白山市三道阳岔铁矿床磁铁矿工艺矿物学研究

磁铁矿工艺学研究主要为白山磁铁矿在后期详查,开采,选矿方面,提供科学依据,对其进行了工艺学研究,研究结果表明:矿石中可供回收的主要金属矿物为磁铁矿,其他均达不到综合利用指标。     

南海尖峰海山多金属结壳地球化学

南海尖峰海山多金属结壳富含30多种元素,其锰铁矿物主要由钡镁锰矿,δ-MnO_2和FeOOH·xH_2O组成。与其它海区的结壳相比,尖峰海山结壳富含Cu、Ni、Ba、Zn、Pb等元素,而Co、Ti、稀土元素(REE)、Sr等元素相对较贫。研究表明,HREE亏损,具明显的Ce正异常,较明显的Tb正异常和Yb负异常。这是氧化弱碱性海洋环境所致。结壳是水成作用的产物,它的形成受南海独特的古海洋环境所控制,海底火山热液作用,可能也是影响因素之一。     

鲁西地区角闪石岩地球化学、矿物学特征及其地质意义

基性-超基性岩脉群通常形成于伸展构造背景,是示踪地幔源特征以及大陆和超大陆破裂的重要标志.鲁西地区角闪石岩为研究古元古代岩浆源和构造演化提供了一个窗口.本文对鲁西地区角闪石岩进行了岩相学、全岩地球化学及角闪石、黑云母电子探针原位分析.角闪石岩具板内构造环境,来自富集地幔.通过角闪石、黑云母成因分析,均具有幔源成因,角闪石结晶温度为702～781℃;结晶压力为29.8～228.8 MPa,结晶深度1～7.5 km,结晶时氧逸度变化范围在NNO+2.68到NNO+3.35之间.结合本次获得角闪石岩磷灰石U-Pb年龄为(1817±35)Ma,认为鲁西地区(1817±35)Ma处于板内拉伸环境,存在幔源岩浆上侵,已进入大陆裂解阶段.     

超高压变质作用研究现状及问题

本文从超高压变质作用的矿物学、Ｐ－Ｔ－ｔ轨迹和超高压地体抬升、保存机制三个方面总结了近年来超高压变质作用研究所取得的重要进展和存在的问题。超高压变质作用的矿物学研究正在向深入发展，其Ｐ－Ｔ－ｔ轨迹具有三种成因类型。而其超高压地体的抬升、保存机制则是争论的焦点，其中增生楔模式（Ｐｌａｔｔ，１９８７）和连续俯冲─仰冲机制较好地解释了抬升过程，但也存在一些问题需进一步研究。     

Mineralogical characteristics of upper Jurassic Mikulov Marls,the Czech Republic,in relation to their thermal maturity

The Upper Jurassic Marls of Mikulov present a formation that is considered to be the most promising strata to produce hydrocarbons in the Vienna basin. The marls are composed of dark pelagic marlstones that frequently contain layers of limestone with thickness reaching several hundreds of meters. Twenty-seven core samples from selected wells located in the south-eastern portion of the Czech Republic representing depths ranging from 2300 to 4500 m were analyzed by x-ray diffraction to assess bulk mineralogy and the progress of smectite illitization.Bulk mineralogy of the Mikulov Marls comprises carbonates (mean value = 54.4 mass%), clay minerals (26.6 mass%), quartz (15.0 mass%), and feldspar (1.6 mean%). In the decreasing order, the clay mineral fraction is composed of illite/mica, kaolinite, illite-smectite, and chlorite. The amount of smectite in illite-smectite decreases with depth from 70% to 28%. There is a change from random to ordered interstratification at the depth of 3300 m. The transition from short-range ordering (R1) to long-range ordering (R3) occurs at depths greater than 4,500 m.There was a good correspondence between thermal maturity parameters: the percentage of smectite in illite-smectite structures and vitrinite reflectance as a parameter of organic matter. The increase of the metamorphic grade was compared in respect to the geothermal gradient with adjacent basins.     

柴达木盆地第三系咸水湖相生油岩古沉积环境地球化学特征

在系统分析柴达木盆地西部第三系咸水湖相生油岩样品的微量元素、有机物、粘土矿物组成的基础上,揭示了研究区生油岩的无机元素和有机质组成特征;并结合沉积环境的无机与有机地球化学指标,重建了生油岩沉积时的古沉积环境。生油岩的B、Cl-及伽玛蜡烷含量表明,沉积时的水介质条件是半咸水—咸水环境,并伴随湖盆沉积中心北迁过程各层位地层的盐度发生规律性时空]化;生油岩的Fe2 /Fe3 、S2-、Pr/Ph比值、藿烷碳数分布模式及黄铁矿含量反映其沉积时的沉积环境为强还原性;粘土矿物组合特征及含量揭示这些生油岩的沉积相带介于中心咸湖相和边缘咸湖相之间。     

马里亚纳海沟挑战者深渊初期多金属氧化物的 矿物学、地球化学特征及其成因环境研究

对大洋27航次在西太平洋马里亚纳海沟挑战者深渊获取的3个多金属氧化物样品进行了X射线矿物衍射分析、穆斯堡尔谱分析及地球化学元素分析,研究其矿物、地球化学特征差异。结果表明,所取样品处于多金属氧化物发育的初始阶段,具有独特的矿物地球化学特征:(1)相较于太平洋CC区及中太平洋海盆获取的多金属结核样品,本研究样品的矿物组成中含有异常高的石英、斜长石以及黏土矿物,而水羟锰矿和钙锰矿含量较低。(2)样品中铁相矿物主要为正方针铁矿(91.6%),另含少量纤铁矿(8.4%),推测是纤铁矿向更加稳定的正方针铁矿衍变的结果。(3)由于样品中深海黏土组分以及氧化物核心物质的混入,加上吸附金属氧化物时间较短,导致SiO₂和Al₂O₃含量均高于正常结核,而Fe、Mn、Cu、Co、Ni等其余金属元素含量较低。(4)由于形成时间较短,样品中稀土元素含量相对较低,ΣREE仅约为0.4×10^-3(一般太平洋CC区及中太平洋结核中稀土含量均大于1.0×10^-3);加之海水氧化还原作用的降低以及研究区海底热液活动的影响,Ce元素未表现出多金属结核中常见的正异常。     

青藏高原东部边缘"成都黏土"粒度记录的约500 kaBP的干旱化增强事件

亚洲内陆干旱化是新生代青藏高原隆升和全球气候恶化的重要标志。对位于青藏高原东部边缘的成都黏土粒度记录的研究,及与黄土高原地区粒度记录的对比,表明该地区的粒度记录都在约500kaBP时发生了一次明显的粒度增大、粗颗粒含量增加的变化,表明东亚地区约500kaBP以来发生了一次明显的干旱化增强事件,推测青藏高原在中更新世强烈隆升进入冰冻圈,导致中下层西风环流显著分叉绕流以及随后的进一步强化,是亚洲内陆干旱化阶段性增强的重要原因。     

Scour depth under pipelines placed on weakly cohesive soils

We here study the scouring processes that evolve around a submarine pipeline placed on a weakly cohesive seabed. We first analyze some laboratory tests carried out by Vijaya Kumar et al. [21], Xu et al. [25] and Zhou et al. [28] that focused on the scouring around a horizontal cylinder lying on a cohesive bed, subject to waves and currents. The specific purpose is that of finding a new formula for the prediction of the equilibrium scour depth under submarine pipelines. After a theoretical analysis of the main parameters, the sought formula has been found to be a function of: (i) the hydrodynamic forces acting on the cylinder (through the Keulegan–Carpenter parameter KC), (ii) the clay content of the soil C_c, and (iii) the burial depth e₀/D. In the presence of small amounts of clay (C_c< 5 %), the scour depth depends directly on KC (as confirmed by many literature works for pipelines lying on sandy soils, e.g. [18]) and inversely on C_c (as already seen for bridge abutments on cohesive soils, e.g. [1]), the best-fit law being characterized by a coefficient of determination R² = 0.62. If some burial depth is accounted for, this being a novelty of the present work, a more general formulation can be used, valid in the presence of weakly-cohesive soils and with burial depths of the pipe smaller than 0.5 (R² = 0.79). For large clay-content ranges (2% < C_c < 75 %), the scour depth depends directly on both KC and C_c, this giving R² = 0.79 (no burial depth) and 0.91 (some burial depth). However, this finding is at odds with the main literature, because, for large amounts of clay, it is fundamental to consider the liquidity index LI, which accounts for some important clay properties, like the plasticity. We argue that the absence of LI is balanced by the direct dependence of the scour depth on C_c. Notwithstanding the small number of available data, a formula for the prediction of the scour depth under pipelines lying on cohesive soils is fundamental for several engineering applications. The present contribution represents the first attempt to build such a formula, when the pipeline is subject to the wave-current forcing and the seabed is characterized by a relatively small clay content.     

Toward a quick evaluation of the performance of gravity installed anchors in clay: Penetration and keying

Gravity installed anchors (GIAs) are the most recent generation of anchoring solutions to moor floating facilities for deepwater oil and gas developments. Challenges associated with GIAs include predicting the initial embedment depth and evaluating the keying performance of the anchor. The former involves high soil strain rate due to large anchor penetration velocity, while the later influences the subsequent behavior and pullout capacity of the anchor. With the coupled Eulerian–Lagrangian method, three-dimensional large deformation finite element models are established to investigate the penetration and keying of GIAs in non-homogeneous clay. In the penetration model, a modified Tresca soil model is adopted to allow the effects of soil strain rate and strain softening, and user-defined hydrodynamic drag force and frictional resistance are introduced via concentrated forces. In the keying model, the anchor line effects are incorporated through a chain equation, and the keying, diving and pulling out behaviors of the anchor can all be replicated. Parametric studies are undertaken at first to quantify the effects of various factors on the performance of GIAs, especially on the penetration and keying behaviors. Based on the results of parametric studies, fitted formulae are proposed to give a quick evaluation of the anchor embedment depth after the installation, and the shackle horizontal displacement, shackle embedment loss and anchor inclination at the end of the keying. Comparative studies are also performed to verify the effectiveness of the fitted formulae.