China. The Ag-Ag-Cu orebodies hosted in the Zijinshan granitic batholith are mainly stratoid and lens in shape, and controlled by a series of NW-trending listric faults with shallow dip angles. Four mineralization stages are recognized on the basis of mineral assemblage, ore fabrics, and crosscutting relationships of the ore veins, namely: pre-ore (pyrite + sericite + quartz ± chlorite), main Cu (chalcopyrite + pyrite + sericite + quartz ± bornite), main Ag-Au (Ag and Au minerals + pyrite + quartz + adularia ± calcite ± apatite ± chalcopyrite ± galena ± sphalerite) and post-ore (quartz ± chalcedony ± calcite) stages. Fluid inclusions (FIs) in the deposit include aqueous liquid-rich (WL-), aqueous vapor-rich (WV-), and minor carbonic (C-) and daughter mineral-bearing (S-) type ones. WL-subtype is the main inclusion type in the Yueyang deposit, accounting for more than 90% in proportion in each stage. Minor WV-subtype inclusions occur in both the main Cu and Ag stages, while the C-type and S-type ones are only observed in the main Cu stage. Fluid inclusion and H-O isotope study indicated that the ore-forming fluid of the main Cu stage is primarily magmatic vapor, which further underwent fluid boiling and mixing with meteoric water, while the ore-forming fluid of the main Ag stage is meteoric water-dominated, and the precipitation of silver and gold was mainly resulted from fluid boiling and the precipitation of other sulfides. On the basis of the aforementioned geological, fluid inclusion and stable isotope studies, we proposed a two-stage model for the Yueyang deposit, including a magmatic vapor-related porphyry type Cu mineralization and meteoric water-related low-sulfidation epithermal Ag-Au-Cu mineralization, although the porphyry Cu mineralization is very limited in scale. The mineralization and exhumation depths of the Yueyang deposit are estimated to be 448‒527 m and 18‒97 m, respectively. By comparison with the exhumation depths of other deposits in the Zijinshan orefield, it is suggested that more epithermal deposits could be found in the southwest of the orefield due to less uplift and exhumation therein.     

Geology and ore genesis of the late Paleozoic Heijianshan Fe oxide–Cu (–Au) deposit in the Eastern Tianshan,NW China

The Heijianshan Fe–Cu (–Au) deposit, located in the Aqishan-Yamansu belt of the Eastern Tianshan (NW China), is hosted in the mafic–intermediate volcanic and mafic–felsic volcaniclastic rocks of the Upper Carboniferous Matoutan Formation. Based on the pervasive alteration, mineral assemblages and crosscutting relationships of veins, six magmatic–hydrothermal stages have been established, including epidote alteration (Stage I), magnetite mineralization (Stage II), pyrite alteration (Stage III), Cu (–Au) mineralization (Stage IV), late veins (Stage V) and supergene alteration (Stage VI). The Stage I epidote–calcite–tourmaline–sericite alteration assemblage indicates a pre-mineralization Ca–Mg alteration event. Stage II Fe and Stage IV Cu (–Au) mineralization stages at Heijianshan can be clearly distinguished from alteration, mineral assemblages, and nature and sources of ore-forming fluids.Homogenization temperatures of primary fluid inclusions in quartz and calcite from Stage I (189–370 °C), II (301–536 °C), III (119–262 °C) and V (46–198 °C) suggest that fluid incursion and mixing probably occurred during Stage I to II and Stage V, respectively. The Stage II magmatic–hydrothermal-derived Fe mineralization fluids were characterized by high temperature (>300 °C), medium–high salinity (21.2–56.0 wt% NaCl equiv.) and being Na–Ca–Mg–Fe-dominated. These fluids were overprinted by the external low temperature (<300 °C), medium–high salinity (19.0–34.7 wt% NaCl equiv.) and Ca–Mg-dominated basinal brines that were responsible for the subsequent pyrite alteration and Cu (–Au) mineralization, as supported by quartz CL images and H–O isotopes. Furthermore, in-situ sulfur isotopes also indicate that the sulfur sources vary in different stages, viz., Stage II (magmatic–hydrothermal), III (basinal brine-related) and IV (magmatic–hydrothermal). Stage II disseminated pyrite has δ³⁴S_fluid values of 1.7–4.3‰, comparable with sulfur from magmatic reservoirs. δ³⁴S_fluid values (24.3–29.3‰) of Stage III Type A pyrite (coexists with hematite) probably indicate external basinal brine involvement, consistent with the analytical results of fluid inclusions. With the basinal brines further interacting with volcanic/volcaniclastic rocks of the Carboniferous Matoutan Formation, Stage III Type B pyrite–chalcopyrite–pyrrhotite assemblage (with low δ³⁴S_fluid values of 4.6–10.0‰) may have formed at low fO₂ and temperature (119–262 °C). The continuous basinal brine–volcanic/volcaniclastic rock interactions during the basin inversion (∼325–300 Ma) may have leached sulfur and copper from the rocks, yielding magmatic-like δ³⁴S_fluid values (1.5–4.1‰). Such fluids may have altered pyrite and precipitated chalcopyrite with minor Au in Stage IV. Eventually, the Stage V low temperature (∼160 °C) and low salinity meteoric water may have percolated into the ore-forming fluid system and formed late-hydrothermal veins.The similar alteration and mineralization paragenetic sequences, ore-forming fluid sources and evolution, and tectonic settings of the Heijianshan deposit to the Mesozoic Central Andean IOCG deposits indicate that the former is probably the first identified Paleozoic IOCG-like deposit in the Central Asian Orogenic Belt.     

青海驼路沟钴矿床流体包裹体及成矿物理化学条件

应用均一法、激光拉曼显微探针法研究驼路沟钴矿床的流体包裹体,发现其包裹体类型多样,以气液两相包裹体和富二氧化碳包裹体为主,测得均一温度为220℃~300℃,众值为275℃,成矿流体形成于中低温环境。通过对其他热力学参数计算,确定出驼路沟钴矿床成矿流体具有中低盐度、低密度、弱还原-还原性的特点。包裹体气、液相成分分析表明其与现代海底热液沉积物的流体成分类似,进一步佐证了驼路沟钴矿床为热水喷流沉积成因。     

Controls on the mechanisms of fluid infiltration and front advection during regional metamorphism: a stable isotope and textural study of retrograde Dalradian rocks of the SW Scottish Highlands

Vein-controlled retrograde infiltration of H₂O-CO₂ fluids into Dalradian epidote amphibolite facies rocks of the SW Scottish Highlands under greenschist facies conditions resulted in alteration of calcite-rich marble bands to dolomite and spatially associated ¹⁸O enrichment of about 10%. on a scale of metres. Fluid inclusion data indicate that the retrograde fluid was an H₂O-salt mixture with a low CO₂ content, and that the temperature of the fluid was about 400d? C. Detailed petrographic and textural (backscattered electron imaging) studies at one garnet-grade locality show that advection of fluid into marbles proceeded by a calcite-calcite grain edge flow mechanism, while alteration of non-carbonate wall-rock is associated with veinlets and microcracks. Stable isotopic analysis of carbonates from marble bands provides evidence for advection of isotopic fronts through carbonate wall-rocks perpendicular to dolomite veins, and fluid fluxes in the range 2.4–28.6 m³/m² have been computed from measured advection distances. Coincidence of isotope and reaction fronts is considered to result from reaction-enhanced kinetics of isotope exchange at the reaction front. Front advection distances are related to the proportion of calcite to quartz in each marble band, with the largest advection distance occurring in nearly pure calcite matrix. This relationship indicates that fluid flow in carbonates is only possible along fluid-calcite-calcite grain edges. However, experimental constraints on dihedral angles in calcite-fluid systems require that pervasive infiltration occurred in response to calcite dissolution initiated at calcite-calcite grain junctions rather than to an open calcite pore geometry. The regional extent of the retrograde infiltration event has been documented from the high δ¹⁸O of dolomite-ankerite carbonates from veins and host-rocks over an area of least 50 × 50 km in the SW Scottish Highlands. Isotopically exotic ¹⁸O-rich retrograde fluids have moved rapidly upwards through the crust, inducing isotopic exchange and mineral reaction in wall-rocks only where lithology, pore geometry or mineral solubilities, pressure and temperature have been appropriate for pervasive infiltration to occur.     

辽宁四道沟金矿床的脉动构造

辽宁四道沟金矿床内直接控制矿化的主要为一系列不规则的小型微型裂隙,这些控矿裂隙形成于叠加褶曲作用晚期,是一种脉动构造。叠加褶曲轴都是脉动构造发育的良好地段。根据流体包裹体特征,可将脉动作用划分为四个阶段,表明了成矿的多阶段性。     

On the fluid and viscoelastic deformations of the planets

The shape of the Earth and of planets depends on the exciting forces and on the rheology of the medium. From the equilibrium equation, we present the main modelisations of the viscous and inviscid fluids and we essentially describe the characteristics of linear viscoelastic deformations, for the Maxwell viscoelastic model of rheology. We use the elastic, viscoelastic and fluid Love numbers in order to investigate the associated relaxation modes. For these various kinds of rheology of the planets interior, we compute the geoid and the topography induced by an internal mass distribution. Finally, we show the importance of this viscoelastic deformation calculations in the study of the celestial body rotations.     

Low-thermal-gradient Hercynian metamorphism in the eastern Pyrenees

Abstract Fluids with compositions in the system CO₂-H₂O-NaCl were trapped in quartz veins enclosed in low-grade metamorphic rocks (chlorite zone) on the southern flank of the Canigó Massif, eastern Pyrenees. The veins, which also contain arsenopyrite crystals, were formed contemporaneously with the main Hercynian foliation and metamorphism. Volumetric properties of the fluid and the results of arsenopyrite geothermometry suggest P-T trapping conditions of 4.6–6 kbar and 450–530° C. This implies that an episode of metamorphism with an average geothermal gradient of 25° C km⁻¹ occurred during the main deformation event. This episode preceded the low- P /high- T metamorphism described around domes and to date considered as characteristic of the Hercynian orogeny in the Pyrenees.     

南极乔治王岛长城站地区火山岩中矿物包裹体的研究

本文主要讨论了长城站地区第三纪火山岩系的透辉石和斜长石中熔融包裹体的特征、均一温度、挥发组分、玻璃和子矿物的化学成分。透辉石中熔融包裹体均一温度为1070～1170℃,斜长石中熔融包裹体均一温度m≥1100℃。透辉石和斜长石熔融包裹体气泡中组分CO_2为45～93％,H_2S为微量～35％,CH_4为2～20％和CO为2～14％,少量为N_2,O_2,H_2O和H_2。这些组分从火山喷发早期至晚期呈规律性变化。对熔融包裹体的玻璃和子矿物进行成分测定,其子矿物为钙铁橄榄石。     

Fluid inclusions in high pressure/low temperature rocks from the Calabrian Arc (Southern Italy): the burial and exhumation history of the subduction-related Diamante-Terranova unit

The Diamante-Terranova Unit (DIATU), in the Calabrian Arc of southern Italy, is part of an ophiolitic sequence involved in a high pressure/low temperature event (P=8 kbar; T =400 °C) followed by re-equilibration at greenschist facies conditions (P=3 kbar; T =300 °C). The rocks contain two types of quartz–calcite veins – an earlier generation of deformed, folded and faulted veins formed during or before subduction, and a later set of planar, undeformed veins formed during exhumation of the DIATU. The earlier folded quartz–calcite veins contain regularly shaped aqueous inclusions as well as inclusions with a highly irregular dendritic texture. The later planar veins contain only regularly shaped aqueous inclusions similar to those in the earlier veins. In both vein types, all inclusions are demonstrably secondary in origin. Regularly shaped inclusions from both vein types are low salinity (0–5 wt% NaCl). Most contain liquid and vapour and homogenize to the liquid (Th 135–180 °C), whereas others contain only liquid at room temperature. Both the two-phase and monophase inclusions occur in the same fractures and are thought to record the same trapping event, with the monophase inclusions remaining metastable liquid at room temperature. No microthermometric data could be obtained from the dendritic inclusions in the earlier folded veins. Inclusions with the highly irregular dendritic texture found in the earlier veins are similar to those produced experimentally during laboratory-induced deformation of synthetic inclusions in quartz under conditions of internal underpressure, simulating either isobaric cooling or isothermal compression. The occurrence of inclusions with the dendritic texture in the earlier folded veins, and their absence from the later planar veins, suggests that the earlier veins formed before or during subduction and were folded and faulted in a compressional environment and their contained fluid inclusions were modified to produce the dendritic texture. During later uplift of the DIATU, planar veins containing regularly shaped aqueous inclusions formed and some of the fluids forming these veins were also trapped as secondary inclusions in the earlier folded veins. The results of this study provide convincing evidence that inclusions with a highly irregular dendritic morphology represent early inclusions that have survived prograde conditions in a high pressure/low temperature metamorphic environment (but have been texturally modified). The high pressure/low temperature ‘implosion’ texture is preserved over geological time, even after being overprinted by internal overpressure conditions generated during retrograde decompression. We suggest that inclusions that have survived prograde metamorphism are common in high pressure/low temperature rocks, but are often not identified as such due to their morphology which makes their recognition difficult.     

Chemical Composition of the Primitive Mantle Source of Peridotite Inclusions at Mount Lianshan, Liuhe County,Jiangsu Province

This paper presents a study of the major and trace element compositions of fresh mantle-derived spinel lherzolite and harzburgite inclusions from Cenozoic alkaline basalt in Mount Lianshan and Mount Panshi, Liuhe County, Jiangsu Province. An estimation is made of the contents of the major elements and some of the trace elements in the primitive mantle source region of the area, from which the authors have obtained MgO/Al2O3= 7.86. The contents of MgO and Al2O3 are also obtained as 37.58% and 4.78% respectively based on the correlation of MgO-Al2O3. Then, the contents of various elements in the primitive mantle are calculated using their regression equations with MgO, and the compositor) of the primitive mantle, a basic issue in geochemistry study, is discussed on that basis.