岩浆包裹体化学成分研究

岩浆包裹体化学成分研究难度较大,为了获得可信的数据,应当注意:1.非演化型岩浆包裹体的化学成分可以代表其初始成分。演化型岩浆包裹体应先均一、淬火后再行测定。2.均一演化型岩浆包裹体应严格遵守加热规则,否则过热作用会使包裹体壁部分熔化,造成淬火后所测包裹体成分与其真正的初始成分并不相当。3.实测资料证明,“边界层效应”对于岩浆包裹体化学成分影响微不足道。4.岩浆包裹体的化学成分只能代表其主矿物结晶时周围岩浆的成分,即仅相当于岩浆液相线上的一个点。5。把显微冷热台测温、激光喇曼探针和电子探针分析技术结合使用,对查明单个包裹体中挥发组分的性状和浓度具有很大的潜力和前途。     

大别山双河和碧溪岭超高压变质岩流体包裹体研究

对大别山双河和碧溪岭含柯石英榴岩和硬玉石英岩进行了详细的流体包裹体研究。根据流体包裹体的成分和盐度的不同,可以划分出至少五种类型不同的气液包裹体;（１）Ｎ２包裹体;（３）高盐度流体包裹体;（３）ＣＯ２包裹体;（４）ＣＯ２－Ｈ２Ｏ包裹体;（５）低盐度流体包裹体。本仅见于含柯石英榴辉岩,而高盐度流体包裹体则几乎存在于所有的榴辉岩和硬玉石英岩中。ＣＯ２包裹体沿榴辉岩中微剪切带分布,或存在于强变形的硬玉石     

Logs Fluid Typing Methods and Adaptive Analysis of Tight Sandstone Reservoir of Yingcheng Formation in Lishu Fault

Tight clastic reservoirs are characterized with low porosity and low permeability, which reduce contributions of reservoir fluids to geophysical logging responses, and it is more difficult to identify fluids of the reservoir. Therefore, it is necessary to study log interpretation and comprehensive evaluation methods for such clastic reservoirs. This study focused on geological characteristics of tight clastic reservoir of Yingcheng formation in Lishu Fault. Based on logs sensitivity to fluids, some fluid typing methods were discussed in detail, which included log curve overlap method, acoustic time overlapping method from density and neutron logs, porosity difference and ratio method, porosity-resistivity crossplot, normal distribution method, and other methods, and some effective fluid evaluation method were established and optimized. These above-mentioned methods were verified, which could achieve layer qualitative identification of tight sandstone in the study area. By contrast, two logs overlapping methods, porosity difference and ratio method, resistivity-porosity crossplot are more suitable for natural gas reservoirs, while porosity difference and ratio method, porosity-resistivity chart, normal distribution method are more suitable for oil and water reservoirs. The case study suggests that these methods be combined to archive more correct log interpretation in the study area, which provides important decision-making reference for oilfield exploration and development.     

Sediment provenance in a tropical fluvial and marine context by magnetic 'fingerprinting' of transportable sand fractions

The sources and fluxes of sediment to the Great Barrier Reef lagoon from north‐eastern Australian rivers have been the subject of much concern and study, with the large catchments of the Burdekin and Fitzroy Rivers thought to be the key sources at present. Here, the utility of newly developed magnetic ‘fingerprinting’ methods for identifying sediment provenance, both onshore and offshore, and in association with individual large flood events, is investigated. Within the Burdekin catchment, sediments are mobilized from different subcatchments by runoff generated by intense, localized rainfall events. Magnetic measurements were made on untreated and acid‐treated samples of river channel sediments within the Burdekin River subcatchments and from the estuarine and inner shelf depocentres of Burdekin River sediments. The acid treatment removes all discrete magnetic particles and coatings, and leaves magnetic inclusions (protected within host silicate grains) as the basis of the measured magnetic signature of a sample. The magnetic properties of the acid‐treated samples display statistically distinct sediment provenance groupings. Sand samples from the Upper Burdekin River appear magnetically distinct from samples from tributaries of the Burdekin (e.g. Hann Creek, Fanning River) and also from nearby coastal rivers, including the Haughton. Suspended sand samples from a Burdekin flood event in 2000 appear to have a different source compared with those from floods in 1998 and 1999. Comparisons of the terrestrial, acid‐treated sand fractions with the same, acid‐treated, sand‐size fractions from transects taken offshore suggest that the surface sediments in Upstart Bay and Bowling Green Bay have different sources. Some of these sources are as yet unidentified but may represent the unsampled, lower‐discharge south‐western Burdekin subcatchments, and/or along‐shore drift of sand from the south, perhaps even from the Fitzroy River, over millennial timescales of cyclone pumping. The magnetic inclusion method precludes any obfuscation or confounding of sediment source, which might arise from hydraulic sorting and/or post‐depositional magnetic diagenesis or authigenesis.     

流体包裹体研究:进展、地质应用及展望

在多数地质作用过程中,流体都担任着元素迁移的载体、化学反应的活化荆的角色.大量研究表明,岩石、矿物以及元素在有无流体的情况下会表现出迥异的物理和化学性质,所以对于认识某一地质过程而言,流体方面的研究往往能够提供极其重要的信息.流体包裹体则以其直接反映古流体的成分,在各种矿物中的普遍存在性,以及对各种后期改造有一定的抵抗力等特点而成为研究古地质流体的最佳样本,并已经被成功地应用到各种地质过程的研究中.从基本概念出发,讨论了流体包裹体的种类和原生、次生流体包裹体的区分,对流体包裹体的岩相学观察要点以及流体包裹体研究的最新进展做了简要的综述,着重介绍了研究中常用的分析方法及变质岩中流体包裹体的研究,并举例说明了流体包裹体在矿床学、石油地质学中的应用,以及近期的一些关于流体包裹体中保存生物标志和生物遗迹化石的研究,最后对未来流体包裹体研究的发展方向作了简单的展望.     

大水沟碲矿床成矿物理化学条件研究

本文在对大水沟碲矿床各成矿阶段矿物共生分析、成矿温度、矿液成分研究的基础上,对成矿的其它物理化学条件,如pH、f_O2、f_S2、f_Te2等作了热力学计算,并结合矿床地质资料,计算与分析了成矿过程中碲的迁移形式及富集机理。     

Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.     

Dunites of the Inagli massif (Central Aldan), cumulates of lamproitic magma

We consider a hypothesis for the origin of PGE-bearing ultramafic rocks of the Inagli massif (Central Aldan) through fractional crystallization from ultrabasic high-potassium magma. We studied dunites and wehrlites of the Inagli massif and olivine lamproites of the Ryabinovy massif, which is also included into the Central Aldan high-potassium magmatic area. The research is focused on the chemistry of Cr-spinels and the phase composition of Cr-spinel-hosted crystallized melt inclusions and their daughter phases. Mainly two methods were used: SEM-EDS (Tescan Mira-3), to establish different phases and their relationships, and EPMA, to obtain precise chemical data on small (2-100 μm) phases. The obtained results show similarity in chromite composition and its evolutionary trends for the Inagli massif ultramafites and Ryabinovy massif lamproites. The same has been established for phlogopite and diopside from crystallized melt inclusions from the rocks of both objects. Based on the results of the study, the conclusion is drawn that the ultramafic core of the Inagli massif resulted from fractional crystallization of high-potassium melt with corresponding in composition to low-titanium lamproite. This conclusion is consistent with the previous hypotheses suggesting an ultrabasic high-potassium composition of primary melt for the Inagli ultramafites.     

西天山达巴特斑岩型铜矿床流体地球化学特征和成矿作用

本文对西天山地区达巴特斑岩铜钼矿床矿石中石英的流体包裹体进行了均一法和冷冻法测温,对相应的石英单矿物进行了氢氧同位素测定,据此判断了成矿流体的来源和成矿物理化学条件。结果表明含铜钼矿石中的流体包裹体主要为气液两相包裹体和含子矿物三相包裹体,不同样品中同类包裹体具有基本一致的均一温度、子矿物溶化温度、冰点、盐度和密度值, 数据显示成矿流体均呈中温低盐度的特点。矿石氢氧同位素组成表明矿床的成矿流体属于岩浆水范畴,而且具有深部来源甚至幔源的可能性。根据矿体主要分布在火山机构南北两侧与地层的接触带及其内发育的断裂构造中这一空间关系,结合流体包裹体测温结果,推测尽管该矿床成矿流体具有深源特征,但成矿作用发生在中浅部环境,成矿与火山机构最晚期的花岗斑岩具有密切的成因关系。     

流体包裹体成分物理化学参数的NET2.0C#语言计算程序

根据地球化学热力学原理,利用流体包裹体成分测试数据和有关热力学原理,在原有基础上采用NET2.0 C#语言进行修编,编制成目前切实可行的计算机处理程序——矿物包裹体成分、物理化学参数的计算程序.其目的是方便广大地质工作者将这些参数用于地质找矿和科学研究中.