丁二酸柱撑水滑石的制备及表征

以镍铝水滑石为前体（主体）,以蒸馏水为分散介质,用离子交换法组装丁二酸根（客体）插层水滑石,同时用一步合成法合成丁二酸根插层水滑石,并用XRD,IR,TG-DTA和元素分析等手段对样品进行了表征。结果表明,离子交换法制得的产品中丁二酸根阴离子取代了镍铝水滑石前体层间的碳酸根离子,组装得到晶体结构良好的丁二酸根插层水滑石,层间距为1．23nm。     

荔湾3-1组块浮托安装实船监测与数值模拟

目前海洋平台日趋集成化、模块化,重量和体积都逐渐增大,使得适合安装大型组块的浮托安装法得到飞速发展。介绍荔湾3-1大型导管架平台浮托安装中使用的实测技术,对驳船的运动监测和海洋环境监测等测量数据进行分析,分析结果被应用于指导整个浮托安装过程,保证浮托安装符合安全施工标准。对浮托安装载荷转移阶段采用数值计算方法进行作业过程模拟,将计算结果与实测结果进行对比分析,两者具有较好的相似性。     

溢油物理化学性质灰色模式的研究

应用灰色系统理论对海面溢油物理化学性质(蒸发率、溶解率、表面张力、黏度和密度)在风化过程中的变化进行研究,建立了溢油物理化学性质在风化过程中的预测模式GM(1,1)和GM(0,m).结果表明,在风化过程中,溢油物理化学性质的GM(1,1)和GM(0,m)模式预测精度令人满意,皆符合统计学检验的要求;在风化过程中,溢油物理化学性质所具有的灰色相关性可用GM(0,m)模式的灰色辨识参数来表征;在风化过程中,溢油的蒸发率和溶解率可分别用表面张力、黏度和密度作为预报因子。     

Changes in the Structure of a Coastal Fish Assemblage Exploited by a Small Scale Gillnet Fishery During an El Niño–La Niña Event

During 1998 an experimental gillnet fishing survey was carried out in a Mexican Central Pacific inshore zone. One-hundred and thirty fish species belonging to 51 families and 18 orders were identified. The most abundant species wereMicrolepidotus brevipinnis (29·0% of the total abundance) and Caranx caninus (19·2%), followed by C. caballus (6·3%), Kyphosus analogus (4·3%) and C. sexfasciatus (3·4%). Thermal SST anomalies showed the existence of two periods. The first, from January to April with positive anomalies, defines the end of an El Niño episode. The second period, from May to December, constitutes the beginning of the La Niña episode. The typical seasonality in a non-anomalous year continued for a large percentage of the inshore fish community, and the effects of the anomalous event consisted of changes in seasonality of occurrence in some individual species and the unusual abundance of some uncommon species. The species richness was higher during the El Niño–La Niña event than in a non-anomalous year, and therefore the event could be considered an interannual environmental mechanism that favours fish diversity in inshore waters.     

Carbon isotopes and lignin phenols for tracing the floods during the past 70 years in the middle reach of the Changjiang River

The Lake Tian E Zhou(TEZ,an oxbow lake)was formed during the rerouting of the Changjiang River in 1972,with strong influences from the main river channel and flood events.Herein,a sediment core was collected from the Lake TEZ for the measurements of carbon isotopes and biomarkers,including stable carbon isotopes(δ13C),radiocarbon composition(?14C),and lignin phenols,as well as lead-210 to reconstruct recent heavy flood events over the past 70 years.At the 24–26 cm interval,the sediment contained the highest OC%,TN%,and lignin phenols content,as well as significantly depleted 13C but enriched 14C,corresponding to the extreme flood event in 1998.In addition,statistics from t-test showed that lignin phenols normalized to OC(Λ8),the concentration of 3,5-dihydroxy benzoic acid(3,5-BD),and the ratio of p-hydroxy benzophenone to total hydroxyl phenols(PHB/HP)were all significantly different between the layers containing flood deposits and the layers deposited under normal non-flood conditions(p<0.05).These results indicate that the later three parameters are highly related to flood events and can be used as compelling proxies,along with sediment chronology,for hydrological changes and storm/flood events in the river basin and coastal marine environments.     

An Implicit Coupled 1D/2D Model for Unsteady Subcritical Flow in Channel Networks and Embayment

In this study, 1D and 2D shallow-water models were coupled to simulate unsteady flow in channel networks and embayment. The 1D model solved the 1D shallow-water equations (St. Venant) using the Preissmann box method and targeted long narrow reaches of the river networks, while the 2D model targeted broad channels and embayment and solved the 2D shallow-water equations using a semi-implicit scheme applied to an unstructured grid of triangular cells. The 1D and 2D models were solved simultaneously by building a matrix for the free surface elevation at every 1D junction and 2D cell center. Velocities were then computed explicitly based on the results at the previous time step and the updated water level. The originality of the scheme arose from a novel coupling method. The results showed that the coupled 1D/2D model produced identical results as the full 2D model in classical to benchmark problems with considerable savings in computational effort. Application of the model to the Pearl River Estuary in southern China showed that complex patterns of tidal wave propagation could be efficiently modeled.     

健跳港上游引水对海床冲淤影响的数值模拟分析

健跳港是一个狭长的淤泥质港汊,针对枯季和洪季健跳港海床不同的冲淤特点,利用一维潮流泥沙模型复演了该港海床的冲淤过程,通过调整挟沙力系数来模拟健跳港枯水期的淤积和洪水期的冲刷这两种不同的海床变化形态,并预测了健跳港上游引水后对该港河床的淤积影响。     

The inventory and chemical characterization of dissolved proteins in oceanic waters

One-dimensional sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and high resolution two-dimensional electrophoresis (2-DE) were applied to separate protein molecules in dissolved organic matter (DOM) from oceanic waters. Results were: (1) The 2-DE distinguished a total of 412 protein spots in 10 samples from five water columns over the Pacific, although fewer than 30 proteins were resolved as bands from the identical samples by SDS-PAGE. (2) Major and ubiquitous protein bands (34 and 39 kDa proteins) on the SDS-PAGE gel were resolved into horizontally spread arrays (trains) of spots on the 2-DE gels, indicating that these bands were a mixture of protein species that have the same molecular weight (MW) but different isoelectric points (pIs). (3) Proteins that exhibited such electrophoretic patterns on the 2-DE gels were glycosylated with variable linkages between the sugar and polypeptide chains. (4) N-terminal amino-acid sequencing demonstrated that individual spots within each train of spots had identical N-terminal amino-acid sequences.The N-terminal amino-acid sequences of the 39 and 34 kDa glycoprotein spots in samples collected at different sites were also identical. Protein isoforms with the same amino-acid sequence but different glycosylation profiles, termed glycoforms, were often observed on the 2-DE gel. Thirty-one and 24 spots on the 2-DE gels were glycoforms of two glycoproteins with MWs of 39 and 34 kDa, respectively; they were one protein species. The glycoforms of the 39 kDa protein were identified as a low molecular weight alkaline phosphatase (L-AP) of Pseudomonas aeruginosa PAO1 by a homology search through five amino-acid sequence databases. The present and earlier work indicates that all identified source organisms of dissolved proteins belong to the Pseudomonas group. We propose the hypothesis that proteins associated with membrane vesicles liberated from a minor member of the bacterioplankton assemblage, the marine Pseudomonas group, are one of the important sources of dissolved proteins in oceanic waters. This hypothesis may apply to the source pathway and survival not only of proteins and also to the universally occurring bacterial peptidoglycan and lipopolysaccharide components in DOM.     

FY-1C/1D全球海上气溶胶业务反演算法研究

介绍了基于FY-1C/1D气象卫星数据进行全球海洋气溶胶反演的业务算法,主要论述了海上气溶胶反演的单通道算法基本原理.该算法的核心内容是建立气溶胶光学厚度查算表,该查算表基于6S辐射传输模式,在假定气溶胶模式条件下,卫星的表观反射率是卫星观测几何(太阳卫星角)和气溶胶光学厚度函数,最终由卫星观测表观反射率反演出气溶胶光学厚度.业务反演过程中还考虑到数据质量检验、云检测处理和太阳耀斑区去除等.利用该算法对FY-1C卫星自2001年起的部分资料进行反演试验,并在FY-1D卫星发射后投入业务应用,自2002年8月开始能实时得到每天和每月的全球气溶胶光学厚度产品.从两颗卫星两年多连续反演结果分析可以非常清晰地发现全球气溶胶主要排放源地和全球海上气溶胶分布的季节变化,与国外卫星反演结果十分接近.