Variability in the speciation of iron in the northern North Sea

Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (Fe_R) and total iron (Fe_T) in unfiltered samples, while dissolved iron (Fe_D) was measured by GFAAS after extraction of filtered sea water. Fe_R was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. Fe_T was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for Fe_R, 10.0 nM for Fe_T and 1.7 nM for Fe_D were obtained for the area sampled. Fe_R concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. Fe_R concentrations were found to be enhanced below the nutricline (below 40 m) as a result of the remineralisation of organic material. Enhanced levels of Fe_T were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. Fe_D concentrations varied between values similar to those of Fe_T in samples from the north of the area to values similar to those of Fe_R in the south. The bloom was thought to have influenced the distribution of both Fe_R and Fe_T, but less evidence was observed for any influence on Fe_R and Fe_D. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.     

基于损伤部位向量法的钢框架损伤识别研究

对损伤部位向量(DLV)法作了简单介绍,并用该方法对钢框架进行了损伤识别和损伤定位。该方法假定结构损伤前后为线性,对结构损伤前后柔度矩阵差进行奇异值分解,将奇异值为零所对应的向量,作为静荷载施加在无损结构的测点位置,则应力为零的单元为可能损伤的单元。对3种不同工况的钢框架进行了振动模态试验,用前3阶模态参数构造框架的柔度矩阵,按照DLV法对其进行了损伤识别,识别结果与已知损伤情况相一致。从测试自由度不完备、噪声和振型质量归一化系数这3个方面对识别效果进行了分析,结果表明:当损伤使结构动力特性有微小改变时,使用该方法不易定位损伤,应结合局部损伤识别方法进行判定;当损伤使结构动力特性有较大改变时,该方法能有效识别损伤的单元。DLV方法概念简单,理论明确,不受结构类型的限制,不需要结构的数学模型和模型缩聚或扩展技术,只需获得结构损伤前后的前几个低阶模态参数,即可识别结构一处或多处损伤,实际应用时可操作性强。     

基于AHP的新疆南天山西段中强地震预测指标体系及效能评估

本文从新疆南天山西段地区映震效果较好的预测指标出发, 采用AHP(Analytic Hierarchy Process, 层次分析法)建立了新疆南天山西段地区预测指标体系。 在此基础上, 应用1～9比率标度法构建相应的判断矩阵, 进而计算各指标的权重。 结果显示, 几项映震效果较好的指标中, 权重值相对较大的是短期预测指标中的形变异常和部分测震学参数。 同时AHP模型也给出了新疆南天山西段有无中强地震的综合判断指标Y, Y值可较好地反映新疆南天山西段地区中强地震的震兆强弱程度和异常可靠性, 当Y≥2.191时, 新疆南天山西段地区短期内存在发生中强地震的危险。     

竖向质量分布对框架结构动力特性影响的研究

在框架结构动力分析中,往往是把填充墙质量集中在楼层处进行求解.文中考虑填充墙实际分布对结构自振特性的影响,通过传递矩阵法求解结构自振频率和振型,并进一步分析了高阶频率的分布规律.结果表明,与采用集中质量模型的振型叠加法相比,填充墙的竖向质量分布会对框架结构高阶频率产生很大影响;框架结构的高阶模态具有局部性和密集分组的特...     

An algorithm for fast 3D inversion of surface electrical resistivity tomography data: application on imaging buried antiquities

In this work a new algorithm for the fast and efficient 3D inversion of conventional 2D surface electrical resistivity tomography lines is presented. The proposed approach lies on the assumption that for every surface measurement there is a large number of 3D parameters with very small absolute Jacobian matrix values, which can be excluded in advance from the Jacobian matrix calculation, as they do not contribute significant information in the inversion procedure. A sensitivity analysis for both homogeneous and inhomogeneous earth models showed that each measurement has a specific region of influence, which can be limited to parameters in a critical rectangular prism volume. Application of the proposed algorithm accelerated almost three times the Jacobian (sensitivity) matrix calculation for the data sets tested in this work. Moreover, application of the least squares regression iterative inversion technique, resulted in a new 3D resistivity inversion algorithm more than 2.7 times faster and with computer memory requirements less than half compared to the original algorithm. The efficiency and accuracy of the algorithm was verified using synthetic models representing typical archaeological structures, as well as field data collected from two archaeological sites in Greece, employing different electrode configurations. The applicability of the presented approach is demonstrated for archaeological investigations and the basic idea of the proposed algorithm can be easily extended for the inversion of other geophysical data.     

增长曲线模型中线性估计类所有可容许估计

对增长曲线模型中回归矩阵的函数的线性估计进行了研究。在矩阵损失下 ,作者得到了线性估计在一切线性估计类中可容许的充要条件     

我国海水贝类养殖低碳效应评价

食物生产系统的碳排放占人类活动碳排放总量的 30%, 碳汇渔业是一种重要的面向人类社会高质量食物蛋白质供给 的低碳发展路径。本文基于常见的 11 种养殖贝类的固碳系数和蛋白质含量特性研究,系统评估了我国2019 年养殖牡蛎 、蛤 类、扇贝、贻贝和蚶类等在养殖周期内碳捕集特性以及对低碳发展的贡献。研究表明： (1) 11 种养殖贝类之间贝壳和软体 组织含碳量的差异并不明显,但干重比和出肉率差异显著。因此,贝类固碳量核算不能忽视种类差异。 (2)所选 11 种贝类 软体组织皆属于高蛋白食品,虾夷扇贝软体组织 (干重) 的蛋白质含量最高。针对单位质量贝类养殖,长牡蛎的碳封存贡献 度最大,而华贵栉孔扇贝提供的蛋白质最多,两者都是碳汇渔业的优势种。(3) 据估算,我国2019 年海水养殖贝类中牡蛎、蛤 类 、扇贝和蚶类总共吸收固定了约 117.98 万吨 C02,提供了 40.65 万吨蛋白质 。这些蛋白质相比于牛肉源蛋白质可减少 4 048.74 万吨 C02 当量的排放量。由于贝类固碳强度大,探索低碳可持续的贝类养殖是绿色渔业经济的重要引擎, 也是建立可持续高质量“蓝色粮仓”和生物固碳的重要路径, 将在我国低碳产业发展中发挥重要作用。     

赤点石斑鱼人工配合饵料中蛋白质最适含量的研究

本文探讨了不同蛋白质含量的配合饵料对赤点石斑鱼（Epinephelusakaara）生长的影响。通过60d度验得出：在各配合饵料组中，蛋白质含量为49．52％的试验的相对增重率（46．84％）体长相对增长率（15．96％）、蛋白质效率（60．35％）和饵料转化率（29．85％）等均为最佳。配合饵料组鱼体肌肉营养成分（蛋白质、脂肪、氨基酸和鲜味氨基酸）也均优于对照组，而更接近野生鱼。经回归方程分析，赤点石斑鱼人工配合饵料中蛋白质最适含量为48．37％～49．24％。     

关于GAOR、GSSOR的特征值关系式

对两种广义迭代方法ＧＡＯＲ和ＧＳＳＯＲ分别导出了其迭代矩阵和Ｊａｃｏｂｉ迭代矩阵的特征值之间的关系式，这些结果推广了已有的结果     

New finite-gap solutions for the coupled Burgers equations engendered by the Neumann systems

On the tangent bundle TS^N-1 of the unit sphere S^N-1, this paper reduces the coupled Burgers equations to two Neumann systems by using the nonlinearization of the Lax pair, whose Liouville integrability is displayed in the scheme of the r-matrix technique. Based on the Lax matrix of the Neumann systems, the Abel--Jacobi coordinates are appropriately chosen to straighten out the restricted Neumann flows on the complex torus, from which the new finite-gap solutions expressed by Riemann theta functions for the coupled Burgers equations are given in view of the Jacobi inversion.