Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

Situating corporate framings of child labor: Toward grounded geographies of working children in globalized agriculture

The expansion of multinational corporations into agricultural production around the world is resulting in new forms of engagement in specific places. In the context of neoliberal restructuring, these engagements are tied to shifting landscapes of societal, governmental and industry-based perceptions on the role of corporations in labor regimes. But how are these engagements developed and how do they connect to the everyday lives of workers? In India, when Monsanto expanded into hybrid cotton seed production in the early 2000s, the corporation came under pressure to address concerns over the widespread employment of children and young workers for seed pollination. In response, the corporation developed an approach to child labor that, I argue, works to reinforce generalized and problematic notions of childhood and work. Corporate engagements in global agriculture need to be situated in time and space, and alongside the experiences of workers. Children experience attempts to shape their patterns of work and mobility as a series of surmountable obstacles, disconnected from the process of deciding whether or not they will engage in this work. Drawing on qualitative fieldwork in Gujarat and Rajasthan, and documentary analysis of public documents, I outline the development of a corporate response to child labor and place it within the context of the rise of corporate social responsibility, global ideas of child labor, and in the specific case of cotton seed production in western India. I demonstrate that contextualized geographies of working children in globalized agriculture reveal the nature of multinational corporations’ engagements in specific places.     

The earthquake foci and deep structure of the Earth’s crust and upper mantle along the southern Sakhalin-Sea of Okhotsk-Kamchatka profile

The Kuril-Kamchatka seismofocal zone was thought to be a single plate approximately 90 km wide and dipping to a depth of 700 km at an angle of 40°–45°. This concept reflects primarily the physical differences (elastic wave velocities, density, temperature, etc.) between the seismofocal zone and the mantle hosting it. Detailed investigations show that the seismofocal zone proper is also heterogeneous with earthquake hypocenters variably concentrated and clustered within this zone, where both seismogenic and aseismic strata, as well as subvertical zones, can be identified. The latter are reflected in the structure and faults of the Earth’s crust and upper mantle.     

填土表面倾斜时的主动土压力计算

支护结构工程中,当坡顶填土表面倾斜时,无法采用常规的土压力理论进行计算。探讨了《建筑边坡工程技术规范》存在的问题,提出了推荐方法。通过算例验证了推荐方法,具有计算简单、计算结果合理的优点,可供工程设计中参考使用。     

舒城县东部地区地下水环境质量评价与污染分析

根据舒城东部地区地下水环境实地调查结果,本文选取78个地下水样,按埋深10m以浅、10m以深进行地下水质量分类评价和污染分析.结果表明:①地下水水质绝大部分为Ⅳ类、Ⅴ类水,地下水污染非常严重,主要污染因素是Fe、Mn、Al、Hg、NO3-和氨氮等.②埋深10m以浅的地下水水质主要是Fe、Mn、Al、Hg、NO3-和氨氮...     

围压-孔压改变条件下致密砂岩及泥页岩泊松比变化特征及机制

在围压(外压)或孔压(内压)发生变化的条件下,致密砂岩及泥页岩泊松比的变化特征及机制仍有待厘清.本研究从Terzaghi有效应力理论和国内学者提出的新有效应力概念出发,基于松辽盆地高台子组致密砂岩、青山口组泥页岩三向动、静态泊松比测定结果,剖析了两类岩石泊松比的变化特征及机制.岩石样品三向泊松比变化曲线的分布呈现显著的...     

基于反褶积算法的地震干涉技术被动源成像

地震干涉技术可以将任意2个检波器接收到的数据合成为在若干检波器之间传播的波,就好像其中的一个检波器作为一个虚拟震源来发挥作用。它可以从混沌无序的地震信号中发现有用信息,从地震噪声中提取有用信号以此推断地震波穿过介质的地质构造。基于反褶积算法,对其理论公式进行了较详细的推导,实现被动源地震干涉成像,证明了反褶积算法的可行性;并将其结果与互相关算法的结果进行对比,分析了2种方法在信噪比和分辨率方面的差异。数值计算表明,反褶积算法的纵向分辨率比互相关算法的高。对其进行的加噪试算表明,震源叠加后的反褶积算法呈现出高信噪比的特点。     

地表的分形测量及其大地构造学意义

以湖北红安地区为例,采用投影覆盖法(projectivecoveringmethod)对地表进行了二维分形测量,结果表明,地表面积具有双分形(bifractal)关系,即具有小尺度的结构分形(texturalfractal)和大尺度的构造分形(structuralfractal),分叉点(breakpoint)的尺度为3610m,分维值都在2～3之间且结构分维值大于其构造分维值。可见,地表形态具有分形性质,分维值可以指示地表形态的复杂程度。构造分维值可作为构造活动强度的一个指标,可为大地构造单元的划分提供定量依据。复杂地表形态主要是由构造活动(内营力作用)和各种复杂表生地质作用(外营力作用)引起的,前者主要控制大尺度的地形起伏,后者则塑造小尺度的地表形态。地表分维值可以指示地表的发育成熟度,该地区小尺度的结构分维值大于大尺度的构造分维值表明其处于地表形态的发育晚期。此外,地表的分形尺度可以来用确定构造活动尺度,从而指导构造地质与找矿勘探研究。