Noble gas tracers for characterisation of flow dynamics and origin of groundwater: A case study in Switzerland

The Grenchen aquifer system in the Swiss Plateau was extensively investigated in order to determine the extent of groundwater contamination and to assess the natural attenuation capacity. Environmental tracer data were applied to estimate groundwater travel times, mixing ratios, and evaluate groundwater origin. Recharge is basically possible in two distinct topographical areas, the immediate vicinity of the town of Grenchen and the elevated plateau of the first Jura Mountain ridge. Groundwater dating was performed with the ³H/³He dating method and supplemented by ⁸⁵Kr measurements. Stable isotope data (δ¹⁸O, δ²H) and dissolved noble gas concentrations allow the determination of the recharge temperature, which is correlated to the recharge elevation. Noble gas temperatures (NGT) decrease in the direction of groundwater flow and range from 10 to 13 °C in the upstream area of the town to 7–9 °C in the downstream river plain. This trend could suggest the admixture of water from the underlying limestone aquifer recharged under cooler infiltration conditions, e.g. at higher recharge elevations. However, it is shown in this study that the difference in NGT does not require such a recharge. Rather, increasing air temperatures over the last 40 years and the urban heat island effect could possibly explain most of the observed temperature shift. Furthermore, it is concluded that the downstream river plain is hydrologically disconnected from the upstream town area. Consequently most water from the town area is drained by the creek Witibach and recharge in the river plain is higher than previously assumed.     

Histopathology alterations and histochemistry measurements in mussel, Mytilus edulis collected offshore from an aluminium smelter industry (Norway)

Histopathological characteristics of specific organs express condition, and represent time-integrated impacts on the organism stemming from alterations at lower levels of biological organisation. As integrative parameters, histochemical investigations have proved to be sensitive tools to detect effects of chemical compounds.The objective of this study was to determine changes in the tissues of mussels collected at a PAH contaminated site compared to a reference site using histopathological and histochemical parameters: lipofuscin (LF) accumulation in mussel digestive gland, and lysosomal membrane stability (LMS), and using additional information provided by body burden analysis to compare the sensitivity of these parameters.The histochemical measurements for both LF and LMS gave a clear indication of a high level of stress in animals from the PAH contaminated site. This LF accumulation in lysosomes is the result of peroxidation of autophagocytosed proteins associated with protein aggregates and oxidatively damaged organelles. These measurements were able to detect the effects of PAHs, and showed a strong relationship with the body burden results.     

Developing environmental indices using fuzzy numbers ordered weighted averaging (FN-OWA) operators

Environmental indices (EI) constitute a common communication tool that is often used to describe the overall status of environmental systems (air, water and soil). EI development entails the use of mathematical operators to aggregate various non-commensurate input parameters in a logical manner. The ordered weighted averaging (OWA) operator is a general mean type operator that provides flexibility in the aggregation process such that the aggregated value is bounded between minimum and maximum values of the input parameters. This flexibility of the OWA operator is realized through the concept of orness, which is a surrogate for decision maker’s attitude. The type of input parameters also affects the choice of aggregation operators. If the input parameters are linguistic or fuzzy, the aggregation through OWA operators is not possible, and the use of fuzzy arithmetic is warranted. The concept of fuzzy number OWA (FN-OWA) operators is explored to handle situations in which one or more input parameter has fuzzy (or linguistic) values. The proposed approach is demonstrated using data provided in an earlier study by Swamee and Tyagi (ASCE J Environ Eng 126(5):451–455, 2000) for establishing water quality indices. Multiple hypothetical scenarios are also generated to highlight the utility and sensitivity of the proposed approach.     

湖泊自生碳酸盐氧同位素环境记录研究：（一）环境解释模型

湖泊自生碳酸盐氧同位素组成(δ18OC)在区域气候与环境变化方面的应用研究近年来发展迅速,成果令人瞩目,保存在各类湖泊沉积物柱芯中的δ18OC记录揭示了湖泊水温乃至汇水区域气温,湖泊不同水深处的水温差异、湖泊水位、降水δ18O、冰川融水δ18O、湖水盐度等重要的气候和环境信息。对前人通过研究来自不同类型湖泊、具不同曲线形态的δ18OC记录提出的多种环境解释模型进行了归纳。     

Do river deltas in east India retreat? A case of the Krishna Delta

The construction of multiple dams and barrages in many Indian River basins over the last few decades significantly reduced river flow to the sea and affected the sediment regime. More reservoir construction is planned through the proposed National River Linking Project (NRLP), which will transfer massive amounts of water from the North to the South of India. The impacts of these developments on fertile and ecologically sensitive deltaic environments are poorly understood and quantified at present. In this paper an attempt is made to identify, locate and quantify coastal erosion and deposition processes in one of the major river basins in India—the Krishna—using a time series of Landsat images for 1977, 1990 and 2001 with a spatial resolution ranging from 57.0 m to 28.5 m. The dynamics of these processes are analyzed together with the time series of river flow, sediment discharge and sediment storage in the basin. Comparisons are made with similar processes identified and quantified earlier in the delta of a neighboring similarly large river basin—the Godavari. The results suggest that coastal erosion in the Krishna Delta progressed over the last 25 years at the average rate of 77.6 ha yr^− 1, dominating the entire delta coastline and exceeding the deposition rate threefold. The retreat of the Krishna Delta may be explained primarily by the reduced river inflow to the delta (which is three times less at present than 50 years ago) and the associated reduction of sediment load. Both are invariably related to upstream reservoir storage development.     

An integrated lake-catchment approach for determining sediment source changes at Aqualate Mere,Central England

This paper raises fundamental questions about the sole use of paleolimnological techniques to identify sediment sources and develop catchment management plans. The concept of an integrated lake: catchment framework was established 30 years ago, yet paleolimnologists occasionally fail to appreciate the dynamics of the contributing catchment. This is especially critical when the predominant source of sediment accumulating in a lake is allochthonous. In this paper we argue that a detailed appraisal of catchment sources and investigation of historical documentary evidence is needed to identify and evaluate the relative significance of sediment sources. We used such an approach at Aqualate Mere, Shropshire, UK. Mineral magnetic and radionculide signatures of potential catchment sources and accumulating lake sediments were compared in an attempt to match the sources to sediments deposited in the Mere. Dated lake sediments indicate there has been an increase in sedimentation rate and the relative amount of minerogenic material delivered to the Mere over the last 200 years. In contrast to a previous study at the same site, there is no evidence to attribute this increase to an overspill from a nearby canal. Other catchment disturbances include landscaping in parkland surrounding the Mere in the early nineteenth century and drainage systems installed to improve catchment agriculture over the last ca. 150 years. Both activities may explain the change in sedimentation rates and types, independent of the hypothesized canal origin. Although our results exclude the canal as a major sediment source, identifying the contribution of other potential catchment sources remains problematic. ¹³⁷Cs inventories for the lake are similar to those recorded at a local reference site, suggesting little influx of ¹³⁷Cs-bearing topsoil, yet ¹³⁷Cs activities remain high in the upper 20–30 cm of the lake sediment profile, indicating a topsoil origin. Combined radionuclide and mineral magnetic signatures proved to be relatively poor discriminators of potential sources, and the high atmospheric pollution load from the West Midland conurbation has probably altered recent lake sediment signatures. Although further research is required to identify the origins of recent (last ca. 200 years) minerogenic sediment inputs to the Mere, we suggest that the combined lake: catchment approach offers a more rigorous method for understanding the impact of catchment disturbance than analysis of the paleolimnological record alone.     

From paleo to policy: partitioning the historical point and nonpoint phosphorus loads to the St. Croix River,Minnesota-Wisconsin,USA

Paleolimnological studies show that phosphorus (P) loads to the federally protected St. Croix River, a tributary of the Upper Mississippi River, have increased about threefold over the last century. Ongoing management efforts to protect and restore the river hinge on the question of whether the increased nutrient load results from point-source discharges or nonpoint runoff from agricultural intensification and urban expansion. Here we determine the historical contribution of point source phosphorus (P) loads to the St. Croix watershed from 1900–2000 A.D. Historical point source loads were estimated based on discharge volumes, demographics, industrial sources, wastewater technologies, and facility discharge records, where available. Sewering in the basin began in 1905, and since that time, there have been as many as 169 permitted point source dischargers basinwide, including municipal, industrial, and agricultural facilities. Early wastewater management typically discharged untreated sewage; technological advances had secondary treatment in place at most facilities by the 1960s–1970s and much of the municipal population was served by tertiary treatment by the 1990s. Peak nutrient discharges from point sources occurred in the 1960s–1970s. Detergent phosphorus bans instituted in the late 1970s for Minnesota and Wisconsin, greater use of land and groundwater effluent disposal, and improvements in treatment technology brought about decreases in P loads in the 1980s and 1990s. Point-source discharges were compared to historical total phosphorus loads estimated in a whole-basin phosphorus mass balance to calculate the historical contribution of point sources, anthropogenic nonpoint sources, and natural or background sources. We estimated 1990s point source loads at 48 t P yr⁻¹, which represents about 10% of the total phosphorus load (459 t P yr⁻¹, flow-corrected to 412 t P yr⁻¹) to the basin. Without further controls on nutrient inputs to the St. Croix River, annual flow-corrected P loads are projected to increase to 498 t P yr⁻¹ by the 2020s with point source phosphorus loading contributions at 65 t P yr⁻¹ or 13% of the total load. However, if we exclude background P loads to the St. Croix (166 t P yr⁻¹), recent nutrient loads are primarily from anthropogenic nonpoint sources. Point sources also contribute over 19% of the current and future phosphorus load that can be attributed to human activities in the watershed. Interstate and federal efforts to decrease P loading to the St. Croix River by 20% will need to target both point and nonpoint sources. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D.R. Engstrom served as guest editor of the special issue.     

Environmental decision-making under uncertainty using intuitionistic fuzzy analytic hierarchy process (IF-AHP)

Analytic hierarchy process (AHP) is a utility theory based decision-making technique, which works on a premise that the decision-making of complex problems can be handled by structuring them into simple and comprehensible hierarchical structures. However, AHP involves human subjective evaluation, which introduces vagueness that necessitates the use of decision-making under uncertainty. The vagueness is commonly handled through fuzzy sets theory, by assigning degree of membership. But, the environmental decision-making problem becomes more involved if there is an uncertainty in assigning the membership function (or degree of belief) to fuzzy pairwise comparisons, which is referred to as ambiguity (non-specificity). In this paper, the concept of intuitionistic fuzzy set is applied to AHP, called IF-AHP to handle both vagueness and ambiguity related uncertainties in the environmental decision-making process. The proposed IF-AHP methodology is demonstrated with an illustrative example to select best drilling fluid (mud) for drilling operations under multiple environmental criteria.     

Deriving hillslope sediment budgets in wildfire-affected forests using fallout radionuclide tracers

Information on post-fire sediment and nutrient redistribution is required to underpin post-fire catchment management decisions. Fallout radionuclide budgets (²¹⁰Pb_xs, ¹³⁷Cs and ⁷Be) were derived to quantify soil redistribution and sediment yield in forested terrain following a moderately severe wildfire in a small (89 ha) water supply catchment in SE Australia. Application of these techniques in burnt terrain requires careful consideration of the partitioning of radionuclides between organic and mineral soil components. Beryllium-7 and ²¹⁰Pb_xs were shown to be closely associated with ash, litter and soil organic matter whereas ¹³⁷Cs was more closely associated with subsurface coarse mineral soil. Comparison of the three tracer budgets indicated that the dominant sediment source areas were ridgetops and steep valley sideslopes, from which burnt surface material was conveyed to the stream network via pre-existing gullies. Erosion was predominantly driven by sheetwash, enhanced by soil water repellency, and modified by bioturbation which both supplies subsurface sediment and provides sinks for erosive overland flow. Footslope and riparian zones were not important sediment source areas. The estimated event-based (wildfire and subsequent rainfall) sediment yield is 58 ± 25 t km^− 2, based on fallout ⁷Be measurements. The upper estimate of total particulate phosphorus yield (0.70 kg ha^− 1) is more than 10 times that at equivalent unburnt sites. This illustrates that, soon after fire, burnt eucalypt forest can produce nutrient loads similar to those of agricultural catchments. The tracer budgets indicate that wildfire is an important control on sediment and phosphorus inputs to the stream network over the decadal timeframe and the pulsed nature of this release is an important concern for water quality management.     

横观各向同性饱和土体振动分析

基于饱和地基多孔介质理论,考虑了水土的惯性及耦合作用,研究了横观各向同性饱和地基的稳态振动问题。利用Hankel变换,得到饱和土的位移、应力、孔压的积分形式的解,由此利用数值Hankel逆变换给出了数值算例,最后讨论了横观各向同性饱和地基各向异性对地表竖向振幅的影响。