Distinct climate change synchronous with Heinrich event one, recorded by stable oxygen and carbon isotopic compositions in stalagmites from China

Uranium-series dating of oxygen and carbon isotope records for stalagmite SJ3 collected in Songjia Cave, central China, shows significant variation in past climate and environment during the period 20-10 ka. Stalagmite SJ3 is located more than 1000 km inland of the coastal Hulu Cave in East China and more than 700 km north of the Dongge Cave in Southwest China and, despite minor differences, displays a clear first-order similarity with the Hulu and Dongge records. The coldest climatic phase since the Last Glacial Maximum, which is associated with the Heinrich Event 1 in the North Atlantic region, was clearly recorded in SJ3 between 17.6 and 14.5 ka, in good agreement in timing, duration and extent with the records from Hulu and Dongge caves and the Greenland ice core. The results indicate that there have been synchronous and significant climatic changes across monsoonal China and strong teleconnections between the North Atlantic and East Asia regions during the period 20-10 ka. This is much different from the Holocene Optimum which shows a time shift of more than several thousands years from southeast coastal to inland China. It is likely that temperature change at northern high latitudes during glacial periods exerts stronger influence on the Asian summer monsoon relative to insolation and appears to be capable of perturbing large-scale atmospheric/oceanic circulation patterns in the Northern Hemisphere and thus monsoonal rainfall and paleovegetation in East Asia. Climatic signals in the North Atlantic region propagate rapidly to East Asia during glacial periods by influencing the winter land-sea temperature contrast in the East Asian monsoon region.     

Numerical modeling for analyzing thermal surface anomalies induced by underground coal fires

Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.     

Paleomagnetism and Detrital Zircon Geochronology of the Upper Vindhyan Sequence, Son Valley and Rajasthan, India: A ca. 1000 Ma Closure age for the Purana Basins?

The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including ⁸⁷Sr/⁸⁶Sr and δ ¹³C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α₉₅ = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α₉₅ = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period.     

Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO₂ in tilled land and shrub.     

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.     

Analysis of drivers governing temporal salinity and temperature variations in groundwater discharge from Altug Submarine Karst Cave (Kas-Turkey)

Salinity and temperature variations in groundwater discharge from the Altug submarine karst cave have been observed at 28 m below sea level for every 10 min between November 2004 and August 2005 to determine the drivers that govern the salinization. Comparisons between temporal trends of salinity and temperature with those of precipitation, air pressure, sea level and wind velocity revealed an apparent dominance of precipitation regime on the salinity and temperature variations. Spectral analyses applied to observations showed that the air pressure and sea level oscillations are affected by sun and moon tides which do not have an appreciable impact on the salinity and temperature variations. Annual rate of salinization in Altug cave seems inversely related to the inland groundwater head so that the maximum and minimum fresh water contributions occur at mid-spring and late-summer, respectively.     

Development of a 3D GIS and its application to karst areas

There is a growing interest in modeling and analyzing karst phenomena in three dimensions. This paper integrates geology, groundwater hydrology, geographic information system (GIS), database management system (DBMS), visualization and data mining to study karst features in Huaibei, China. The 3D geo-objects retrieved from the karst area are analyzed and mapped into different abstract levels. The spatial relationships among the objects are constructed by a dual-linker. The shapes of the 3D objects and the topological models with attributes are stored and maintained in the DBMS. Spatial analysis was then used to integrate the data in the DBMS and the 3D model to form a virtual reality (VR) to provide analytical functions such as distribution analysis, correlation query, and probability assessment. The research successfully implements 3D modeling and analyses in the karst area, and meanwhile provides an efficient tool for government policy-makers to set out restrictions on water resource development in the area.     

Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China

MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology. Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December 2003. During this period, the total recharge of the groundwater system was 49,374 × 10⁶ m³ and the total discharge was 56,530 × 10⁶ m³ the budget deficit was −7,156 × 10⁶ m³. In this integrated system, the original data including graphs and attribution data could be stored in the database. When the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online.     

Wind wave-forced fine sediment erosion during the slack water periods in Hangzhou Bay,China

The shallow water wave simulation model-SWAN incorporated with a simple fine sediment erosion model is applied to Hangzhou Bay, China, to model the horizontal distribution of the maximum bottom orbital velocity and corresponding fine sediment erosion rates induced by: (1) southeasterly steady winds (5, 20 and 30 m/s), (2) southwesterly steady winds (5 and 20 m/s); (3) northwesterly steady winds (5 and 20 m/s); (4) east-southeasterly steady winds (5 and 20 m/s); (5) easterly steady winds (5 and 20 m/s) under closed and unclosed boundaries; and (6) unsteady winds during the slack water periods. Results suggest: (1) the steady wind wave-induced maximum bottom orbital velocities and corresponding fine sediment erosion rates generally increased with the increasing steady winds; (2) closed and unclosed boundary conditions had more significant influences on modeled fine sediment erosion rates under 5 m/s easterly steady winds than 20 m/s; and (3) steady and unsteady wind wave-induced maximum bottom currents could be significant in eroding fine sediment bed in Hangzhou Bay. The results show implications for geomorphology, sedimentology, coastal erosion, and environmental pollution mitigation in Hangzhou Bay.     

Regional distribution pattern of groundwater heavy metals resulting from agricultural activities

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.