电感耦合等离子体发射光谱法测定硼硅酸盐玻璃中的硼等常见元素

硼硅酸盐玻璃中的硼、钙、镁、铝、铁、钛、硅等常见元素普遍采用各元素分别测定的方式进行分析,分析效率很低;而且硼的测定普遍采用容量法,当B2O3含量低于1%时,容量法测定误差较大。本文以KOH熔融的方式消解样品,采用电感耦合等离子体发射光谱法(ICP-AES)进行分析。通过实验研究了KOH用量和不同称样量对B2O3测定结果的影响。结果表明,KOH用量在3 g以上时有较好的熔样效率和熔样效果,称样量低于0.4 g对B2O3测定结果无明显影响,考虑到其他元素的测定,确定了KOH用量优选3 g,称样量优选0.1 g。在此条件下,测定B2O3等常见元素的精密度(RSD,n=6)≤2%,加标回收率在96.0%~105.6%之间,除Si O2测定误差较大外,其他元素的测定结果均令人满意。本方法确定的B2O3的定量限为0.067%,且对于B2O3最高含量达到16%的测定结果也令人满意,因此可测定B2O3含量的范围至少为0.067%~16%。当样品中的B2O3含量高于4%时,方法准确度和精密度与国家标准分析方法(容量法)相当;当B2O3含量低于1%时,方法准确度和精密度都优于容量法。与现有报道相比,本方法显著拓宽了B2O3的测定范围,并具有良好的准确度,而且在B2O3准确测定的同时,也实现了Ca、Mg、Al、Fe、Ti的定量分析和Si的半定量分析,大大提高了分析效率,可以实现硼硅酸盐玻璃中B2O3等常见元素的准确快速分析。     

南海北部沉积物常量元素变化、碳酸盐旋回及其古环境意义

通过对南海北部ODP1145站沉积物的常量元素和碳酸盐分析,探讨了早更新世南海北部沉积物常量元素和碳酸盐含量变化特征及其古环境意义.结果表明,南海北部沉积物中主量元素CaO、Fe2O3、K2O、Na2O、MnO和P2O5受碳酸盐含量影响相对较小,而SiO2、MgO、Al2O3和TiO2受到碳酸盐含量影响相对较大.碳酸盐校正后的常量元素变化可以划分为3种类型,即PC1、PC2和PC3,它们的主要特点有:PC1元素组合包括了SiO2、CaO、Na2O、P2O5、Fe2O3和K2O,主要反映了与季风强度有关的生源物质产率变化,指示了距今2.5～1.5Ma时段生产力的逐渐降低;PC2元素组合(Al2O3、TiO2)代表了陆源物质的输入,指示了在约2Ma开始陆源物质输入的明显增加;PC3元素组合(MgO、MnO)可能与海洋自生作用有关,反映了海底氧化/还原环境的相对变化.早更新世南海北部CaCO3含量呈阶段性降低,一方面受陆源物质稀释作用的影响,另一方面可能更与生物生产力逐渐降低有关.主量元素组合及碳酸盐含量在约2Ma和1.7Ma左右均发生显著变化,可能指示了早更新世时期东亚冬季风的两次增强.     

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.     

美、日、欧、俄空间政策调整产生的机遇与挑战

冷战结束后,以军事利用为基本特征的美苏空间争夺,已经被以科技创新和经济为中心的综合国力竞争所替代,信息技术和经济全球化的发展,导致外层空间成为具有知识创新要素和技术带动能力的竞争新领域。世界经济大国已经认识空间政策的设计是事关提升综合国力和竞争优势的重大意义。近年来,美、日、欧对空间政策进行了冷战结束后的第一次,全面重大的调整,伴随着体制转型俄罗斯空间政策调整也在展开,面对即将形成的国际空间竞争与合作新的格局和带来新发展机遇,如何清晰地鉴别、定位,对空间政策做出正确的调整,抓住历史机遇应对挑战是摆在中国面前的战略性、全局性和方向性问题。     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

河流健康评价的主评指标筛选

河流健康是近年来探讨水资源问题的一个热点,其评价指标体系正成为河流管理的目标。为了筛选出一些基本的、易于量化的主要评价指标来揭示河流健康基本状况和变化趋势,通过对1972～2010年约150篇相关文献、45个河流健康评价指标体系902项指标的整理和归纳,应用统计、层次和相关性分析法,确定各指标的被采用率,并同时综合考虑指标的重要性、普遍性、可量化性和易获得性,筛选出揭示河流生境物理、水环境、生物和水资源利用4类特征的主要指标。结果表明,有以下8个指标可作为河流健康的主评指标:河岸植被覆盖率、河流连通性、湿地保留率、径流量变化率、水质达标率、鱼类生物完整性指数、水资源利用率和流域天然植被覆盖率。     

An overview on the seismic zonation and microzonation studies in India

The present study presents a review on the progressive development of the seismic zonation map of India both from official agencies and also from independent individual studies. The zonation map have been modified and updated regularly with the occurrence of major destructive earthquakes over the years in the Indian subcontinent with the addition of new data. This study discusses the criteria chosen for the progressive zonation and the major earthquakes that were responsible for retrospection of the earlier published maps. The seismic zonation maps of India have also been prepared by various independent workers by adopting different approaches to achieve the purpose of the zonation. Despite the endeavors from various sources to provide a solution for the problem of earthquake hazards in India, there were many limitations on the zonation map as it gives the picture at a regional scale mostly on the bedrock level without addressing the local site conditions. But nevertheless, the seismic zonation map gives basic guidelines for any region to know the hazard scenario and if any city or urban population is under threat from seismic point of view, further site specific seismic microzonation may be carried out. In the International scenario, the Global Seismic Hazard Assessment Program (GSHAP) in 1999 prepared a hazard map for world in terms of peak ground acceleration (PGA) with a 10% probability of exceedance in 50 years, but it turned out to be an underestimation of the hazard parameter when compared with the observed PGA. To tackle the problem of seismic hazards, there was a need to have a detail study on the local site conditions in terms of its geological, geophysical and geotechnical properties. With the advent of better instrumentation and knowledge on the mechanics of earthquakes, it was possible to identify zones of hazards at a local level and this gives rise to the study of seismic microzonation. Seismic microzonation work has been carried out in India in some of the strategic important mega cities and industrial build up that has the potential of being damaged from future earthquakes, as has been shown in the past. Though the microzonation map is not the final output map, as it can still be updated at later stage with more input data, it does provide a more realistic picture on the site specific seismic hazard.     

空气滤膜采集大气浮尘样品中多元素的测定

用氢氟酸-盐酸-硝酸-高氯酸体系对空气滤膜上附着的浮尘样品进行分解,电感耦合等离子体发射光谱法、电感耦合等离子体质谱法同时测定溶液中15个主量和微量元素铁、铜、锌、镍、镧、铈、锂、锰、铬、镉、钴、铅、钍、铊、铀。将国家一级标准物质模拟浮尘样品加入空白滤膜进行测定,结果与标准值相符。各元素4次测定结果的相对标准偏差(RSD)小于5%。     

测绘地理信息类专业双语课程评价体系构建

中国高校"双一流"建设要求培养兼备专业能力与国际竞争力人才,而双语教学则是一条有效途径。以CIPP(context,input,process,product)课程评价模型为理论依据,根据测绘地理信息类专业双语教学的特点,从背景评估、输入评估、过程评估、成果评估4个方面构建了测绘地理信息类专业双语课程评价指标体系,为提高中国测绘地理信息类专业双语课程的教学质量提供理论基础。     

汉江上游黄土常量元素地球化学特征及区域对比

本文对汉江上游黄土的常量元素含量及相关地球化学参数CIA、Na/K、淋溶系数、退碱系数、残积系数等进行了系统分析。结果显示：① 汉江黄土的主要化学成分为SiO₂、Al₂O₃和Fe₂O₃,三者含量总和达767.3 g/kg;常量元素含量大小排序为SiO₂>Al₂O₃>Fe₂O₃>K₂O>MgO>Na₂O>CaO。风化成壤过程中Na、Ca、Mg、Si发生不同程度的迁移淋溶,而Fe、Al、K相对富集。② 其风化成壤强度呈现从马兰黄土L₁→过渡性黄土L_t→古土壤S₀逐渐升高、全新世黄土L₀又降低的规律,记录了该区域气候经历了末次冰期（55.0-15.0 ka BP）冷干、早全新世（15.0-8.5 ka BP）增温增湿、中全新世（8.5-3.1 ka BP）达到最暖湿,晚全新世（3.1-0.0 ka BP）降温变干的演变过程。③ 汉江黄土与洛川、巫山、下蜀黄土的元素组合特征高度一致,不同地区常量元素（CaO除外）含量十分接近且UCC标准化值变幅均小于0.25,这暗示了它们风化之初具有相似的风成沉积基础;但不同区域黄土的化学风化强度差异明显,大致呈现洛川黄土<汉江黄土<巫山黄土<下蜀黄土的趋势,与中国现代季风气候的空间变化规律相吻合,即不同地区黄土风化程度差异主要是东亚季风变化影响的结果。