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121.
Compositional Geometry and Mass Conservation 总被引:1,自引:0,他引:1
Robert F. Shurtz 《Mathematical Geology》2003,35(8):927-937
A geometrical structure is imposed on compositional data by physical and chemical laws, principally mass conservation. Therefore, statistical or mathematical investigation of possible relations between data values and such laws must be consistent with this structure. This demands that geometrical concepts, such as points that specify both mass and composition in linear space, and lines in projective space that specify composition only, be clearly defined and consistent with mass conservation. Mass thus becomes the norm in composition space in place of the Euclidean norm of ordinary space. Coordinate transformations inconsistent with this geometry are accordingly unnatural and misleading. They are also unnecessary because correlation arising from the constant mass presents no unusual difficulty in the analysis of the underlying quadratic form. 相似文献
122.
Donna L. Whitney Christian Teyssier Annia K. Fayon Michael A. Hamilton Matt Heizler 《Tectonophysics》2003,376(1-2):37-60
Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m2. Calculated seismic velocities (Vp) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm3. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (LaN/YbN=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton. 相似文献
123.
A. Heusel-Waltrop K. Diehl S. K. Mitra H. R. Pruppacher 《Journal of Atmospheric Chemistry》2003,44(2):211-223
Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO2 by water drops containing heavy metal ions for both, large and small water drops did agree with the model results. 相似文献
124.
The effect of elevated nitric acid concentrations on cloud particle number concentrations and sizes of mixed phase cirrus cloud (containing both supercooled liquid and frozen ice particles) is studied using a detailed multicomponent condensation model. Our model calculations suggest that high nitric acid volume mixing ratios (VMRs), corresponding to upper tropospheric measurements, can increase the ice crystal number concentrations substantially especially in the case of freezing of non-activated solution droplets (as opposed to freezing of supercooled cloud droplets). This is due to increased droplet sizes caused by nitric acid absorption and the resulting uptake of water. 相似文献
125.
XU Jiongxin Professor Institute of Geography Chinese Academy of Sciences Beijing China 《国际泥沙研究》1997,(3)
LINTRODUCTIONThetributariesofmiddleYellowRiverarefamousintheworldforthehighestsuspendedsedimentconcentrationandsedimentyield.Forexample,atWenjiachuanstationofKuyeheRiverthemeasuredhighestsuspendedconcentrationis1700kg/m',andthemeanannualsedimentyieldis25000t/(kln'.a).Theformationofhyperconcentratedflowsandtheirinfluenceonerosionprocessesareofgreatimportancenotonlyfromatheoreticalpointofviewbutalsoforpracticalpurposes.Therefore,scientistsfromChinaandallovertheworldhavedrawntheirintensio… 相似文献
126.
铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究 总被引:1,自引:0,他引:1
在030mol/LHAc介质中,Pb(Ⅱ)与7_碘_8_羟基喹啉_5_磺酸(试铁灵,Feron)的络合物于-054V(vs.SCE)产生一尖锐的极谱波,加入溴化十六烷基三甲基铵(CTMAB)显著增敏,可使极谱波增高约4倍。峰电流与Pb(Ⅱ)浓度在96×10-9~48×10-6mol/L呈良好的线性关系,检出限为48×10-9mol/L。用多种电化学方法研究了该极谱波的性质及电极反应机理表明,络合物组成比为nPb(Ⅱ)∶nFeron=1∶1,极谱波为吸附波,峰电流由中心离子Pb(Ⅱ)还原产生,电子转移数为2。试验了多种离子对峰电流的影响,拟定的方法用于矿样分析,结果与原结果相符。 相似文献
127.
128.
狐狸山金矿区,在无蚀变作用参与的韧性变形过程中,岩石化学成分发生了明显的变化。但大多数微量元素含量变化不大,稀土元素配分模式基本不变,它们可以反映原岩的特点。蚀变糜棱岩型矿体与围岩相比,稀土配分模式、亲硫元素Au、Ag、Cu和两性元素As、Sb含量差别显著,尤其是Au含量,前者是后者的百倍~几万倍,金的成矿作用主要与韧性变形后期富金流体的蚀变作用关系密切。 相似文献
129.
Characteristics of Volcanic Rocks in the Shoshonite Province, Eastern China, and Their Metallogenesis 总被引:17,自引:0,他引:17
Wang Dezi Ren Qijiang Qiu Jiansheng Chen Kerong Xu Zhaowen Zeng Jiahu Department of Earth Sciences Nanjing University Nanjing Jiangsu 《《地质学报》英文版》1996,70(3):246-259
The shoshonite province in eastern China is characterized by extensive distribution (ca. 80000 km2) of Late Jurassic-Early Cretaceous (165-100 Ma) shoshonite series with subordinate high-K calc-alkali series. It was formed in a dominantly tensile stress field. In comparison with their analogues in island arcs and active continental margins in other countries, the volcanic rocks in the shoshonite province have their specific characteristics in petrology, mineralogy and geochemistry as well as related mineralization association, which are the comprehensive reflection of the special composition and structure of the mantle and crust of the province and the special Mesozoic regional tectonic setting. 相似文献
130.
Magmatic arc metamorphism: petrology and temperature history of metabasic rocks in the Coastal Cordillera of northern Chile 总被引:6,自引:0,他引:6
We investigated the metamorphic cooling history of underplated magmatic rocks at midcrustal depth. Granulites and amphibolites occur within the Jurassic magmatic belt of the Coast Range south of Antofagasta in northern Chile between 23°25' and 24°20' S. The protoliths of the metamorphic rocks are basic intrusions of Early Mesozoic age. They are part of the magmatically formed crust, and the essentially dry magmas were emplaced in an extensional regime. The granulites (clinopyroxene–orthopyroxene–plagioclase) show all stages of fabric development from magmatic to granoblastic fabrics. Pyroxene compositions were reset at temperatures around 800° C independent of the stage of textural equilibration. The granulites were partially amphibolitized at upper amphibolite facies temperatures of 600–700° C. Following cooling, a possible reheating to greenschist facies temperatures around 500° C is indicated by prograde zoning in magnetite–ilmenite pairs. Mineral assemblages are not suitable for barometry, but a conservative estimation of the garnet-in reaction at given whole-rock compositions suggests maximum pressures in the granulite facies of around 5 kbar, and similar pressures are indicated by phengite barometry for the greenschist facies. The P–T path of granulite–amphibolite metamorphism is one of slow cooling from magmatic temperatures with heterogeneous deformation. The thinning of the pre-Andean (Precambrian–Triassic) crust was apparently compensated by the magmatic underplating and this special tectonomagmatic setting caused the prolonged residence of the accreted rocks at midcrustal levels. 相似文献