Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.     

长庆气田奥陶系风化壳气藏、气源研究

对10年来长庆气田奥陶系风化充气藏气源问题存在的不同观点（上古生界煤成气和奥陶系海相碳酸盐岩气何者为主）及相应的证据进行了总结和讨论,认为“奥陶系自生自储为主”的观点对地质和地球化学现象的解释存在疑问,包括用次要组分来判别混源天然气的主要来源,用不确切的端员气地球化学特征来计算混源比,对本溪组底部岩石的封盖性和下奥陶统碳酸盐岩的原始生烃潜力评价偏高,忽略了石炭系存在能够生成油型气的海相源岩。因此,长庆气田不能作为海相贫有机质的碳酸盐岩生成的大、中型油气田的实例。根据天然气及气源岩的地球化学特征,提出长庆气田奥陶系风化壳气藏气是以上古生界煤成气为主、石炭系海相源岩生成的油型气为辅的混合气。     

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

广西十万大山盆地下二叠统生物礁古油藏及隐伏礁预测

广西宁明县亭亮下二叠统茅口组生物礁古油藏,为十万大山盆地已暴露破坏的礁古油藏之一。该古油藏的含沥青储层主要分布于礁体的上部和顶部,含沥青礁灰岩厚达９８ｍ以上,礁储层次生溶孔的形成与分布主要受控于深埋有机溶剂作用,同时在空间上还与礁顶部古风化壳和不整合面密切相关,论文深入探讨了礁古油藏形成的主要成岩作用类型及其埋藏一构造发展史,有机质演化史及成岩孔隙演化史三者的配置关系和成藏机理,另据地震和电法资料     

后疫情时代全球石油供需格局研究

2017年以来,全球石油消费持续疲软,消费增速呈逐渐下降的趋势,新冠肺炎疫情对石油需求的打击更是"雪上加霜".本文回顾了疫情发生以来国际原油价格及大型油气公司股票价格的走势,探讨了疫情对全球石油需求和供应市场的影响,研判了短期及中长期全球石油供需格局,得出了三点结论:(1)疫情对全球石油需求产生重大冲击,预计2020年...     

柴西地区扎哈泉致密油储层特征及评价

柴西地区致密油储层内部结构复杂、非均质性强,为了更高效地进行致密油勘探开发,利用岩芯薄片、X衍射、场发射扫描电镜、CT扫描和物性分析等方法,对扎哈泉地区上干柴沟组开展致密储层特征及储层物性控制因素研究。研究表明,上干柴沟组为典型的致密储层,以细砂岩和粉砂岩为主,填隙物含量较高,以原生孔隙为主,微米级孔隙是主要的储集空间,有效储层平均孔隙度为5. 9%,平均渗透率为0. 43 m D。储层内部孔隙分布较均匀,总体呈现微米级孔隙加纳米级喉道的特征,其中微米级孔隙基本呈片状分布,连通性好,纳米级孔隙则呈点孤立状分布。储层物性受原始沉积条件和后期成岩作用控制,坝砂泥质含量低,纯度高,物性较好。压实作用和碳酸盐胶结使储层变差,硬石膏胶结对孔隙的影响具有两面性,晚成岩期的溶蚀作用对储层改善作用明显。研究区致密油有效储层可分为三类,其中Ⅰ类有效储层为本区的"甜点"区,是下一步优先勘探开发的重点区块,Ⅱ-Ⅲ类有效储层则是重要的挖潜区,通过工程技术攻关可切实实现柴西地区的增产扩能。     

深层白云岩储层油充注对孔隙保存作用研究

受震旦纪末期桐湾运动影响,四川盆地震旦系灯影组白云岩因遭受大气降水岩溶作用而发育了丰富的溶蚀孔隙。虽然经历了漫长的埋藏成岩演化过程,深层灯影组白云岩中仍见有丰富的储集空间未被成岩矿物充填而保存下来。通过对钻井及野外剖面进行系统岩石矿物学研究发现,储集空间保存段是灯影组上部的沥青显示段;而没有沥青的下部白云岩中的孔隙空间多被白云石等成岩矿物所充填。对林1井研究发现,上部沥青发育段白云岩储层孔隙度多大于3.0%,最高可达10.6%,平均为4.0%;但下部沥青不发育的自生白云石充填段孔隙度一般都小于3.0%,平均为1.95%。下部白云岩段溶蚀孔洞中自孔洞边缘向中心,所充填的白云石中流体包裹体均一温度从120℃逐渐增加至238℃;电子探针分析Fe、Mn平均含量从0.063%和0.025%逐渐升高至0.35%和0.108%;氧同位素组成δ18 OVPDB从-6.8‰逐渐降低至-11.2‰;表明了下部沥青未充填段成岩充填作用在埋藏过程中持续进行。油气充注改变了白云岩储层中的成岩流体环境并抑制了成岩矿物的形成;在后期埋藏过程,油逐渐转变成沥青覆盖在孔洞壁周围,也抑制了成岩矿物的沉淀形成;因而在现今沥青存在的深层白云岩储层中仍有丰富的孔隙空间保存下来。     

鄂尔多斯盆地陇东地区长9油层组油源分析

鄂尔多斯盆地陇东地区长9油层组油源问题是制约该地区勘探进程的因素之一。为了解决这一问题,首先依据长9原油地球化学资料对原油成因进行了研究;针对长7烃源岩和长9烃源岩地球化学特征相似性导致难以评价两种烃源岩对长9油层组成藏贡献的问题,本文基于聚类分析理论,利用灵敏的生物标志化合物参数计算、分析了长9原油与长7烃源岩和长9烃源岩间的相关性和类属关系,同时结合陇东地区地质特征探讨了长9原油成藏可能的运移路径。研究结果表明:长9原油形成于弱氧化-弱还原的淡水湖泊环境,原油母质主要由水生生物和高等植物构成,原油已经成熟;长9原油主要来自长7烃源岩,部分来自长9烃源岩;长7烃源岩和长9烃源岩生成的原油沿北东-南西向运移。烃源岩较强的生排烃能力、良好的疏导体系和有利的砂体展布对长9石油成藏起着至关重要的作用。     

松科二井邻域沙河子组含油气地层结构特征——基于测井和地震数据的分析

松辽盆地大陆深部科学钻探工程"松科二井"获得了最完整的沙河子组地层岩心,初步识别出深部页岩气气测异常43层,累计厚度102 m,显示出沙河子组地层具有良好的深部能源前景。为进一步分析松辽盆地沙河子组地层油气资源潜力,本文在前人研究的基础上,结合松科二井测井、岩心数据和地震数据,分析松科二井邻域沙河子组地层的层序特征和空间展布,同时以随钻录井记录到的气测异常为出发点,分析沙河子组地层的测井和地震响应。结果显示:松科二井邻域沙河子组地层具有厚度大、横向延续小的地层展布特点,根据测井、岩心及地震数据,将沙河子组地层分为4个三级层序:SQ1、SQ2、SQ3和SQ4,其中顶部SQ4层序具有较好的油气前景,其岩性以泥岩为主,并具有相对较高孔隙度、低波阻抗的测井曲线特征,在地震剖面上表现为连续强振幅,阻抗反演剖面上存在局部低波阻抗特征,揭示了该区沙河子组深层天然气资源的赋存条件。     

渤海湾盆地沉积斜坡及其含油气性

将渤海湾盆地的沉积斜坡按结构分为3类4种,并归纳出4种相应的沉积序列;按沉积相将砂体划分为8种储集层类型,以河流——三角洲砂为最佳储层;并归纳出斜坡带的4种油气藏分布模式;总结了斜坡带油气聚集的基本条件;通过对4种斜坡的类比表明:凹坡型为最佳含油斜坡。并对冀中坳陷斜坡带的油气勘探提出了建议。