固—液反应体系CaF2—HCl—H2O内化学振荡的动力学模型

本文根据物理化学基本原理，提出HF的表面吸附催化机制对于CaF2-HCl-H2O固－液反应体系溶解振荡起着关键性作用。同时建立了该 体系的动力学模型，研究其振荡现象的非线性动力学起因，虽然这一数学模型是基于CSTR反应器为对象而建立的，不过其基本的结论对叠层式流动反应器的情况也是适用的。     

Compaction of granular soils by uniform vibration equivalent to vibrodriving of piles

Summary A programme of laboratory tests was undertaken to identify the volume reduction of a range of granular soils in response to uniform vibration. The purpose of the tests was to quantify the potential compaction settlement of granular soils due to vibrations typical of those experienced when sheet or bearing piles are installed or extracted by vibrodriver. The vibrations in soils within 2–20 m of a vibrodriven pile are well defined as sinusoidal, at the frequency of the vibrodriver, and typically in the range of 1.0g down to 0.02g (whereg=gravitational acceleration). Thein-situ conditions were replicated in the laboratory by vibration of a Rowe cell containing a soil sample. This allowed control of stresses before and during vibration. Tests were conducted on nine granular soils, ranging from uniform Leighton Buzzard sands to a sandy fine-to-medium gravel. Soil samples were prepared at minimum relative density, generally in the saturated state, but also dry and partly saturated. Each sample was consolidated at a selected effective stress of between 10 and 100 kPa. It was then vibrated vertically at increments of controlled acceleration, under conditions of free drainage and maintained confining stress. Reduction in sample thickness was measured continuously. Results showed that even in a small, drained, sample the full volume reduction was reached only after many minutes, although the early response was more rapid. The trends of results showed that: increased surcharge pressure reduced the subsequent vibratory compaction; well-graded soils showed greater compaction than more uniform sands; compaction increased markedly when acceleration exceeded 1 g; saturated soils showed larger compaction than dry and partially saturated soils; compaction was influenced little by frequency, although rate of compaction reduced with frequency increase.     

海南岛,台湾岛河流水化学比较研究

本文对我国两大岛屿——海南岛和台湾岛河流的主要离子化学及河流的物理和化学侵蚀率进行了比较研究,对两岛河流水化学的共同点和差异及其成因进行了探讨。研究表明,无论是河水离子总量,还是物理侵蚀率和化学侵蚀率,台湾岛均显著地高于海南岛。两岛河水中氯离子含量、物理侵蚀率和化学侵蚀率均为东部水系高于西部水系。     

中国东部三个中新生代含油(气)盆地和拗(凹)陷泥岩压实与流体运移模拟

根据自己研制的高压控温泥岩压实仪,对我国三水、泌阳和黄骅三个中新生代含油(气)盆地和拗(凹)陷进行了压实模拟,从而证实了我国东部三个中新生代盆地和拗(凹)陷存在四个压实阶段,证实了泥质沉积物和地温梯度是严重影响压实和流体运移的主要因素,同时还证实了三水盆地和泌阳凹陷存在着严重的剥蚀。     

Compaction of diagenetically altered mudstones – Part 2: Implications for pore pressure estimation

Diagenetically altered mudstones compact mechanically and chemically. Consequently, their normal compaction trends depend upon their temperature history as well as on the maximum effective stress they have experienced. A further complication is that mudstones are commonly overpressured where clay diagenesis occurs, preventing direct observation of the hydrostatic normal compaction trend. A popular way to estimate pore pressure in these circumstances is to calculate the sonic normal compaction trend in a well with a known pressure–depth profile by applying Eaton's method in reverse, and then to estimate pore pressure in offset wells using Eaton's method conventionally. We tested this procedure for Cretaceous mudstones at Haltenbanken. The results were inconsistent because the sonic log responds differently to disequilibrium compaction overpressure and unloading overpressure, and their relative contributions vary across the basin. In theory, a two-step method using the density and sonic logs could estimate the contributions to overpressure from disequilibrium compaction and unloading. The normal compaction trend for density should be the normal compaction trend at the maximum effective stress the mudstones have experienced, not at hydrostatic effective stress. We advocate the Budge-Fudge approach as a starting point for pore pressure estimation in diagenetically altered mudstones, a two-step method that requires geological input to help estimate the overpressure contribution from disequilibrium compaction. In principle, the Budge-Fudge approach could be used to estimate the normal compaction trend for mudstones at the maximum effective stress they have experienced, and so form the basis of the full two-step method through the use of offset wells. Our initial efforts to implement the full two-step method in this way at Haltenbanken produced inconsistent results with fluctuations in estimated pore pressure reflecting some of the fluctuations in the density logs. We suspect that variations in the mineralogical composition of the mudstones are responsible.     

Compaction of smectite-rich mudstone and its influence on pore pressure in the deepwater Joetsu Basin,Sea of Japan

Pore pressure prediction is needed for drilling deepwater wildcats in the Sea of Japan because it is known from past experience that there can be drilling problems can arise due to overpressure at shallow depths. The “Joetsu Basin” area is located offshore to the southwest of Sado Island on the eastern margin of the Sea of Japan. The sedimentary succession of the Neogene is mainly composed of turbidite sediments which contained smectite-rich mudstones. The cause of overpressure in the study area is expected to be a combination of mechanical disequilibrium compaction and chemical compaction, especially from the illitization of smectite.We have constructed basin models and performed numerical simulations by using 1D and 3D PetroMod to understand clearly the history of fluid flow and overpressure development in the lower Pliocene Shiya Formation and Middle to Upper Miocene Teradomari Formations. A compaction model coupled with both mechanical and chemical compaction for smectite-rich sediments is used for pore pressure calibration. We have examined three key relationships: porosity-effective stress, porosity-permeability, and the kinetics of smectite-illite transformation. We determined the ranges for the parameter values in those relationships that allow a good fit between measured and modelled pore pressures to be obtained. Results showed that for the most likely case, high pore pressure in the Lower and Upper Teradomari developed since 8.5 Ma and 5.5 Ma, respectively. Pore pressures in studied structures have approximately doubled since 1 Ma due to the high deposition rate of the Pleistocene Haizume Formation and smectite-illite transformation in the lower Pliocene-Shiya and Middle to Upper Miocene- Lower and Upperr Teradomari formations. In three cases (high case, most likely case and low case), the overpressures in the Shiya, Upper and Lower Teradomari Formations are less than 1 MPa, 15 and 30 Ma, respectively.The results provide a basis for planning future wells in the “Joetsu Basin” area and in other basins where geological conditions are similar, i.e., deepwater, high sedimentation rate, high geothermal gradient and smectite-rich sediments.     

Can light intensity cause shifts in natural product and bacterial profiles of the sponge Aplysina aerophoba?

The potential role of microbial consortia on sponge chemistry is well known. However, how environmental factors affect microbial and chemical profiles and how these shifts affect the sponge holobiont are far from being understood. This study experimentally investigated the effect of light on both the concentration of secondary metabolites and the bacterial assemblages of the sponge Aplysina aerophoba. We quantified major brominated alkaloids (BAs) using a high‐performance liquid chromatography system coupled with a UV‐detector and analysed sponge‐associated bacteria using denaturing gradient gel electrophoresis of 16S rRNA gene amplicons. We identified distinct chemical and bacterial profiles between the ectosome and the choanosome of A. aerophoba. The abundance of most secondary metabolites increased regardless of the illumination regime. We found that the probability of occurrence of three microbial phylotypes (operational taxonomic units 84, 86 and 87) was strongly associated with increasing concentrations of three brominated compounds (aerophobin‐1, aplysinamisin‐1 and isofistularin‐3). Although the role of these bacteria remains uninvestigated, these associations between natural products and specific microbial phylotypes outline further hypotheses that will improve our understanding of the organization and functioning of these complex host–symbiont interactions.     

Field Studies of Dynamic Compaction on Marine Deposits

Marine deposit ground usually need significant improvement before the construction of civil structures in coastal areas due to the poor mechanical properties of soils. Dynamic compaction (DC) is a widely used technique in such projects. In this study, a case history of DC tests in sandy soils with a weak embedded layer is introduced. Two series of DC tests—single point tests and impact zone tests—were applied to test zones with similar geological conditions to investigate the effect of energy level on the depth of improvement (DI). The highest energy used is up to 15000 kN · m. Field measurements were conduct before and after DC in each series to validate the effectiveness of improvement, including crater settlement, excessive pore pressure, and acceleration measurement for single point tests, and the pressure meter and CPT tests for impact zone tests. For single point tests, the effectiveness of improvement increases as the energy level increases to 12000 kN · m. Further increase of compaction energy does not have an effect on settlement, pore pressure, or ground acceleration. For impact zone tests, the energy level does not show a positive correlation with the DI, mainly due to the presence of an embedded weak layer.     

黄山夏季气溶胶多尺度吸湿性的参数化方案构建研究

利用2014年7月在黄山光明顶观测的气溶胶吸湿性参数（κ）和气溶胶离子化学组分、有机碳（OC,organic carbon）数据,对多尺度气溶胶吸湿性参数进行分析,并在此基础上建立了多尺度κ的参数化方案。研究结果表明,影响黄山夏季气溶胶来源的主要气团包括西南气团、北方气团以及东南气团。黄山夏季κ的变化范围为0.2-0.48,且随粒径增大成先增大后减小的分布特征;气溶胶粒径在0.15-1.1 μm的强吸湿段,κ>0.3,而在粒径小于0.15 μm和粒径大于1.1 μm弱吸湿段,κκ分布不同,气溶胶粒子在小于1.1 μm的粒径段,当受西南气团影响时,κ值最大,而受东南气团影响时,κ值最小;在气溶胶粒径大于1.1 μm时,κ在两个气团背景下呈现与气溶胶粒径小于1.1 μm时相反的分布特征。影响粒径小于1.1 μm气溶胶吸湿能力的主要水溶性化学组分为NH4+、SO42-、水溶性有机碳（WSOC,water soluble organic carbon）,而影响大于1.1 μm粒径范围气溶胶吸湿能力的主要水溶性化学组分为NH4+、SO42-、NO3-、WSOC和Ca2+。由气溶胶多尺度离子化学组分和WSOC构建的气溶胶κ的参数化方案,在小于1.1 μm和大于1.1 μm的粒径范围内的表达式分别为κreg=0.12+0.45fNH4++0.63fSO42-+0.18fWSOC和κreg=0.01+0.78fNH4++0.76fNO3-+0.8fSO42--0.28fCa2++0.14fWSOC（f为对应组分的质量份数）。两个参数化方案均能较好地预报κ,预报值κreg与κ的计算值间存在较好的相关关系,相关系数通过了置信度99%的显著性检验,且预报误差在30%范围内。      

几种红藻琼脂的组分结构及理化性质的比较

以我国3种经济红藻龙须菜、石花菜、坛紫菜为原料，对高温稀碱法、常温浓碱法和无碱法提取的琼脂进行理化性质和化学组分结构方面的横向比较。结果表明，所提取琼脂的主要组分均为无取代的琼脂糖；凝固温度与甲氧基的取代位置及含量有关；我国3种琼脂海藻均为优质的琼脂原料；提取琼脂时，石花菜不用碱处理，龙须菜和坛紫菜则必须经过碱处理；从灰分和硫酸基含量角度分析，石花菜琼脂优于坛紫菜琼脂后，后者又优于龙须菜琼脂。