赣中聚源大型石英脉型白钨矿床含铀富钨矿物初步研究

聚源钨矿是华南地区为数不多的大型石英脉型白钨矿矿床之一。在详细的野外地质调查基础上,本文利用α径迹蚀刻、电子显微镜、扫描电镜以及电子探针等实验手段,对该矿床含钨和含铀矿物开展了精细矿物学的研究工作,探讨了成矿过程中钨和铀的富集规律。研究显示,该矿床钨铀矿物的形成可分为四个阶段：第一阶段,钨铀主要进入富含Nb、Ti的氧化物矿物,形成铌铁矿、钇易解石等富钨矿物,另有极少量的钨进入黑钨矿和早阶段白钨矿;第二阶段,铌铁矿与钇易解石被后期流体交代,形成含钨富铀的骑田岭矿、铌锰矿以及钛-钇易解石;第三阶段,钨进入中阶段白钨矿,这一阶段也是钨最主要的矿化阶段;第四阶段,钨进入晚阶段白钨矿。最后两阶段白钨矿中铀含量不高。骑田岭矿(WO₃ 26.74%~29.68%),是聚源钨矿中除白钨矿和黑钨矿之外钨含量最高的含钨矿物。该矿易解石族矿物WO₃最高可达9.80%,极度富钨,是目前有文可查的钨含量最高的易解石。聚源钨矿中的含钨矿物大多数为白钨矿,但绝大多数的白钨矿却在骑田岭矿、易解石族矿物、铌铁矿族矿物、黑钨矿之后形成,说明成矿流体在演化过程中,绝大多数W首先进入富含Nb、Ti的含铀矿物和少量黑钨矿,之后才是白钨矿的大量结晶。

     

内蒙古北山造山带时空结构与古亚洲洋演化

内蒙古北山造山带自北向南发育红石山－百合山、月牙山－洗肠井和帐房山－玉石山3条蛇绿构造混杂岩带。其中北部的2条蛇绿岩带揭示了北山造山带两阶段演化的历史：月牙山－洗肠井蛇绿混杂岩带洋壳形成于530~520 Ma,沿该带多处保存较完好的蛇绿岩洋壳残块（洋壳结构具向北变新特征）,与北侧的早古生代公婆泉岩浆弧（由南向北岛弧成熟度变高）共同指示了北山洋向北俯冲消减的过程,即490 Ma初始俯冲,450~440 Ma为俯冲峰期,430~420 Ma为同碰撞阶段,400 Ma的双峰式岩浆岩组合指示了北山洋的消亡和后造山伸展的过程;红石山－百合山蛇绿混杂岩带是发育在雀儿山－圆包山岛弧基础上的SSZ型蛇绿岩,弧后开裂洋壳的形成与南侧最早发育的岛弧岩浆作用年龄接近（340~320 Ma）,310~290 Ma俯冲峰期造成南侧白山岩浆弧大量的岩浆活动,早二叠世末期（275 Ma）的辉长岩和花岗岩侵位及早—中二叠世双堡塘组下部的角度不整合均反映了红石山洋盆的闭合。前人所划"石板井－小黄山蛇绿岩带"实为一条早古生代发育的深大断裂,沿带发育中基性侵入体及少量超基性岩,后期（志留纪末）叠加有较强的韧性剪切变形。中生代以来的走滑作用和逆冲推覆构造改造了古生代的构造格架,使红石山-百合山蛇绿混杂岩带向北左行切错了十余千米,北山南部的中—新元古界推覆至下古生界之上。对内蒙古北山造山带时空结构的厘定,有助于中亚造山带造山作用过程的理解及其对古生代地壳增生的深入研究,也对银额盆地晚古生代新层系油气资源勘查起到基础支撑。     

湘中锡矿山式锑矿成矿地质条件分析

湘中锡矿山式锑矿形成于晚白垩-古新世,空间上与岩脉关系密切,各锑矿床、矿化点都伴有或附近发育有煌斑岩及中-酸性岩脉群,在锑矿成矿同期地质事件中,还有周缘一些中-新生代红色盆地的形成及基性火山岩喷发,据之,提出湘中锡矿山式锑矿成矿与燕山晚期拉张构造-岩浆活化作用有关.锑矿床(点)基本上都产出于两组或两组以上断裂的交汇点附近,3组断裂的交汇部位对应于最主要的锑矿床(点).矿体具体受断裂交汇部位附近的次级短轴背斜轴部、倾伏背斜的倾伏端及其翼部被纵向陡倾角断裂构造所切穿的部位控制,是断裂导矿与背斜构造圈闭的体现.岩性组合控矿表现为易于硅化蚀变交代的砂质碳酸盐岩与隔挡层泥质岩所构成的岩性圈闭.根据包裹体均-温度和盐度测定成果,推算成矿压力为(200～300)×105Pa,成矿深度约为1 km.     

Geochemical fractionation of Ni,Cu and Pb in the deep sea sediments from the Central Indian Ocean Basin: An insight into the mechanism of metal enrichment in sediment

Metal speciation study in combination with major element chemistry of deep sea sediments provided possible metal enrichment pathways in sediments collected from environmentally different locations of Central Indian Ocean Basin (CIB). Metal speciation study suggests that Fe–Mn oxyhydroxide phase was the major binding phase for Ni, Cu and Pb in the sediments. The second highest concentrations of all these metals were present within the structure of the sediments. Easily reducible oxide phase (within the Fe–Mn oxyhydroxide binding phases) was the major host for all the three metals in the studied sediments. Major element chemistry of these sediments revealed that there was an increased tendency of Cu and Ni to get incorporated into the deep sea sediment via the non-terrigenous Mn-oxyhydroxide fraction, whereas, Pb gets incorporated mostly via amorphous Fe-hydroxides into the sediment from the CIB. This is the first attempt to provide an insight into the mechanism of metal enrichment in sediment that host vast manganese nodule.     

Delineation and assessment of Central Indian Suture through lineament extraction approach using Remote Sensing and Geographic Information System

Lineament extraction approach allowed mapping of larger number of lineaments in a classical manner in tectonic and structural studies. In the present study, various techniques were adopted to extract lineaments using Landsat ETM+ images. To remove the biasness of the images, some pre-processing techniques like stream ordering, band differencing, colour texturing were employed to enhance the edges of the structural features. Extracted lineaments and its distribution and orientation were mapped using ArcGIS Spatial analyst tool. Results of the study showed maximum number of lineaments were oriented in the ENE–SWS direction with 63° overall inclination. Accuracy assessment and validation were made with respect to visual interpretation and overlaying the lineament on Digital Topographic Model as well as with respect to an existing geological lineament map of the study site. The result of accuracy assessment indicates higher compatibility of Central Indian Suture with the geological map of the study area.     

月球东海盆地综合解析与撞击初始条件的研究

东海是月球上最年轻的多环撞击盆地,关于其形成机制的研究很多,但成果大都基于正撞击的机制提出的,虽然有部分学者提出东海是斜撞击的,但缺乏具体撞击参数。本文通过多源数据融合,综合分析LRO影像数据、LOLA地形数据、M~3高光谱数据和IIM高光谱数据,对东海地区的地貌特征、物质成分进行了较为系统的解译,发现在东海中央熔融区存在一条与东海撞击方向垂直的中央隆起区域(中央隆起线),其也是中央熔融区粗糙部分与光滑部分的分界线,结合撞击坑成坑理论,认为其可能是撞击过程冲击波作用引起的堆叠作用形成的。同时利用GRAIL数据及对该地区的重力异常的成因进行了分析,认为异常是由于压强、温度及岩石粘度的改变引起局部莫霍面抬升和中央熔融物的形成而出现的,进而估算出熔融物占盆地内物质的25%,约为1.1×10~6km~3。同时,对GRAIL数据的剖面分析结果也支持了本文的斜撞击理论。最后,综合多方面的信息和撞击理论获取东海盆地构造分布图,并根据中央隆起线、溅射物及线性构造的分布特征等,提出东海盆地理论上是由一直径在50~100km的撞击体以10~30km/s的速度自东偏北约20°~30°方向以20°~30°的角度斜撞击月表而形成的。这可为研究更早期的月球撞击坑提供理论参考。     

西准噶尔玛依勒地区枕状玄武岩年代学、地球化学及岩石成因

通过对造山带内洋岛玄武岩的时代及地球化学性质研究,不仅可以进行古海山/大洋高原的识别,而且还可以进行古洋盆演化及古构造格局恢复。笔者等最新在西准噶尔玛依勒山北侧识别出一套枕状玄武岩,其与火山碎屑岩、硅质岩共生。枕状玄武岩斜长石微晶普遍发育中空骸晶结构,是在水下熔岩急剧萃冷条件下迅速结晶的产物。通过LA-ICP-MS锆石U-Pb测年,获得枕状玄武岩206Pb/238U加权平均年龄为437.2±2.2Ma,该年龄的获得填补了志留纪碱性玄武岩的空白。岩石地球化学分析结果显示,玛依勒枕状玄武岩为碱性玄武岩系列,岩石具有中等Si O2(44.89%~47.81%),高Ti O2(3.28%~4.12%)及P2O5(0.50%~0.70%),低Mg O(3.49%~6.79%),轻、重稀土元素分异较为明显((La/Yb)N=5.5~7.3),无明显Eu异常(Eu/Eu*=0.96~1.06),相对富集Rb、Th、U,亏损Ba、K、Sr,没有明显Nb、Ta负异常,这些地球化学特征与洋岛玄武岩(OIB)极其相似。微量元素含量及反映源区性质的比值表明,枕状玄武岩来源于富集地幔源区,主要组成为尖晶石和石榴石二辉橄榄岩,并发生了5%±的部分熔融,其形成于大洋板内与地幔柱有关的海山/大洋岛屿环境。结合前人研究,认为西准噶尔乃至古亚洲洋在中古生代洋内俯冲的同时,大洋板内可能存在地幔柱活动。     

西准噶尔成矿带晚古生代花岗岩类岩浆活动及其构造意义

中亚造山带是晚古生代地壳显著生长与大规模成矿的重要地区。本文采集了中亚造山带西部的西准噶尔成矿带哈图-别鲁阿嘎希及其附近地区11个岩体共33件花岗岩类样品,对其开展了岩石地球化学与同位素示踪等研究,厘定了该地区晚古生代岩浆活动的特点与大地构造环境,并与哈萨克斯坦境内的巴尔喀什成矿带晚古生代岩浆活动进行了对比。研究表明,哈图地区晚石炭世花岗岩类主要为后碰撞伸展构造环境的A型花岗岩类,别鲁阿嘎希等地区存在洋内俯冲与岛弧环境的埃达克岩,显示了西准噶尔晚古生代构造环境时空变化的复杂性。该地区花岗岩类εNd(t)值较高(+4.62~+7.53)、εSr(t)值为(-57.61~+18.21),具有中亚造山带花岗岩类的共同特征,为古生代增生的新生陆壳,其源区与亏损地幔组分具有亲缘关系,这与巴尔喀什成矿带东段的花岗岩类具有一致性。花岗岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值范围分别为18.2776~19.1677、15.5260~15.5796和38.2080~39.0821,为造山带花岗岩类。     

Application research of enhanced in-situ micro-ecological remediation of petroleum contaminated soil

Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation technique includes optimistic in-situ microbial communities, physical chemistry methods, alfalfa planting and regulation of soil environmental elements. Experiments showed that the oil content in the contaminated soil with oil content about 2 898.25 mg/kg can be reduced about 98.61% after in-situ micro-ecological remediation for 99 days, which demonstrated the effectiveness of in-situ micro-ecological remediation methods for petroleum contaminated soil in central plains of China, and explored the practical and feasible application of these methods.     

New tectonic map of Northern-Central-Eastern Asia:Position and evolution of Mesozoic sedimentary basins

The beginning of the XXI century was marked a new rising of the international tectonic cartography as a result of analysis and synthesis of a huge volume of geological information obtained for the territory of Asia especially during the last 30 years. The previous tectonic maps for Asia were created in the 1960 s--1970 s of the last century. Since that time,the national geological surveys have compiled tectonic maps exclusively in the limits of their own state boundaries. The international cooperation of five countries since 2002( Russia,China,Mongolia,Kazakhstan and Republic of Korea) gave a unique possibility to join the data into a united cartographic form as Atlas of Geological Maps( since 2002-Atlas of Geological Maps of Central Asia and since 2007-Atlas of Geological Maps of Northern-Central-Eastern Asia). Both atlases include four maps: geological,tectonic,metallogenic,and energy resources. Tectonic Map of Northern-Central-Eastern Asia and Adjacent Areas at scale 1 ∶ 2 500 000 was the key map for further compilation of the metallogenic and energy resources( coal,oil and gas) maps. By this reason,special attention was given to showing the structure and composition of the Mesozoic sedimentary basins in Northern-Central- Eastern Asia as the most perspective structures for oil-and-gas and coal prospect.