小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

2000—2019年秦岭南北实际蒸散发时空变化特征

基于遥感数据全面认识复杂地形单元实际蒸散发时空规律,对区域可持续水资源管理具有重要的意义。论文基于MODIS实际蒸散发(ET)数据,对2000—2019年秦岭南北ET时空变化特征进行分析,探究不同分区ET对植被变化的响应关系,进而识别ET趋势和年代变化的高相关海气环流因素。结果表明：① 在变化趋势上,以1000 m等高线为界,即秦岭地区北亚热带和山地暖温带的分界线,低海拔河谷地带为ET显著增加区,山地高海拔地区为ET下降区;② 除城市、乡镇周边地区,研究期间秦岭南北下垫面相对稳定,转为生态用地的活跃区主要分布在山地1000 m过渡带,其是ET与NDVI变化显著相关区,而1000 m以上高海拔地区两者相关性较低;③ ENSO、青藏高原北部气压异常,与秦岭山地、汉江谷地ET的趋势变化和年代波动显著相关,而西太平洋副热带高压与ET的趋势显著相关,与年代波动特征相关较弱。即发生中部型厄尔尼诺事件时,西太平洋副热带高压偏强,对流层低层形成异常反气旋,导致中国东部雨带北移,秦岭山地和汉江谷地降水偏少,气温偏高,ET往往偏大。研究结果启示：秦岭南北科学适应气候变化时,应关注秦岭山地、汉江谷地ET变化显著相关的环流信号;应深刻理解秦岭高海拔地区蒸散发下降趋势对区域水资源管理的影响。     

内蒙古孟恩陶勒盖银铅锌铟矿床成因研究

文章从地质特征及地球化学特征方面论证了孟恩陶勒盖矿床的成因。地质特征显示该矿床的形成与花岗岩之间不存在成因联系，矿床相对于岩浆岩围岩是后成的，花岗岩及断裂构造只是为矿床提供了储存空间。矿床地球化学特征显示该矿床的成因与可能位于深部的燕山期岩浆活动有关，成矿元素及硫主要来自岩浆，成矿流体以岩浆水为主。因此该矿床属于岩浆热液型多金属矿床。     

Geochemistry and Crustal Evolution of Volcano-sedimentary Successions and Orthogneisses in the São Gabriel Block, Southernmost Brazil — Relics of Neoproterozoic Magmatic Arcs

Precambrian metaplutonic rocks of the São Gabriel block in southernmost Brazil comprise juvenile Neoproterozoic calc-alkaline gneisses (Cambaí Complex). The connection with associated (ultra-)mafic metavolcanic and metasedimentary rocks (Palma Group) is not well established. The whole complex was deformed during the Brasiliano orogenic cycle. Both metasedimentary and metavolcanic rocks as well as metaplutonic rocks of the Cambaí Complex have been sampled for geochemical analyses in order to get constraints on the tectonic setting of these rocks and to establish a tectonic model for the São Gabriel block and its role during the assembly of West-Gondwana. The major element compositions of the igneous rocks (Palma Group and Cambaí Complex) indicate a subalkaline character; most orthogneisses have a calc-alkaline chemistry; many metavolcanic rocks of the Palma Group show signatures of low-K tholeiitic volcanic arc basalts. Trace element data, especially Ti, Zr, Y, Nb, of most igneous samples from both the lower Palma Group and the Cambaí Complex indicate origin at plate margins, i.e., in a subduction zone environment. This is corroborated by relative enrichment in LREE, low contents of Nb and other high field strength elements and enrichment in LILE like Rb, Ba, and Th. The data indicate the possible existence of two suites, an oceanic island arc and a continental arc or active continental margin. However, some ultramafic samples of the lower Palma Group in the western São Gabriel block indicate the existence of another volcanic suite with intra-plate character which possibly represents relics of oceanic island basalts (OIB). Trace element data indicate contributions from andesitic to mixed felsic and basic arc sources for the metasedimentary rocks. The patterns of chondrite- and N-MORB-normalized spider diagrams resemble the patterns of the igneous rocks, i.e., LILE and LREE enrichment and HFS depletion. The geochemical signatures of most igneous and metasedimentary samples and their low (⁸⁷Sr/⁸⁶Sr)_t ratios suggest only minor contribution of old continental crust.A geotectonic model for the São Gabriel block comprises east-ward subduction and following accretion of an intra-oceanic island arc to the eastern border of the Rio de la Plata Craton at ca. 880 Ma, and westward subduction beneath the newly formed active continental margin between ca. 750 and 700 Ma. The São Gabriel block represents relics of an early Brasiliano oceanic basin between the Rio de la Plata and Kalahari Cratons. This ocean to the east of the Rio de la Plata Craton might be traced to the north and could possibly be linked with Neoproterozoic juvenile oceanic crust in the western Brasília belt (Goiás magmatic arc).     

吉林基性超基性岩的地质特征及找矿方向

从多旋回大地构造演化的观点,分析吉林区域多旋回的构造运动,控制多旋回的基性超基性岩浆活动及其相应的成矿作用,认为与含镍有关的基性超基性岩体,主要受“台槽边界”赤峰—开源深断裂控制,沿深断裂一侧或两侧成带分布,分群集中。为铜镍矿床区域勘查工作,提供地质资料。     

Li_2O-(Mg、Zn、Ni)O-V_2O_5三元体系的相平衡

对Li_2O-(Mg、Zn、Ni)O-V_2O_5三元体系在500—800℃相图的研究表明,在每个系统内部都出现了一个依端员组分摩尔比为1:2:1的化合物。即橄榄石型的LiMgVO_4,硅铍石型的LiZnVO_4和尖晶石型的LiNiVO_4。不同的是,Li_2O-MgO-V_2O_5中发现了第二个三元相和一个固溶体。LiO_2-NiO-V_2O_6中得出一个固溶体,而LiZnNO_4中未得固溶体。     

流感世界大流行的气候特征

流感爆发与气候的剧烈变化有关。本文揭示了拉马德雷冷位相、拉尼娜、太阳黑子极值年、厄尔尼诺、低温冷害、沙尘暴、潮汐南北震荡异常与流行性感冒世界大流行相互对应的关系及其物理机制,对气候及其相关灾害的预测有重大科学意义。规律表明,在拉马德雷冷位相时期,全球强震、低温、飓风伴随拉尼娜、全球性流感伴随厄尔尼诺将越来越强烈。面对日益增大的全球灾害,长期气候预报意义重大。     

Planetary-Scale Wave Structures of the Earth’s Atmosphere Revealed from the COSMIC Observations

GPS radio occultation（GPS RO） method,an active satellite-to-satellite remote sensing technique,is capable of producing accurate,all-weather,round the clock,global refractive index,density,pressure,and temperature profiles of the troposphere and stratosphere.This study presents planetary-scale equatorially trapped Kelvin waves in temperature profiles retrieved using COSMIC（Constellation Observing System for Meteorology,Ionosphere,and Climate） satellites during 2006-2009 and their interactions with background atmospheric conditions.It is found that the Kelvin waves are not only associated with wave periods of higher than 10 days（slow Kelvin waves） with higher zonal wave numbers（either 1 or 2）,but also possessing downward phase progression,giving evidence that the source regions of them are located at lower altitudes.A thorough verification of outgoing longwave radiation（OLR） reveals that deep convection activity has developed regularly over the Indonesian region,suggesting that the Kelvin waves are driven by the convective activity.The derived Kelvin waves show enhanced（diminished） tendencies during westward（eastward） phase of the quasi-biennial oscillation（QBO） in zonal winds,implying a mutual relation between both of them.The El Nino and Southern Oscillation（ENSO） below 18 km and the QBO features between 18 and 27km in temperature profiles are observed during May 2006-May 2010 with the help of an adaptive data analysis technique known as Hilbert Huang Transform（HHT）.Further,temperature anomalies computed using COSMIC retrieved temperatures are critically evaluated during different phases of ENSO,which has revealed interesting results and are discussed in light of available literature.     

试论厄尔尼诺对广西气候异常影响的物理机制

通过对瓦克环流、哈德莱环流、副热带高压、台风等的分析 ,结合广西降水和气温异常状况 ,认为厄尔尼诺现象发生时 ,赤道东太平洋海温异常升高 ,使瓦克环流和哈得莱环流发生变化 ,引起副热带高压增强 ,台风生成数减少 ,从而产生广西前汛期偏涝 ,后汛期偏旱 ,全年气温偏暖的结果     

CMIP5模式中El Ni?o-EAWM关系的模拟对东亚冬季风模拟的影响

本文利用统计学的方法,评估了17个参加第五次国际耦合模式比较计划(CMIP5)的海气耦合模式对东亚冬季风(EAWM)年际变化的模拟。结果表明:多数模式对东亚冬季风的年际变化有一定的模拟能力,其中对东亚大槽年际变化的模拟最好;模式对东亚冬季主要系统的年际变化在空间上的模拟好于强度,对强度的模拟以偏弱为主;通过综合评估得到模拟能力好的模式有:bcc-csm1-1,CCSM4,HadCM3,NorESM1-M。针对模式间对冬季风年际变化模拟能力差别较大的现象,选取了4个模拟能力最好的模式和5个最差的进行讨论;通过评估El Ni?o对东亚冬季环流的影响,发现模式对El Ni?o与EAWM之间相互关系(El Ni?o-EAWM)的模拟能力是模式间对冬季风年际变化模拟偏差较大的原因之一,即对El Ni?o-EAWM模拟好的模式对东亚冬季风年际变化的模拟也好。