Occurrence of Organic Matter in Calcimicrobialites across Permian-Triassic Boundary in Huayingshan Region, Sichuan, South China

Calcimicrobialites across the Permian-Triassic boundary in Huayingshan (华蓥山) region were investigated using the fluorescence microscopic measurements to understand the occurrence of organic matter. The microbialites are composed of micrite matrix and coarse spar cement. Abundant rhombic or magnetic needle-like carbonate minerals were observed adrift within the cement. The fluorescence microscopic measurement indicates the micrite matrix in microbialites shows the most abundant organic matter, with the rhombic or magnetic needle-like carbonate minerals and coarse spar cement coming to the 2nd and the 3rd, respectively. Organic matter is mainly preserved in the space between the grains of the micrite minerals but almost evenly distributed in the rhombic or magnetic needle-like carbonate minerals. As one of the common diagenesis types, dolomitization is observed to occur in the microbialites in Huayingshan. However, the carbonate cement in microbialites still has high content of element Sr as shown by the microprobe analysis, reflecting that the dolomitization might have happened in a restricted environment. Observation under the fluorescence microscope shows that dolomitization just led to the redistribution of organic matter in the grain space of dolomite minerals, inferring that the diagenesis has a slight effect on the preservation, and thus on the content of organic matter in the microbialites.     

辽宁小塔子沟金矿地质特征及成矿控制因素

小塔子沟金矿床位于凌源一北票金矿成矿带的中部,为受区域断裂构造、燕山期石英二长岩和太古界小塔子沟组变质杂岩所控制的含金石英脉型和蚀变岩型金矿,通过对矿床地质特征的分析,进一步总结该区成矿控制因素,认为区域上找矿前景广阔。     

水泥粉煤灰加固有机质土的试验研究

对于高有机质含量的泻湖相软土,单纯采用水泥不能有效提高该软土的力学性能,因此提出了采用水泥和粉煤灰作为固化剂的加固方法。通过不同水泥掺入量、粉煤灰掺入量和龄期下水泥土的无侧限抗压强度试验,分析了水泥粉煤灰固化土的强度规律和变形规律,探讨了水泥和粉煤灰加固高有机质含量软土的机理。结果表明,粉煤灰对于水泥试块的早期强度影响较小,对后期强度影响较大;粉煤灰最佳掺入量为12％,超过此掺入量水泥土强度反而会降低,粉煤灰水泥土的破坏应变、E50也在粉煤灰掺量为12％时分别达到最低值和最大值。水泥掺加粉煤灰可有效地提高高有机质含量软土的强度。     

长江流域沿江镉异常源追踪与定量评估的方法技术研究:以长江流域安徽段为例

长江全流域性的Cd异常是被中国正在进行的多目标地球化学调查发现的重大生态环境问题。以长江流域安徽段为研究对象,对沿江镉异常源追踪与定量评估的方法技术进行了系统研究。通过对安徽段长江干流及其主要支流悬浮物中元素含量的测量查明:悬浮物是流域内重金属元素大跨度迁移的主要载体;Cd在悬浮物中的富集程度远远大于其他重金属元素,这或许正是Cd可以形成沿江流域性异常的主要原因;长江干流悬浮物中重金属元素含量的变化明显受到沿江支流的影响。安徽段长江干流及其主要支流重金属元素输出通量定量计算结果表明:秋蒲河是安徽段重金属元素输出通量最大的支流,每年在安徽段长江两岸土壤中沉积下约4.45t的Cd。利用悬浮物加密测量、1∶5万土壤测量和岩石测量对顺安河流域Cd异常源追踪结果显示:内生金属矿床特别是铅锌矿是悬浮物中Cd的最大的供应源。采用河漫滩沉积物分层采样技术和同位素测年技术,初步恢复了研究区Cd等重金属元素沉积和污染的地球化学历史,对研究区Cd等重金属元素异常的未来演变趋势进行了预警预测。     

准噶尔盆地中拐地区下侏罗统层序地层特征与聚煤控制因素分析

在分析前人对准噶尔盆地层序地层学研究成果的基础上,综合应用岩心、测井和地震资料,对准噶尔盆地西北缘中拐地区下侏罗统进行层序地层划分,总结了层序和体系域界面的识别标志,将下侏罗统划分为4个三级层序和7个体系域,同时叙述了各三级层序的结构特征。通过对层序内含煤岩系的发育特点分析,发现其主力煤层主要发育在JSQI和JSQ3湖侵体系域中,本文作者认为研究区内湖侵时期为有利的聚煤时期,聚煤作用主要受构造沉降、物源供给、气候和沉积环境等因素的控制。     

Spatial distribution features and environment effect of heavy metal in intertidal surface sediments of Guanhe estuary, Northern Jiangsu Province

In northern Jiangsu coastal zone area, Guanhe River is the biggest river and has the best navigation conditions among rivers which flow into the Yellow Sea. The grain sizes show gradual increase from the high intertidal zone to lower intertidal zone. The heavy metal values have slight changes along both sides of the river mouth, but show an evident change perpendicular to the tidal flat. In the latter case, they show a good correlation with grain size fluctuation, that is, the heavy metal values gradually decline when the grain size increases from the high intertidal zone to the lower intra-tidal zone. Analyses of the heavy metal elements show that on the Guanhe estuary surface sediment, the content of the elements Hg, As and Cu is above background values; Pb and Zn contents are rather close to the background values; and Cd content is less than the background values. The element Hg comes out to be harmful in a medium level to ecological environment, while the elements of Cr, As, Cu, Pb, Zn and Cd fall in a safe range of MPL. On the whole, Guanhe estuary tidal flat is not very harmful to the ecology in terms of the heavy metals. __________ Translated from Marine Geology & Quaternary Geology, 2007, 27(5): 23–32 [译自: 海洋地质与第四纪地质]     

Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.     

Environmental geochemistry of the River Gomti: A tributary of the Ganges River

Water and sediment samples collected from the Gomti River, a tributary of the Ganges River system, during the postmonsoon season have been analyzed to estimate major elemental chemistry. Water chemistry of the River Gomti shows almost monotonous spatial distribution of various chemical species, especially because of uniform presence of alluvium Dun gravels throughout the basin. The river annually transports 0.34×10⁶ tonnes of total suspended material (TSM) and 3.0×10⁶ tonnes of total dissolved solids (TDS), 69 percent of which is accounted for by bicarbonate ions only. Samples collected downstream of the city of Lucknow show the influence of anthropogenic loadings for a considerable distance in the river water. Na⁺, Cl^–, and SO₄ ^2– concentrations build up downstream. The bed sediment chemistry is dominated by Si (36 percent), reflecting a high percentage of detrital quartz, which makes up about 74 percent of the mineralogy of the bed sediments in the River Gomti. The average Kjeldahl nitrogen concentration (234 g/g) indicates indirectly the amount of organic matter in the sediments. The Hg concentration in sediments has been found to be higher (average 904 ppb) than the background value. The suspended sediments are well sorted, very finely skewed, and extremely leptokurtic, indicating a low energy condition of flow in the Gomti River. The influence of chemical loads in the Gomti has been found to be small or nonexistent on the Ganges River, perhaps because the water discharge of the Gomti (1.57 percent) to the Ganges is quite low.     

The stellar populations within theρ Oph cloud cores

We have obtained infrared colors and limiting magnitudes from 1.25–4.8µm for a sample of 26 of the cm continuum radio sources located in the core of the Oph molecular cloud. Their colors demonstrate that the majority of the sources appear to be heavily reddened objects surrounded by circumstellar accretion disks. In these cases the radio emission most likely diagnoses accretion driven energetic outflow phenomena: either ionized winds or possibly synchrotron emission from shocked gas associated with stellar jets.     

Densities of Huanghe River estuary and Bohai Bay waters

The densities of 36 water samples from the Huanghe River estuary and Bohai Bay were determinedby a magnetic float densimcter under three temperatures from 15℃ to 25℃.All the measured densities ofsamples were greater than that of the values calculated from the International Equation of State of Seawater.The differences between the measured and calculated densities increased with the decrease of salinities.The dif-ferences appeared exponentially correlated with[Ca~(2+)]/s,[Mg~(2+)]/s and[SO_4~(2-)]/s,and had"s"type curverelationship with the alkalinity in all salinity range.But in the salinity ranging from 25.72 to 31.57,therelationships were all linear.The density difference can be estimated from the equation △ρ（10~3kg·m~(-3)）=（-2.79+236.5([Ca~(2+)]/s)/(-9.7464×10~（-3）+[Ca~(2+)]/s).It was the high alkalinity and[Ca~(2+)]/s that resulted in the measured densi-ties of seawaters being higher than the calculated densities in the Huanghe estuary and Bohai Bay.