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861.
有机质对S1nm锰矿相金属阳离子交换能力的影响 总被引:3,自引:0,他引:3
大洋多金属结核问题长期以来一直受到人们的关注[1~3].大量的研究结果表明,多金属结核中最有经济价值的铜、钴、镍等有价金属元素,主要赋存于仅占整个结核约15%锰矿相中.我们曾对人工合成1 nm锰矿相(synthetic 1nm manganate,以下简称S1nm锰矿相)金属阳离子交换能力作过初步探讨[4,5],研究表明,Cu2+,Co2+,Ni2+,Zn2+等与S1nm锰矿相具有强烈的阳离子交换能力,证明了多金属结核成矿后期的离子交换是铜、钴、镍、锌等有价金属元素进入多金属结核的重要途径之一. 相似文献
862.
Monitoring of altimeter microwave radiometer measurements is necessary in order to identify radiometer drifts or offsets that if uncorrected will introduce systematic errors into ocean height measurements. To examine TOPEX Microwave Radiometer (TMR) and Jason-1 Microwave Radiometer (JMR) behavior, we have used coincident wet zenith delay estimates from Very Long Baseline Interferometry (VLBI) and Global Positioning System (GPS) geodetic sites near altimeter ground tracks. We derived a TMR path delay drift rate of -1.1 ± 0.1 mm/yr using GPS data for the period from 1993.0-1999.0 and -1.2 ± 0.5 mm/yr using VLBI data. Thereafter, the drift appears to have leveled off. Already after 2.3 years (82 cycles) of the Jason-1 mission, it is clear that there have been significant systematic errors in the JMR path delay measurements. From comparison with GPS wet delays, there is an offset of -5.2 ± 0.6 mm at about cycle 30 and a more abrupt offset of -11.5 ± 0.8 mm at cycle 69. If we look at the behavior of the JMR coldest brightness temperatures, we see that the offsets near cycle 30 and cycle 69 are mainly caused by corresponding offsets in the 23.8 GHz channel of -0.49 ± 0.12 K and -1.18 ± 0.13 K, although there is a small 34.0 GHz offset at cycle 69 of 0.75 ± 0.22 K. Drifts in the 18.0 and 34.0 GHz channels produce a small path delay drift of 0.3 ± 0.5 mm/yr. 相似文献
863.
J. P. Boon J. J. van Zanden W. E. Lewis B. N. Zegers A. Goksyr A. Arukwe 《Marine environmental research》2002,54(3-5)
The short-term effects of the commercial PBDE flame retardant mixtures Penta-BDE and Octa-BDE on the expression of cytochrome P450 1A (CYP1A), vitellogenin (Vtg) and zona radiata proteins (Zrp) were investigated in juvenile salmon (Salmo salar). For this purpose, groups of fish were dosed twice (oral intake at days 1 and 4) with 10 and 50 mg/kg body weight of both commercial mixtures. The fishes were sacrificed at day 7 (n=5 for each group) and 14 (n=6 for each group), and blood, liver, fillet, and brain were collected. Blanks and positive controls were also part of the experiment. The expressions of Vtg, Zrp, and CYP1A were measured with several techniques (EROD, ELISA, Western, Northern and Slot Blot). The values in the groups of fish treated with Penta-BDE or Octa-BDE did not significantly differ from the reference group for any of the parameters tested. In contrast, the positive control groups treated with estradiol-17β for Vtg and Zrp expression, and β-naphthoflavone for CYP1A expression did show a significant response, indicating the potential sensitivity of the fishes for the parameters measured. Since the results of the chemical analyses showed concentrations of a number of PBDE congeners in liver, fillet, and brain that were about three orders of magnitude above those of fish from the North Sea, it is concluded that the short-term toxicity of both commercial PBDE mixtures for these endpoints was low. 相似文献
864.
865.
Estuary-wide benthic macrofauna–habitat associations in Willapa Bay, Washington, United States, were determined for 4 habitats (eelgrass [Zostera marina], Atlantic cordgrass [Spartina alterniflora], mud shrimp [Upogebia pugettensis], ghost shrimp [Neotrypaea californiensis]) in 1996 and 7 habitats (eelgrass, Atlantic cordgrass, mud shrimp, ghost shrimp, oyster [Crassostrea gigas], bare mud/sand, subtidal) in 1998. Most benthic macrofaunal species inhabited multiple habitats; however, 2 dominants, a fanworm, Manayunkia aestuarina, in Spartina, and a sand dollar, Dendraster excentricus, in subtidal, were rare or absent in all other habitats. Benthic macrofaunal Bray–Curtis similarity varied among all habitats except eelgrass and oyster. There were significant differences among habitats within- and between-years on several of the following ecological indicators: mean number of species (S), abundance (A), biomass (B), abundance of deposit (AD), suspension (AS), and facultative (AF) feeders, Swartz's index (SI), Brillouin's index (H), and jackknife estimates of habitat species richness (HSR). In the 4 habitats sampled in both years, A was about 2.5× greater in 1996 (a La Niña year) than 1998 (a strong El Niño year) yet relative values of S, A, B, AD, AS, SI, and H among the habitats were not significantly different, indicating strong benthic macrofauna–habitat associations despite considerable climatic and environmental variability. In general, the rank order of habitats on indicators associated with high diversity and productivity (high S, A, B, SI, H, HSR) was eelgrass = oyster ≥ Atlantic cordgrass ≥ mud shrimp ≥ bare mud/sand ≥ ghost shrimp = subtidal. Vegetation, burrowing shrimp, and oyster density and sediment %silt + clay and %total organic carbon were generally poor, temporally inconsistent predictors of ecological indicator variability within habitats. The benthic macrofauna–habitat associations in this study can be used to help identify critical habitats, prioritize habitats for environmental protection, index habitat suitability, assess habitat equivalency, and as habitat value criteria in ecological risk assessments in Willapa Bay. 相似文献
866.
冰激锥体振动物理模拟实验 总被引:3,自引:0,他引:3
应用DUT 1非冻结可破碎模型冰进行冰激锥体振动模拟实验的实验设备和模型的设计 ,给出了低冰速和高冰速两种情况下的结构位移曲线、冰力曲线及其幅值谱分析结果 ,得出了结构卓越频率和冰速与特征长度之比的关系 ,发现冰激锥体振动同冰激柱体振动一样有“频率锁定”现象。将实验结果与已有的冰排与圆柱相互作用实验结果进行比较 ,发现冰激锥体振动和冰激柱体振动有着相似的机理 相似文献
867.
利用模板法合成 1种新的含醇羟基西佛碱型大环冠醚 L (7,11-二氮杂 - 3,15 -二氧杂 - 4 ,5 ;8,10 ;13,14-三苯并环十六 - 6 ,11-二烯 - 1-醇 )的铜、锌配合物。经元素分析 ,IR、MS分析确定配合物的组成 M(L2 ) (NO3 ) 2 及其配位情况 ,由模板反应得到 [1+ 1]型西佛碱大环化合物。 DMF溶液中的电导数据证实它们均属非电离型 ,并运用 TG- DTA分析比较铜、锌配合物的热稳定性。 相似文献
868.
869.
Haasch ML 《Marine environmental research》2002,54(3-5):297-301
The mummichog (Fundulus heteroclitus) has been shown to be responsive to peroxisome proliferating agents (PPAs). Peroxisomes function as important sites for fatty acid beta-oxidation. Peroxisome proliferation by PPAs or starvation can lead to changes in the size and number of peroxisomes and the expression of omega-hydroxylases (CYP2K1/2M1 in rainbow trout). Mummichogs were subjected to 96 h fasting or 96 h recovery from fasting. Expression of PMP70- and CYP2K1/2M1-like proteins in vehicle-treated or non-treated controls was compared in both males and females. Fasting and vehicle produced decreases in PMP70- and CYP2K1/2M1-like proteins in both males and females. In reproductive females, decreases due to fasting and vehicle treatment were greater than in female fish that were not gravid. Recovery from fasting resulted in levels of CYP2K1/2M1 near control levels in males while in recovered females, about 2-fold higher levels compared to controls were noted. These results indicate that gender, reproductive status and diet can produce changes in the expressed levels of peroxisomal PMP70 and microsomal CYP2K1/2M1-like proteins in the mummichog. 相似文献
870.
It is demonstrated that the Jason-1 measurements of sea surface height (SSH), wet path delay, and ionosphere path delay are within required accuracies, via a global cross-calibration with similar measurements made by TOPEX/Poseidon (T/P) over a 6-month period. Since the two satellites were on the same groundtrack separated in time by only 70 s, measurements were recorded at approximately the same location and time. The variations in the wet path delay measured by Jason-1 compared to T/P are only 5 mm RMS, well within the required performance of 1.2 cm RMS. The RMS of the ionosphere differences is also well within the expected values, with a mean RMS of 1.2 cm. The largest difference is that the Jason-1 SSH is biased high relative to T/P SSH by 144 mm after the T/P and Jason-1 data are both corrected with improved sea state bias (SSB) models. However, the bias will change if a different SSB model is used, so the user should be cautious that the bias used matches the SSB models. The bias is generally constant within ± 10 mm in the open ocean, but appears to be higher or lower in some regions. Additionally, the SSH has been verified by comparison with 36 island tide gauges over the same period. After removing the global relative bias, the Jason-1 SSH data agree with tide gauges within 3.7 cm RMS and with T/P data within about 3.5 cm RMS on average for 1-s measurements, meeting the required accuracy of 4.2 cm RMS. 相似文献