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61.
Stéphane Audry Gérard BlancJörg Schäfer Frédéric GuérinMatthieu Masson Sébastien Robert 《Marine Chemistry》2007
The behavior and budget of Mn, Cd and Cu in the Gironde estuary were investigated through data from both the water column (WC) and sediment depth profiles. In the estuarine freshwater reaches, Mn and Cd removal from and Cu addition to the dissolved phase occurs with a magnitude equivalent to 10%, 30% and 25% of their respective annual fluvial gross dissolved input, respectively. In the saline estuary, diffusive benthic outflow is the main source of dissolved Mn (74% of the total gross dissolved input within the estuary) to the WC. In contrast, Cd (96%) and Cu (89%) are mainly released into the dissolved phase of the WC from fluvial, estuarine and dredging-related particles through complexation (Cd) and organic carbon mineralization (Cu). Anthropogenic activities (sediment dredging) induce pore water inputs, particulate sulfide oxidation and sediment resuspension, significantly contributing to the metal budget of the WC. The related amounts of metals released could be equivalent to 20–50% (Cd) and up to 70% (Cu) of their respective net dissolved addition. Mass balances suggest that a large part of the metals previously released into the dissolved phase from processes within the estuary are removed by suspended particles due to (co-)precipitation of Fe/Mn (oxy)hydroxides and scavenging on autochthonous organic matter. On an annual basis, the Gironde estuary acts as a net sink of dissolved Mn, removing 60% of the dissolved fluvial inputs, and as a net source of dissolved Cd and Cu, contributing ∼ 85% and 20–45% to the dissolved Cd and Cu fluxes to the ocean. 相似文献
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64.
顶空气相色谱法测定海水二甲基硫和浮游植物细胞二甲基硫丙酸的研究 总被引:12,自引:2,他引:12
建立了顶空GC/FPD测定海水中二甲基硫(DMS)和浮游植物细胞中二甲基硫丙酸(DMSP)的方法,并研究盐度、温度、气液相比DMS诸因素对DMS顶空灵敏度的影响。该法对DMS测定的相对标准偏差均小于6%,平均回收率为106%,最低检出限为20ng/L。细胞DMSP先经碱作用转化为DMS,在50℃下作用时间不少于6h,峰高与浓度的双对数线性相关系数大于0.99。对1994年冬、1995年夏采自胶州湾 相似文献
65.
Oleg Zaytsev Rafael Cervantes-Duarte Orzo Montante Artemio Gallegos-Garcia 《Journal of Oceanography》2003,59(4):489-502
High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity
that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The
upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m3/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local
wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of
the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California
shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery
from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct
experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely
related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient
transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters
into the lagoon system.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
66.
九龙江河口区水体中的226Ra和228Ra 总被引:8,自引:0,他引:8
用MnO2-纤维富集大体积水样中的Ra同位素,并用直接射气法测定226Ra和228Ac的β计数法测定228Ra的方法,研究了九龙江河口区226Ra,228Ra的行为,结果表明:在该河口区226Ra,228Ra均呈非保守行为,226Ra,228Ra的最高值分别在盐度为19和9处测得。228Ra/226Ra)A.R.值在盐度小于19的区域约为3左右。与世界其他河口区相比,九龙江河口区的226Ra,22 相似文献
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本文分析了济州岛南部区域温度双跃层现象的类型及其成因。特别阐明了双跃层的波状现象,指出:强流锋区的侧向效应,黑潮次—中层混合水的爬升,黄海冷水团边缘密度环流引起的侧向流动,以及上、下层流速、流向不一致引起的剪切作用,是导致双跃层波状现象的主要原因。发现上、下跃层之间存在着“跃层间环流”,这是一个有趣的海洋学现象,它将导致双扩散的发生和有利于双跃层的维持。 相似文献
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