The global search and commercialization of alternatives and substitutes for ozone-depleting substances

The Montreal Protocol has halted 99% of global production of chemical substances that deplete stratospheric ozone, which protects life on earth from the harmful effects of ultraviolet (UVB) radiation. UVB causes skin cancer and cataracts, suppresses the human immune system, destroys plastics, and damages agricultural crops and natural ecosystems. Because ozone-depleting substances (ODSs) are powerful greenhouse gases, the Montreal Protocol also protects climate. From the authors’ perspectives in multiple roles as environmental entrepreneurs, practitioners, and authorities, this paper explains how individuals, companies, and military organizations researched, developed, commercialized and implemented alternatives to ODSs that are also safer for climate. With the benefit of hindsight, the authors reflect on what was neglected or done badly under the Montreal Protocol and present lessons learned on how Montreal Protocol institutions can be renewed and revitalized to phase down hydrofluorocarbons (HFCs).     

冲-洪积平原1:5万区域地质调查技术方法探索

首都地区规划建设工作主要分布于平原松散地层之上,第四纪地质研究显得尤为重要。依托近几年来在北京地区开展的平原覆盖区1:5万区域地质调查和活动断裂专项调查项目成果,系统总结了平原区第四纪区域地质调查与评价的主要工作手段和技术方法,及其在解决第四纪基础地质问题及生态环境中所起的作用。通过平原区区域地质调查工作,可查明第四纪精细地质结构、含水层分布特征,精确厘定活动断裂位置及其活动时限,探讨自然环境演化序列与人类活动关系等,为城市规划、重大工程建设和应急水源地水资源合理开采提供基础地学数据。研究成果对首都城市减灾防灾、生态环境演变研究具有重要地学支撑作用。     

两次强降水过程雨滴谱特征及差异

利用寿县观测站内的Parsivel激光雨滴谱仪结合观测站雨量数据及雷达基数据,分析了发生在2015年6月26—30日梅雨期间和2015年8月7—10日超强台风"苏迪罗"影响期间2次强降水过程的雨滴谱结构特征及其差异,拟合了雨强与雷达反射率因子之间的关系。结果表明:雨强的大小直接影响雨滴谱的特征参量,且随着雨强增大而增大;梅雨锋暴雨中1.0mm直径≤1.5mm的粒子所占比例最多,雨强贡献率最大;台风雨中0.75mm直径≤1.0mm的粒子所占比例最多,但1.0mm直径≤1.25mm的粒子对雨强的贡献最大,说明较大粒子对强降水的贡献较大。     

利用风廓线雷达研究郑州机场低空急流特征及其对飞行的影响

利用2016、2017年郑州机场高分辨率边界层风廓线雷达半小时平均观测资料, 对机场上空低空急流时空分布特征进行统计研究, 结果表明:夏末、秋季低空急流出现次数相对较少, 春季、夏初是高发时期, 冬季易出现较强的超低空急流, 只有春季风速从低层到高层呈现先增大后减小、再增大的变化过程, 8月末可能是急流的时空转换期; 夜间和凌晨是高发时段, 白天降低30%~40%, 一般情况下, 00—12时(世界时, 下同)急流较弱, 12时后明显增强向上发展, 19时开始减弱, 持续至21时; 急流中心最大风速一半以上在12~18 m/s, 高度集中在60~180 m和300~900 m, 超低空急流占大部分, 夜间出现最大风速的概率远高于白天; 低空急流发生高度大部分在飞机起飞或着陆的范围内, 使飞机复飞概率增加, 对夜间航班影响更大。      

柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

Regional and temporal changes in bivalve diversity off the south coast of Portugal

From 2000 to 2006, a total of 75 bivalve species were identified, varying from 29 (spring 2001) to 54 species (spring 2005) per year. Seasonal tendencies in diversity varied according the year, thus the interpretation of long-term and regional scales is essential before drawing any conclusions in other studies. Richness and diversity consistently decreased with depth and increased with sediment grain size (from low in very coarse sand to high in coarse silt). Diversity decreased progressively from 3 to 16 m depth, thus the harsher shallower environments (due to waves and tidal air exposure) showed greater diversity than the most stable areas. Communities in finer sediments were more diverse than those in coarser sand. Evenness showed patterns opposite to diversity, overall.Diversity and evenness maps (produced with multivariate universal kriging), showed that most geographic areas with greater diversity were farer from river outflows and wastewater treatment plants. Two types of geographic pattern were observed: areas with persistently greater bivalve diversity through time and areas that changed locally from year to year. This spatial analysis can be used to establish priority conservation areas for management purposes, and to analyse the persistency of regional diversity patterns. The area with most habitat heterogeneity (Sotavento) corresponded to greatest diversity.There was a positive relationship between Spisula solida and Chamelea gallina landings and bivalve diversity 2 years and 1 year later, respectively. Possibly, local fisheries, by selectively withdrawing the commercial numerically dominant species from the ecosystem, increased diversity 1 to 2 years later, as the ecological niches of the dominants are quickly filled by several other species thereby creating a more even community. On regional scales, no significant impact was found on long-term bivalve diversity in local fisheries,     

Sensitivity of penman-monteith reference crop evapotranspiration in Tao’er River Basin of northeastern China

A non-dimensional relative sensitivity coefficient was employed to predict the responses of reference crop evapotranspiration （ET0） to perturbation of four climate variables in Tao＇er River Basin of the northeastern China. Mean monthly ET0 and yearly ET0 from 1961 to 2005 were estimated with the FAO-56 Penman-Monteith Equation. A 45-year historical dataset of average monthly maximum/minimum air temperature, mean air temperature, wind speed, sunshine hours and relative humidity from 15 meteorological stations was used in the analysis. Results show that： 1） Sensitivity coefficients of wind speed, air temperature and sunshine hours were positive except for those of air temperature of Arxan Meteorological Station, while those of relative humidity were all negative. Relative humidity was the most sensitive variable in general for the Tao＇er River Basin, followed by sunshine hours, wind speed and air temperature. 2） Similar to climate variable, monthly sensitivity coefficients exhibit large annual fluctuations. 3） Sensitivity coefficients for four climate variables all showed significant trends in seasonal/yearly series. Also, sensitivity coefficients of air temperature, sunshine hours and wind speed all showed significant trends in spring. 4） Among all sensitivity coefficients, the average yearly sensitivity coefficient of relative humidity was highest throughout the basin and showed largest spatial variability. Longitudinal distribution of sensitivity coefficients for air temperature, relative humidity and sunshine hours was also found, which was similar to the distribution of the three climate variables.     

1：100万图号中行号、列号正误的快速判断方法

针对多个县(市)、区土地调查文字材料将1:100万图号中的行、列号用错而产生严重缺陷的事实,本人认真学习了"国家基本比例尺地形图分幅和编号"的基础知识,并总结归纳出简易的快速判断正误的方法,以杜绝类似差错的发生.     

城市文化战略导向下上海演艺空间的演变

摘要：后工业时代,文化资源的挖掘利用正日益成为各国政府引导城市更新、城市转型的重要手段。上海也积极利用各种文化资源来塑造国际文化大都市的形象。论文在回顾上海文化战略发展的基础上,分析了文化战略导向下上海对演出场馆资源的五种开发利用模式,并重点剖析了城市文化战略的实施对上海演出空间的塑造作用。在当前上海打造国际文化大都市的进程中,演出场馆的空间分布格局正日趋成形,同时,这种文化符号效力也带来了显著的空间效应,包括全球文化消费引领地的形成,艺术表演集聚区的初现以及演出空间的专业化拓展等。塑造与提升上海演艺文化空间格局成为上海加快建设国际文化大都市的必经之路。     

DFT对Rb+水合团簇及其相关性质的分析

运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1～12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1～12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。