Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil

Effect of chemical fertilizers (urea, NH₄Cl, Ca(NO₃)₂, KCl and KH₂PO₄) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure, it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil. Applying urea (CO(NH₂)₂) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH₄Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH₂)₂ raised the soil pH from 4.51 to 4.96, whereas NH₄Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH₂PO₄ reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual (RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH₄Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH₂PO₄ decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil.     

榴辉岩的化学分类

以山东荣成地区的榴辉岩为例,把榴辉岩分为镁一榴辉岩、铁一榴辉岩和钙一榴辉岩三类。三类榴辉岩的岩石化学,主要造岩矿物成分都有明显差别,石榴石分别是镁铝榴石、铁铝榴石和钙铝榴石。绿辉石的硬玉分子也有不同。三类榴辉岩的化学成分限制是Mg-榴辉岩MgO>10%,石榴石以镁铝榴分子占优势,Fe-榴辉岩的MgO<10,石榴石以铁铝榴石分子占优势。Ca-榴辉岩CaO>19%,石榴石以钙铝榴石分子优势。     

宝顶山石窟造象岩壁风化产物化学特征及形成分析

为研究宝顶山石窟区造象岩壁风化破坏及渗水危害的作用机理,选择不同类型风化产物进行定期采样监测。本文重点论述了外围岩石和造象岩壁风化产物的化学成分及矿物成分、风化产物可溶盐的化学特征及可溶盐类型,以及这些特征的多年变化规律,分析论证了可溶盐不同水化学成因类型的形成特征,为防风化防渗水危害治理措施提供可靠依据。     

森林经营措施对土壤的扰动和压实影响

根据森林经营措施对林地土壤的扰动和压实及其对树木生长和森林生产力的影响 ,指出森林经营措施对土壤造成的干扰是长期存在的 ,干扰强度越大 ,对林地生产力的影响越严重。从伐区作业、林地清理、整地、幼林抚育等方面提出减少土壤受扰动和压实的具体措施 ,为减少经营措施对林地生态系统的影响 ,从而改进传统的森林经营措施 ,实现森林可持续经营提供借鉴。     

考虑几何非线性的强夯流固动力耦合分析

针对强夯法加固地基机理的流固动力耦合分析问题,本文考虑土体的几何非线性,建立土体非线性动力平衡方程和整体流固动力耦合方程,给出土体非线性动力平衡方程的迭代计算格式和流固动力耦合方程的解耦计算方法,并对一具体算例进行了数值分析,得到了地基位移、应力等在强夯作用下的变化规律和在空间上的分布特征,为精确模拟分析强夯加固机理提供了有效途径.     

围隔生态系中叶绿素a浓度、化学耗氧量及透明度之间统计关系的研究

通过对水库中12个围隔两次取样的叶绿素a浓度(单位:μg/L)、化学耗氧量(单位:mg·O_2/L)和塞克透明度(单位:m)的实验数据分析,求得如下回归方程: (1)[Chla]=17.60·[SD]~(-1·86) r=-0.87 (2)[Chla]=-28.85+7.32·[COD] r=0.89 (3)[COD]=6.88·[SD]~(-0·68) r=0.91本文还对这些结果进行了讨论。     

流体包裹体方法在油气源追踪对比中的应用——以四川盆地碳酸盐岩大型气田为例

本文运用流体包裹体方法，基于薄片观察和岩矿学研究，探讨了四川盆地碳酸盐岩大型气田的气源。首先对包裹体的生源属性、多期捕获和后生变化进行了精细的鉴别分析。在此基础上，通过成岩自生矿物微量元素、包裹体相组成、均一温度、初熔温度等参数鉴别多期演化的油气充注。通过烃类包裹体化学成分初步鉴别出煤成气和油型气。根据烃类包裹体的相组成鉴别有机质可能来源于腐泥型源岩还是腐殖型源岩。最后根据同期包裹体生物标志物确定某一期次的油气所对应的烃源层。结果表明研究成果符合地质实际，为传统的油气源追踪对比研究提供了一个重要有效的辅助方法。     

压实过程对红黏土的孔隙分布影响研究

为研究压实作用对红黏土孔隙分布的影响,采用液氮冻干法对经过压力板仪脱至残余含水率后的压实试样进行干燥,继而利用孔隙仪测试其孔隙分布特征。结果表明,不同干密度试样的孔隙分布特征在孔径d >10 μm范围内差异性比较明显,干密度越大分布在该范围内的孔隙越少,但所有试样的大部分孔隙主要分布在孔径d <0.1 μm的范围内,并且分布密度十分相似。换言之,常规压实作用只能改变土体某一较大孔径范围内的孔隙,而对小孔径的孔隙改变不大,这也对于说明红黏土路基填料的压实,常规的压实作用对提高土体的压实度幅度有一定范围。     

Soil moisture dynamics in coastal savanna soils in the tropics under different soil management practices

Abstract

Soil moisture is important for crop cultivation and its adequacy to meet crop-water requirements is determined by the degree of soil management practised and the quantity of water applied to the soil. This study investigates soil moisture dynamics on three plots: Bare (clean, weeds removed), Weedy (kept weedy), and Mulched (cleared of weeds and fully covered with grass mulch) during rainy and dry periods at the Teaching and Research Farm at the University of Cape Coast, in the coastal savanna zone of Ghana. Soil moisture dynamics under different levels of soil compaction were also studied. A Massey Ferguson tractor (MF265) was used to compact the soil at various levels by making 0, 1, 5, 9 and 13 passes. During both the rainy and the dry periods, moisture retention in the soil under bare, weedy and mulched plots increased with depth. During the rainy period, the mean soil moisture retention was in the order: Mulched > Weedy > Bare at both 0–20 cm and 20–40 cm depths. Within a 7–day period, soil moisture measurements from a day after heavy rainfall (intensity > 7 mm h^?1) gave mean moisture losses of 2.7, 4.1 and 3.9% for the Bare, Weedy and Mulched plots, respectively. During the dry period, however, the mean soil moisture retention was of the order: Mulched > Bare > Weedy at both 0–20 cm and 20–40 cm depths. Mean moisture loss during a 7–day dry period was 4.5, 2.9 and 3.4% for the Bare, Weedy and Mulched plots, respectively. Under different levels of soil compaction, the mean moisture retention in the soil increased from 8.3% at 0 pass to 17.8% at 13 passes within the 0–20 cm depth, whilst it decreased from 13.3 to 5.9% from 0 to 13 passes, respectively, within the 20–40 cm depth. It was realized that at less than two passes, the mean soil moisture retention within the 0–20 cm depth was less than the mean moisture retention within the 20–40 cm depth, but the converse happened for more than two passes. The study showed that mulching the soil surface helped to retain enough soil moisture during both the rainy and the dry seasons. Also, soil with high sand content required some sort of soil compaction in order to retain enough moisture at the crop rooting zone.     

挤密条件下U型地埋管换热器换热效率的理论分析及数值模拟

土层的导热系数是影响地源热泵地埋管换热器换热效率的重要因素之一,与土样的密度密切相关。为了提高地源热泵换热器换热效率,本文基于柱热源理论,建立了挤密钻进条件下换热器的传热理论模型,对换热器的换热效率进行了计算,并利用Ansys有限元软件对土层挤密条件下换热器的换热效果进行了数值分析。结果表明,与传统方法相比,土层挤密可有效降低钻孔周围的热阻,U型管换热器的换热效率可提高17%~20%。