Optical constants of amorphous and crystalline H2O-ice in the near infrared from 1.1 to 2.6 μm

Using new laboratory spectra, we have calculated the real and imaginary parts of the index of refraction of amorphous and crystalline H₂O-ice from 20 to 150 K in the frequency range 9000-3800 cm⁻¹ (1.1-2.6 μm) at a spectral resolution of 1 cm⁻¹. These optical constants can be used to create model spectra for comparison to spectra from Solar System objects. We also analyzed the differences between the amorphous and crystalline H₂O-ice spectra, including weakening of bands and shifting of bands to shorter wavelength in amorphous H₂O-ice spectra. We have also observed two spectrally distinct phases of amorphous H₂O-ice.     

Predicted interplanetary shocks/particles at Mars compared with in-situ observations: An overview

The biological and technological consequences of long-duration, solar-related, energetic particle radiation for manned/unmanned spacecraft warrant that consideration be given to providing reliable space weather predictions for future space missions to planet Mars. An account is, herein, provided of how the HAFv.2 numerical model was applied to predict the arrivals of four, flare-related, shocks at Mars generated during a >20-day active period on the Sun in March 1989, and of the arrival of another composite shock produced in association with a 10-day period of solar activity in December 2006. These predictions are compared with in-situ measurements of shock signatures at Mars recorded, in the former case, by the solar-low-energy-detector (SLED) and by the low-energy-telescope (LET) aboard the Phobos-2 spacecraft and, in the latter case, in data recorded by the ASPERA-3/IMA instrument aboard Mars Express. The success of the predictions is discussed and the requirement for further validation of the modeling technique using a large statistical sample pointed out. In-situ measurements made aboard Mars Express by the ASPERA-3/IMA experiment during the rising phase of Solar Cycle 24 can provide data relevant to such validation. The successful application of a SOLar Particle ENgineering COde (SOLPENCO), that estimates solar energetic particle (SEP) fluxes and fluences at the Earth, to the case of an energetic particle event at Mars (6 March 1989) is discussed. Measurements of SEP events recorded by the Solar TErrestrial RElations Observatory (STEREO) supplemented by Mars Express measurements can potentially allow the predictions of SOLPENCO to be further studied downstream using a large statistical sample. However, we are presently only at the beginning of our understanding of the complex Sun-Earth-Mars scenarios that give rise to shock/particle events in the close Martian environment.     

Water sorption on martian regolith analogs: Thermodynamics and near-infrared reflectance spectroscopy

The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10⁻⁵ to ∼0.3 mbar (relative humidity: 10⁻⁴ to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.     

Model Evidence for Interdecadal Pathway Changes in the Subtropics and Tropics of the South Pacific Ocean

Numerical simulations using a version of the GFDL/NOAA Modular Ocean Model(MOM 3) are analyzed to demonstrate interdecadal pathway changes from the subtropics to the tropics in the South Pacific Ocean.After the 1976-77 climate shift,the subtropical gyre of the South Pacific underwent significant changes,characterized by a slowing down in its circulation and a southward displacement of its center by about 5-10 latitude on the western side.The associated circulation altered its flow path in the northwestern part of the subtropical gyre,changing from a direct pathway connecting the subtropics to the tropics before the shift to a more zonal one after.This effectively prevented some subtropical waters from directly entering into the western equatorial Pacific.Since waters transported onto the equator around the subtropical gyre are saline and warm,such changes in the direct pathway and the associated reduction in equatorward exchange from the subtropics to the tropics affected water mass properties downstream in the western equatorial Pacific,causing persisted freshening and cooling of subsurface water as observed after the late 1970s.Previously,changes in gyre strength and advection of temperature anomalies have been invoked as mechanisms for linking the subtropics and tropics on interdecadal time scales.Here we present an additional hypothesis in which geographic shifts in the gyre structure and location(a pathway change) could play a similar role.     

Balancing groundwater conservation and rural livelihoods under water and climate uncertainties: An integrated hydro-economic modeling framework

In arid countries worldwide, social conflicts between irrigation-based human development and the conservation of aquatic ecosystems are widespread and attract many public debates. This research focuses on the analysis of water and agricultural policies aimed at conserving groundwater resources and maintaining rural livelihoods in a basin in Spain's central arid region. Intensive groundwater mining for irrigation has caused overexploitation of the basin's large aquifer, the degradation of reputed wetlands and has given rise to notable social conflicts over the years. With the aim of tackling the multifaceted socio-ecological interactions of complex water systems, the methodology used in this study consists in a novel integration into a common platform of an economic optimization model and a hydrology model WEAP (Water Evaluation And Planning system). This robust tool is used to analyze the spatial and temporal effects of different water and agricultural policies under different climate scenarios. It permits the prediction of different climate and policy outcomes across farm types (water stress impacts and adaptation), at basin's level (aquifer recovery), and along the policies’ implementation horizon (short and long run). Results show that the region's current quota-based water policies may contribute to reduce water consumption in the farms but will not be able to recover the aquifer and will inflict income losses to the rural communities. This situation would worsen in case of drought. Economies of scale and technology are evidenced as larger farms with cropping diversification and those equipped with modern irrigation will better adapt to water stress conditions. However, the long-term sustainability of the aquifer and the maintenance of rural livelihoods will be attained only if additional policy measures are put in place such as the control of illegal abstractions and the establishing of a water bank. Within the policy domain, the research contributes to the new sustainable development strategy of the EU by concluding that, in water-scarce regions, effective integration of water and agricultural policies is essential for achieving the water protection objectives of the EU policies. Therefore, the design and enforcement of well-balanced region-specific polices is a major task faced by policy makers for achieving successful water management that will ensure nature protection and human development at tolerable social costs. From a methodological perspective, this research initiative contributes to better address hydrological questions as well as economic and social issues in complex water and human systems. Its integrated vision provides a valuable illustration to inform water policy and management decisions within contexts of water-related conflicts worldwide.     

Assessing uncertainties in dust emission in the Aral Sea region caused by meteorological fields predicted with a mesoscale model

This study investigates how the choice of the planetary boundary layer (PBL) parameterization and dust emission scheme affects the prediction of dust entrainment simulated with a regional mesoscale model. For this analysis we consider a representative dust episode which occurred on April 2001 in the Aral Sea region. The meteorological fields were simulated using the PSU/NCAR MM5 modeling system considering two different boundary layer parameterizations. In each case, emitted dust fluxes were computed off-line by incorporating MM5 meteorological fields into the dust module DuMo. Several dust emission schemes with a prescribed erodible fraction and fixed threshold wind speed were the subject of our analysis. Implications to assessment of the anthropogenic fraction of dust emitted in the Aral region were investigated by conducting the full, half, and no lake modeling experiments.Our results show that the discrepancies in dust fluxes between the two different PBLs are much higher compared to the discrepancy associated with the use of considered dust production schemes. Furthermore, the choice of the PBL affects the timing and duration of a modeled dust event. We demonstrate that different combinations of the PBL parameterization and wind- or friction velocity-driven dust emission schemes can result in up to about a 50% difference in predicted dust mass caused by the Aral Sea desiccation. We found that the drying-up of the Aral cannot only affect the dust emission by expanding the source area, but also by affecting atmospheric characteristics, especially winds. These competitive factors add further complexity to quantification of the anthropogenic dust fraction in the region.     

极地冰盖物质平衡的最新进展与未来挑战

准确地探明冰盖物质平衡状况,对于研究全球变暖背景下海平面变化具有重要的意义,自IPCC AR4(政府间气候变化专门委员会第四次报告)以来,极地冰盖物质平衡的研究取得了很大进展。本文总结并对比了用卫星测高(雷达测高和激光测高)、物质收支测量和重力测量等方法得到的冰盖物质平衡评估结果,综述了冰盖数值模拟研究在预测冰盖未来的变化趋势以及由此对海平面造成的影响等方面取得的进展,并立足于中国当前的极地冰盖物质平衡研究现状,提出了该研究所面临的挑战。     

基于生态水文学的地下水资源管理研究——以延庆盆地为例

传统的地下水资源管理往往只关注地下水位的变化,而很少考虑变化的水位会对区域生态系统产生什么样的影响。本文在生态水文模拟的基础上提出了一种基于生态水文学的地下水资源管理新方法。该方法耦合土壤水分与地下水位,考虑植物在水分胁迫下的蒸腾抑制机理,通过土壤水分亏缺与植物水分胁迫耦合水文过程与植物响应,进行基于过程的分布式生态水...     

Particle transport and distribution on the Mars Science Laboratory mission: Effects of triboelectric charging

We report on the nature of fine particle (<150 μm) transport under simulated martian conditions, in order to better understand the Mars Science Laboratory’s (MSL) sample acquisition, processing and handling subsystem (SA/SPaH). We find that triboelectric charging due to particle movement may have to be controlled in order for successful transport of fines that are created within the drill, processed through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample handing system, and delivered to the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments. These fines will be transferred from the surface material to the portioner, a 3 mm diameter, 8 mm deep distribution center where they will drop ∼2 cm to the instrument inlet funnels. In our experiments, movement of different material including terrestrial analogs and martian soil simulants (Mars Mojave Simulant - MMS) resulted in 1-7 nanocoulombs of charge to build up for several different experimental configurations. When this charging phenomenon occurs, several different results are observed including particle clumping, adherence of material on conductive surfaces, or electrostatic repulsion, which causes like-charged particles to move away from each other. This electrostatic repulsion can sort samples based upon differing size fractions, while adhesion causes particles of different sizes to bind into clods. Identifying these electrostatic effects can help us understand potential bias in the analytical instruments and to define the best operational protocols to collect samples on the surface of Mars.     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.