Elastic properties and stability of coexisting 3T and 2M 1 phengite polytypes

The elastic properties of coexisting natural 3T and 2M ₁ phengite samples (Cima Pal, Sesia Zone; Val Savenca; Western Alps, Italy) with similar chemical compositions have been studied by room temperature–high pressure powder diffraction, using synchrotron radiation on the ID9A beam-line at ESRF (Grenoble, France). The P–V curves have been modelled by the Birch–Murnaghan model; a third-order expansion fitted to the experimental data yields for 3T and 2M ₁ K ₀=60.4(±0.7) GPa, K′=5.79(±0.11) at V ₀=703.8851 ų, and K ₀=57.3(±1.0) GPa, K′=6.97(±0.24) at V ₀=938.8815 ų, respectively. The relative stability of 3T vs. 2M ₁ has been explored as a function of pressure and temperature in terms of configuration and deformation contributions to the Gibbs energy, using the elastic properties determined here and other thermodynamic parameters from earlier investigations. The results presented agree with the hypothesis of stability of the 3T polytype in the high pressure regime.     

Occurrence of salt water above fresh water in dynamic equilibrium in a coastal groundwater flow system near De Panne, Belgium

A salt water lens is found above fresh water under the shore between Dunkerque (France) and Nieuwpoort (Belgium). This inverse density distribution is in a dynamic equilibrium. It develops due to the infiltration of salt water on the back shore during high tide. Under this salt water lens, water infiltrated in the adjacent dune area flows towards the sea and discharges at the seabed. This water quality distribution differs from the classic salt water wedge under fresh water described in the literature. Here, the evolution to this water quality distribution is simulated with a density dependent numerical model. A large tidal range, shore morphology and a permeable groundwater reservoir are the main conditions for the observed water quality distribution. By altering these conditions, intermediate water quality distributions between the classic salt water wedge and the one discussed here develop. Based on these simulations, it is expected that similar kinds of inverse density distribution could be present in a number of coastal areas, which have tides, a gently sloping shore and a permeable substratum.     

Petrogenesis and tectonic setting of Cadomian felsic igneous rocks, Sandıklı area of the western Taurides, Turkey

In the Sandıklı (Afyon) region, western Taurides, the Late Proterozoic rocks of the Sandıklı basement complex are composed of low-grade meta-sedimentary rocks (Güvercinoluk Formation) intruded by felsic rocks (Kestel Cayı Porphyroid Suite, KCPS). The KCPS is a deformed and highly sheared, dome-shaped rhyolitic body with a granitic core. Quartz porphyry dikes intrude both the slightly metamorphic igneous and the sedimentary rocks of the basement complex. Both the quartz porphyries and rhyolites were converted into mylonites with relict igneous textures. Geochemical data show that these felsic igneous rocks are subalkaline and mainly granitic in composition with SiO₂ >72 wt% and Al₂O₃ >11.5 wt%. The chondrite-normalized incompatible trace element patterns are characterized by distinct negative Rb, Nb, Sr, P, Ti, and Eu with enrichment in Th, U, La, Ce, Nd, Sm, and Zr. The REE patterns of the felsic rocks indicate a strong enrichment in LREE but display slightly flat HREE patterns. According to geochemical characteristics and petrogenetic modeling, extrusive and intrusive rocks of the KCPS were probably derived from an upper continental crustal source (partial melting of granites/felsic rocks) by 18–20% fractional melting plus 18–20% Rayleigh fractional crystallization, which seems to be the most effective igneous process during the crystallization of the KCPS. Single zircon age data from the granitoids and fossils from the disconformably overlying sedimentary successions indicate that the metamorphism and the igneous event in the Taurides are related to the Cadomian orogeny. Based on the geological, geochemical and petrogenetic correlation of the post-collisional granitoids it is further suggested that the Tauride belt in western central Turkey was in a similar tectonic setting to the Gondwanan terranes in North Africa (Younger Granitoids) and southern Europe (Spain, France, Bohemia, Brno Massifs) during the Late Cadomian period.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.     

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

利用三维地震在戈壁沙漠区解决复杂地质构造问题

在分析戈壁沙漠地区地球物理特征的基础上，针对性的提出了解决煤田地质构造问题的方法，包括三维地震野外施工方法的选取、施工因素的选择、资料处理手段；并以获得的实际地质成果证实三维地震在解决复杂地质构造问题的可行性。     

陆相油藏中砂泥岩互层时移地震遮掩效应及其对时移地震资料解释的影响

从差异波形特征的角度出发,分析时移地震差异波形特征与砂泥岩互层油藏中油层速度变化的关系。通过建立由5层地层组成的楔形地质模型,运用褶积公式及时移地震求差公式,得到泥岩速度为2 400 m/s和砂岩速度为2 700m/s条件下,互层中砂岩速度变化±150 m/s的时移地震响应。研究结果表明:砂泥岩互层的差异波形是一个多峰复合波,泥岩夹层的厚度是决定差异波形特征的一个主要因素,并且存在一个临界值,即四分之一主波长;如果泥岩夹层的厚度小于这一临界值,就会发生遮掩效应,即顶部油层的时移地震响应可以掩盖中、下部油层的时移地震响应。