Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

硅质碎屑砂岩中胶结物来源的新认识

分析了浅埋藏砂岩的成岩环境,并从岩石学、矿物学、同位素及质量平衡估算方面论证硅质碎屑砂岩中的胶结物主要来源于砂岩浅埋藏期间的地下水,进而分析浅埋藏带内地下水的流动机制及早期胶结作用对晚期成岩作用的影响。     

Stable isotope study of carbonate-cemented rocks from the Pobitite Kamani area,north-eastern Bulgaria

The Precipitation of carbonate cements in the Pobitite Kamani area (Lower Eocene) began during early diagenesis of sediments. There is evidence, however, that calcite is still forming today.The negative ¹³C values to –29.2 suggest that the carbonate formed during degradation of ¹²C-enriched organic matter (perhaps partly from oxidation of methane). The ¹⁸O values of –0.9 to –1.6 reflect the marine origin of the early diagenetic carbonate cements. Most of the carbonates, however, formed during late diagenesis (at approximately 1300 m burial depth) and/or recently (after uplift) from percolating groundwaters. These carbonates have an isotopic composition characteristic of carbonates which precipitated from meteoric waters under normal sedimentary temperatures in isotopic equilibrium with ¹²C-enriched soil carbon dioxide.     

硫铅酸盐“S”型瞬凝水泥干法护壁堵漏技术研究

介绍了硫铝酸盐“Ｓ”型瞬凝水泥干法者漏时使用的配方,阐述了输送工具和扫孔钻具的设计以及灌注工艺技术。     

The first record of dinosaurs in the Dalmatian part (Croatia) of the Adriatic-Dinaric carbonate platform (ADCP)

The first discovery of dinosaur footprints on the Dalmatian part of the Adriatic-Dinaric carbonate platform (ADCP) is reported. They constitute the geologically youngest record of footprints on the ADCP. The trackbearing layer was formed in the intertidal environment and represents the final stage of a shallowing-upward cycle. Just below it, a heavy dinoturbated limestone layer can be observed. Microfacies analysis, incorporating evidence from benthic foraminifera and algae, indicates a Late Turonian–Early Coniacian age. The overall morphology and size of the footprints points to sauropod dinosaurs; they represent the largest forms recorded so far on the ADCP. This hints at a prolonged sauropod presence on the platform and to its Late Cretaceous connection to the continent rather than isolation.     

Modeling of the classification behavior of the diaphragms used in multi-chamber cement mills

A new approach has been developed for describing the classification that arises at the diaphragm in multi-chamber ball mills. Fourteen industrial scale cement mills have been sampled in this study and after mass balancing, model fits of the equipment were done. Successive mill product predictions for the sampled conditions were achieved, and requirements to build up an optimization capable model are discussed.     

Production of carbonate and silica nano-particles in stirred bead milling

This paper presents the experimental results of the mechanical production of silica and carbonate colloidal particles below 100 nm using two types of stirred bead mills (i.e., DCP Superflow 12 and PML H/V). It is shown that the stirred bead mill with very small beads can be used as an efficient equipment for the production of the colloidal particles in nanoscale from the feed materials of several microns in sizes at high energy consumptions. The DCP Superflow mill with high power densities is superior for the effective size reduction and production rate, compared to the conventional PML H/V mill with lower power densities. The smaller particles could be produced by the DCP Superflow mill at the same level of high energy inputs as from the PML H/V mill. The “grinding limit” for the processes in the mills has been discussed.     

A Solution to the Problem of Predicting the Suitability of Silty–clayey Materials for Cement-stabilization

Major geotechnical problems in construction involving silty–clayey soils are due to their low strength, durability and high compressibility of soft soils, and the swell–shrink nature of the overconsolidated swelling soils. Confronted with these problems, a suitable ground improvement technique is needed, for deep excavations in soft clays, for stability, durability and deformation control. Cement-stabilization is one of the alternatives. An increase in strength and durability, reduction in deformability are the main aims of this method. Conventional cement-stabilization methods are used mainly for surface treatment. However, the use of cement has recently been extended to a greater depth in which cement columns were installed to act as a type of soil reinforcement (deep cement–soil mixing and cement jet grouting). In situ engineering properties of these silty–clayey soils are often variable and difficult to predict. For this reason cement-stabilization methods have a basic target to control the aforementioned engineering properties of these clays so that the properties of a silty–clayey soil become more like the properties of a soft rock such as clayey shale or lightly cemented sandstone. So cement-stabilization of these soils is essential to control their engineering properties and to predict their engineering behaviour for construction. In an effort to predict, classify and study the suitability of silty–clayey soils for cement-stabilization both slaking and unconfined compressive strength tests were carried out on clayey–sand mixtures consisted of two types of clays, kaolin and bentonite. Finally diagrams were prepared to study the variation of slaking and strength due to compaction, curing time and cement percentage and also to predict areas of efficient cement-stabilization.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

测井资料在碳酸盐岩储层评价中的应用

以塔河油田碳酸盐岩储集层基本特征为依据，利用常规和能谱测井资料信息比值法和重叠法等技术．致力于储集层缝、孔、洞测井响应特征敏感性评价研究，从中提取8项储层敏感性参数，并对其进行综合评判，确定出划分储层类别的标准，经过50口井的测试资料验证，采用多参数综合评判来划分储层类别是可行的，对储层的评价效果较好，使常规测井资料得到了更深入、广泛的应用。