粘土矿物对尖刺拟菱形藻多列型生长和藻毒素产生的影响

于１９９４年１－７月在加拿大贝德福（Ｂｅｄｆｏｒｄ）海洋研究所进行粘土矿物（ｈａｌｌｏｙｓｉｔｅ）对尖刺拟菱形藻（Ｐｓｕｅｄｏｎｉｔｚｓｃｈｉａｐｕｎｇｅｎｓｆ．ｍｕｌｔｉｓｅｒｉｅｓ）生长和藻毒素软骨藻酸（ＤｏｍｏｉｃＡｃｉｄ,下简称ＤＡ）生成的影响研究,在Ｇｏｍｐｅｒｔｚ菌类生长方程的基础上,建立了尖刺拟菱形藻生长速率模型,得到各实验条件下的藻细胞最大生长速率,结果表明,粘土矿物对藻细胞的“遮     

Detrital clay grain coats in estuarine clastic deposits: origin and spatial distribution within a modern sedimentary system,the Gironde Estuary (south‐west France)

Porosity and permeability may be preserved in deep sandstone reservoirs by clay coating (mainly chlorite) which limits quartz overgrowths. Chloritization around quartz grains results mainly from mineralogical transformations of pre‐existing clays. It is fundamental to study those clay precursors to better understand and predict the location and distribution of clay coatings in subsurface sandstones for petroleum or geothermal prospecting. This paper reports a high‐resolution analysis of the composition, distribution and fabric of clays along a modern estuary, the Gironde (south‐west France). The scale of the study ranges from thin sections, through sand bar bodies, up to the entire estuary. Results show that clays are detrital and deposited at the same time as sand grains despite strong hydrodynamic conditions. Clays bind to medium‐grained sands forming detrital clay grain coats. On average, 26% of detrital sand grains are coated along the entire length of the estuary. Coat thickness varies from 1 μm to more than 200 μm, and coat coverage exceeds 30% in some samples. The turbidity maximum zone position (surface water turbidity from 1 to 10 g l^?1) in the estuary, which is controlled by seasonal variations in hydrodynamic processes, significantly impacts the location of the maximum clay content and the abundance of coated grains in sandy facies along the estuary. Flocculation in the water column results in the accumulation of suspended matter and contributes to the high turbidity in the estuary. Exopolymeric substances produced by diatoms are observed both in the field and by cryo‐scanning electron microscopy, suggesting that they may play a major role in binding detrital clay around sand grains. Finally, tidal bars and heterolithic point bars in the estuary funnel and estuarine channels are prime sedimentological targets for finding clay coatings and potentially good reservoir quality in deeply buried sandstones.     

Relation water content ratio-to-liquidity index versus the Atterberg limits ratio evaluated with the Kaniadakis exponential law

Water content ratio (WCR) is defined as the ratio water content to liquid limit (LL) and it is proved to be a good replacer of the well-known parameter liquidity index (LI) to predict shear strength of fine-grained soils. An interesting correlation between the slope of LI and WCR and LL/PL ratio was observed. However, this trend is poorly described by conventional regression functions. By employing the Kaniadakis exponential law based on the relativistic mechanics, 22 data set, considering the LL/PL vs the slope of LI and WCR, were very-well matched.     

The development of polygonal fault systems by syneresis of colloidal sediments

Polygonal fault systems occur in numerous sedimentary basins worldwide, are generally located on passive margins in onlap fill units and tend to comprise the finest grained sediments in this geological setting. These fault systems have been most thoroughly described in the central North Sea basin and the detailed structure shows a significant correlation with lithological variations, both vertically and laterally. Extension measured in stacked decoupled tiers of polygonal faults correlates positively with both clay fraction and smectite content. Lateral facies variations are also observed and indicate that time-equivalent sequences upslope from the smectite-rich polygonally faulted sediments are coarse-grained, clay-poor and undeformed. This leads us to believe that the structure and geometry of the fault system are controlled by the colloidal nature of the sediments, and that the volumetric contraction measured on seismic sections can be accounted for by syneresis of colloidal smectitic gels during early compaction. Syneresis results from the spontaneous contraction of a sedimentary gel without evaporation of the constituent pore fluid. This process occurs due to the domination of interparticle attractive forces in marine clays, dependent on environment, and is governed by the change of gel permeability and viscosity with progressive compaction. The process of syneresis can account for a number of structural features observed within the fault systems, such as tiers of faults, the location of maximum fault throw and growth components at upper fault tips. As such, this paper represents the first attempt to correlate microscale properties of clay-rich sediments to their macroscale seismic character.     

Multi-scale micro-structure generation strategy for up-scaling transport in clays

Clays and claystones are used as backfill and barrier materials in the design of waste repositories, because they act as hydraulic barriers and retain contaminants. Transport through such barriers occurs mainly by molecular diffusion. There is thus an interest to relate the diffusion properties of clays to their structural properties. In previous work, we have developed a concept for up-scaling pore-scale molecular diffusion coefficients using a grid-based model for the sample pore structure. Here we present an operational algorithm which can generate such model pore structures of polymineral materials. The obtained pore maps match the rock’s mineralogical components and its macroscopic properties such as porosity, grain and pore size distributions. Representative ensembles of grains in 2D or 3D are created by a lattice Monte Carlo (MC) method, which minimizes the interfacial energy of grains starting from an initial grain distribution. Pores are generated at grain boundaries and/or within grains. The method is general and allows to generate anisotropic structures with grains of approximately predetermined shapes, or with mixtures of different grain types. A specific focus of this study was on the simulation of clay-like materials. The generated clay pore maps were then used to derive upscaled effective diffusion coefficients for non-sorbing tracers using a homogenization technique. The large number of generated maps allowed to check the relations between micro-structural features of clays and their effective transport parameters, as is required to explain and extrapolate experimental diffusion results. As examples, we present a set of 2D and 3D simulations and investigated the effects of nanopores within particles (interlayer pores) and micropores between particles. Archie’s simple power law is followed in systems with only micropores. When nanopores are present, additional parameters are required; the data reveal that effective diffusion coefficients could be described by a sum of two power functions, related to the micro- and nanoporosity. We further used the model to investigate the relationships between particle orientation and effective transport properties of the sample.     

Class A predictions of a NATM tunnel in stiff clay

The paper demonstrates the application of a hypoplastic model in class A predictions of a NATM tunnel in an urban environment. The tunnel, excavated in a stiff clay, is 14 m wide with 6 m to 21 m of overburden thickness. The constitutive model was calibrated using laboratory data (oedometric and triaxial tests) and the parameters were optimised using monitoring data from an exploratory drift. Based on the optimised data set, the future tunnel was simulated. After the tunnel excavation, it could be concluded that the model predicted correctly surface settlements, surface horizontal displacements, and the distribution of vertical displacements with depth. It overpredicted horizontal displacements in the vicinity of the tunnel.     

Mechanisms Controlling the Undrained Strength Behavior of Remolded Ariake Marine Clays

The soft clay of Ariake Bay, in western Kyushu, Japan covers several hundred square kilometers. Ariake clay consists of the principal clay minerals namely smectite, illite, kaolinite and vermiculite, and other minerals in lesser quantity. The percentage of the principal clay mineral can vary significantly. The percent clay size fraction and the salt concentration can also vary significantly. In view of the importance of undrained shear strength in geotechnical engineering practice, its behavior has been studied with respect to variation in salt concentration. Basically two mechanisms control the undrained strength in clays, namely (a) cohesion or undrained strength is due to the net interparticle attractive forces, or (b) cohesion is due to the viscous nature of the double layer water. Concept (a) operates primarily for kaolinitic soil, and concept (b) dominates primarily for montmorillonitic soils. In Ariake clay, different clay minerals with different exchangeable cations and varying ion concentration in the pore water and varying nonclay size fraction are present. In view of this while both concepts (a) and (b) can coexist and operate simultaneously, one of the mechanisms dominates. For Isahaya clay, concept (a), factors responsible for an increase in level of flocculation and attractive forces result in higher undrained strength. Increase in salt concentration increases the remolded undrained strength at any moisture content. For Kubota and Kawazoe clays, concept (b) factors responsible for an expansion of diffuse double layer thickness, resulting in higher viscous resistance, increase the undrained shear strength, that is, as concentration decreases, the undrained strength increases at any moisture content. The liquid limit of Isahaya clay increases with increase in ion concentration and a marginal decrease is seen for both Kubota and Kawazoe clays, and their behavior has been explained satisfactorily.     

Structure of sediments of kaolinite

In an assembly of clay particles placed in a fluid, each particle is typically subjected to: (1) double-layer repulsive forces; (2) van der Waals attractive forces; and (3) contact mechanical forces. The study presented here concerns an approximate, quantitative analysis of clay suspensions, with considerations to the first two - the physico-chemical forces. Using recent theories to calculate the physico-chemical forces between two clay particles in an approximate model of an assembly, the equilibrium void ratio of a clay suspension is computed. The mechanical forces are ignored in the analysis. The results serve to verify the validity of physico-chemical theories employed and help interpret experimental data more fundamentally in terms of the system variables.     

Thermo-hydro-mechanical behaviour of two heavily overconsolidated clays

An experimental study on the thermo-hydro-mechanical behaviour of two heavily overconsolidated clays is presented. Laboratory tests have been conducted on a Spanish bentonite (FEBEX bentonite) and a Belgian kaolinitic/illitic clay (Boom clay), statically compacted at different initial dry densities and water contents. Volume change behaviour of the soils during suction reduction paths at different temperatures and during heating-cooling cycles at constant water content or suction have been investigated through the use of suction and temperature controlled oedometer cells. In addition, the volume change response under unconfined conditions and constant water content has been measured to determine thermal expansion coefficients. The results show similarities and differences between the observed behaviour of the two types of clays that have been interpreted on the basis of their different structures and regarding their proportion of intra-aggregate water.     

Analytical model for vertically loaded anchor performance with a bridle shank

Vertically loaded anchors offer an attractive alternative for mooring systems because of their relatively high efficiency and low cost. The bridle shank is an important feature of these anchors because its reconfiguration significantly affects their performance. A plasticity model considering a bridle shank is introduced to investigate the mechanism of the system. Model-based parametric studies on the effects of the bridle length, drag distance and anchor line angle are also conducted. These studies establish a new, more rational analytical model for these anchors, as well as contribute to the understanding of the mechanism of them in research and practice.