煤中有害物质及其对环境的影响研究进展

综述了煤中有害物质的种类、分布赋存特征及对环境的影响研究进展。探讨了煤中黄铁矿的形态、世代交替、有机硫的结构及煤中硫的地质成因。阐述了煤中微量元素的种类、地质分布、赋存状态、迁移聚集机制及其环境危害。并对煤及燃煤产物中多环芳烃的种类、赋存规律及对环境和人类健康的危害进行了详细阐述。最后指出了煤中有害物质研究中存在的问题与发展趋势。     

大兴迭隆起隐伏岩溶水资源保护措施分析

以大兴迭隆起地区隐伏岩溶含水系统为研究对象,通过对地质、水文地质条件、地下水开发利用现状的分析论述,从水均衡的角度利用反算法开展资源计算评价,评价结果显示基岩岩溶水处于严重超采状态,并进一步结合岩溶水补径排条件分析了按照目前开采状况将可能引起的环境问题,从可持续利用角度提出大兴迭隆起岩溶地下水的保护措施。     

A new locality of palygorskite-rich clay from the southeastern Yucatán: a potential material source for environmental applications

A palygorskite unit was discovered in a road cut of undifferentiated Tertiary limestone between the villages of El Pariso and San Roman (18°49.309N, 88°37.861W) in the southeastern Yucatán Peninsula, Mexico. This is the southern most locality of a clay-rich sedimentary unit reported in the literature for the Tertiary carbonates of the Yucatán Peninsula. This occurrence indicates a much wider range of palygorskite-rich clay deposition than previously recognized. The lithology is 99% clay and 1% sand to silt size diagenetic quartz grains. The clay consists of approximately 85% palygorskite, 15% montmorillonite and trace amounts of titanium oxides. EDS analyses on palygorskite are largely consistent with sedimentary palygorskites from other coastal marine settings, however palygorskite has a low total Fe content (average = 0.40 wt% expressed as Fe₂O₃) compared to many other sedimentary palygorskites. Montmorillonite chemical compositions are typical and compared to the palygorskite have substantially higher Fe₂O₃ concentrations (average = 3.90 wt%). The low percentage of coarse grains in the lithology combined with a high proportion of palygorskite and lack of detrimental trace minerals suggest the deposit is of industrial grade; however, it has limited reserves (6,000 m³). The unit could be potentially used in a wide array of environmental applications which are needed in the region including liners for landfills and constructed wetlands. The unit is in a geographic location which would serve the expanding economy of the region. This resource has the potential to have great impact on the quality of the local environment and the economy of a region under great environmental threat.     

华北地区人类文化遗址的地球化学环境演变

在地球演化历史上,第四纪是人类诞生、发展和壮大的时代,它所形成的地质产物中记录了丰富的生态环境信息。河北省境内第四纪岩石地层(泥河湾组、赤城组、马兰组、迁安组)的风化指数CIA,Fe2O3/FeO,Fe/Mn等地球化学参数可作为年均气温、年均降雨量等气候因子的近似代用指标;华北地区人类文化遗址所在地水系沉积物中Hg,Sn和Au等元素含量随人类文明的演进而阶段性增高。这一结果表明,人类为了适应不断变化的自然地理环境(寒冷、干旱),不得不进行技术创新,从而产生了农业耕作、工业革命及现代信息产业等文明进步成果,但与此同时,却也导致了地质环境的人为污染,甚至可能引发全球温室效应。     

水平荷载下导管架平台桩基础的非线性有限元分析

导管架平台桩基础的控制荷载主要为风荷载、波浪荷载、地震荷载等水平荷载,为研究水平荷载下导管架平台桩基础的承载特性,采用非线性有限元分析方法对水平荷载下桩-土之间的相互作用进行研究,提出了有效模拟桩基水平承载特性的有限元模型,分析了模型桩的刚度、直径、土质参数中水平土压力系数、剪胀角对桩基承载特性的影响及水平荷载下群桩承载特性,并将有限元计算结果与API规范及模型试验结果进行对比。研究结果表明,非线性有限元分析方法分析水平荷载下桩-土相互作用是可行的,计算结果可为导管架平台的桩基设计提供参考。     

Magnitudes, spatial scales and processes of environmental antimony mobility from orogenic gold–antimony mineral deposits, Australasia

Antimony (Sb) is strongly concentrated into hydrothermal mineral deposits, commonly with gold, in metasedimentary sequences around the Pacific Rim. These deposits represent potential point sources for Sb in the downstream environment, particularly when mines are developed. This study documents the magnitude and scale of Sb mobility near some mineral deposits in Australia and New Zealand. Two examples of New Zealand historic mining areas demonstrate that natural groundwater dissolution of Sb from mineral deposits dominates the Sb load in drainage waters, with Sb concentrations between 3 and 24 μg/L in major streams. Mine-related discharges can exceed 200 μg/L Sb, but volumes are small. Sb flux in principal stream waters is ca 1–14 mg/s, compared to mine tunnel fluxes of ca 0.001 mg/s. Dissolved Sb is strongly attenuated near some mine tunnels by adsorption on to iron oxyhydroxide precipitates. Similar Sb mobilisation and attenuation processes are occurring downstream of the historic/active Hillgrove antimony–gold mine of New South Wales, Australia, but historic discharges of Sb-bearing debris has resulted in elevated Sb levels in stream sediments (ca 10–100⁺ mg/kg) and riparian plants (up to 100 mg/kg) for ca 300 km downstream. Dissolution of Sb from these sediments ensures that river waters have elevated Sb (ca 10–1,000 μg/L) over that distance. Total Sb flux reaching the Pacific Ocean from the Hillgrove area is ca 8 tonnes/year, of which 7 tonnes/year is particulate and 1 tonne/year is dissolved.     

在某污染的工业废物填埋场环境水文 地质评价中的同位素水文学研究

本文论述了某污染的工业废物填埋场场址的地质、水文地质条件,应用水化学方法、环境同位素技术(地下水中氚及氢、氧稳定同位素)和同位素单孔示踪技术等同位素水文学领域中的新方法对区内地下水的活动条件以及填埋场场址区分布的第四系孔隙潜水和第三纪红层孔隙-裂隙水的成因进行了分析,测量并确定了填埋场下部地下水的流速及流向。研究结果表明场区地下水的运动与地表水无直接水力联系。污染的工业废物填埋后不会通过地下水的迁移造成对地表水的污染,进而证实填埋场的地质、水文地质条件对处置污染的工业废物是安全可靠的。     

地震作用下预应力锚索加固顺层岩坡极限分析

针对地震作用下预应力锚索加固顺层岩坡典型模型,提出了一种地震作用下预应力锚索加固顺层岩坡的极限分析改进方法,该方法考虑了边坡极限状态时锚索的受力变化。基于岩体刚性假设并考虑滑移过程锚索受力变化,结合极限平衡法推导出边坡加固预应力锚索的受力变化公式;地震作用仅考虑地震波传播至滑动面时产生的透射波对边坡稳定性的影响,从功率的角度出发,结合极限分析上限法与强度折减法,考虑预应力锚索受力变化,推导出地震作用下预应力锚索加固顺层岩坡的动安全系数计算理论公式;结合算例,采用考虑与不考虑滑移过程锚索受力变化两种计算方法,分析了在不同入射波波幅、入射角度及滑动面黏聚力、内摩擦角条件下两种方法计算结果的差异。算例结果表明：考虑与不考虑滑移过程锚索受力变化计算方法,计算得出的动安全系数变化规律一致,但考虑滑移过程锚索受力变化的改进计算方法得出的动安全系数动态变化幅度明显更小,反映了锚索的抗震作用效果,可为地震作用下该类型岩坡的预应力锚索加固设计分析提供参考。     

现代侵蚀作用核素示踪研究新进展

利用放射性核素示踪环境地球化学过程是国际地球科学的前缘课题。介绍了利用宇宙线成因的短寿命散落核素⁷Be示踪土壤季节性侵蚀及其与湖泊沉积耦合关系的最新研究进展;证实了利用核爆炸散落核素¹³⁷Cs示踪累计性土壤侵蚀和沉积计年的可靠性;阐述了²²⁶Ra和²²⁸Ra在土壤中比活度的形态变化分异具有很好的侵蚀－堆积示踪价值;揭示了在不同生物化学条件下,²¹⁰Pb的行为特征和影响因素,并将²¹⁰Pb_ex示踪碳酸盐岩区域土壤侵蚀速率结果与湖泊沉积速率相耦合,证明了利用²¹⁰Pb示踪土壤侵蚀的可行性。     

中国交通行业实施环境经济政策的协同控制效应研究

目前,交通行业已成为中国局地大气污染物和温室气体的重要排放来源之一,而且随着交通运输规模的不断扩大,与工业和生活排放相比,交通排放贡献占比呈相对增加趋势.文中构建了"CGE-CIMS联合模型",对中国交通行业实施环境经济政策的局地大气污染物和CO2协同控制效应进行量化评估.结果显示,与BAU情景相比,环境税、碳税、成品...