Hype among low-carbon technologies: Carbon capture and storage in comparison

Carbon dioxide capture and storage (CCS) technology has become a crucial part of climate change mitigation strategies around the world; yet its progress has been slow. Some have criticised CCS as a distracting hype, even as mainstream support continues. This article adapts the literature on technological hypes to develop a framework suitable for technologies with limited media/public exposure, such as CCS. It provides a qualitative context and analyses seven quantitative indicators of hype that are largely internal to the CCS technology regime. Throughout, the article contrasts results for CCS with those of comparable technologies. The main findings, which support the view that CCS has been hyped, are as follows. “Expectations” mounted rapidly in the form of project announcements for electricity applications of CCS and deployment forecasts in influential reports. However, announcements soon plummeted. “Commitments” remained high, nonetheless, judging by allocations in public budgets and number of peer-reviewed publications. Meanwhile, “outcomes”—in terms of patents, prototypes and estimated costs—reveal few if any improvements for CCS. Considering these findings and the characteristics of CCS, its development is likely to be more difficult than initially expected. Accordingly, this article calls for decisively prioritising CCS for industrial and, potentially, bioenergy uses. Coal- and gas-fired power plants may be replaced by non-CCS technologies, so power CCS development is far less pressing.     

Consequences of a simulated rapid ocean acidification event for benthic ecosystem processes and functions

Whilst the biological consequences of long-term, gradual changes in acidity associated with the oceanic uptake of atmospheric carbon dioxide (CO₂) are increasingly studied, the potential effects of rapid acidification associated with a failure of sub-seabed carbon storage infrastructure have received less attention. This study investigates the effects of severe short-term (8 days) exposure to acidified seawater on infaunal mediation of ecosystem processes (bioirrigation and sediment particle redistribution) and functioning (nutrient concentrations). Following acidification, individuals of Amphiura filiformis exhibited emergent behaviour typical of a stress response, which resulted in altered bioturbation, but limited changes in nutrient cycling. Under acidified conditions, A. filiformis moved to shallower depths within the sediment and the variability in occupancy depth reduced considerably. This study indicated that rapid acidification events may not be lethal to benthic invertebrates, but may result in behavioural changes that could have longer-term implications for species survival, ecosystem structure and functioning.     

Study on the characteristics and causes of carbon tetrachloride pollution of karst water in eastern suburbs of Jinan

By comparing the testing data of the hydrochemistry components and organic pollution of karst water sample in Jinan with large amount of historical data, the author finds the long-existing problem of carbon tetrachloride pollution and the great change of hydrochemical characteristics of karst water in eastern suburbs of Jinan. Since karst water is the main water-supply source in eastern suburbs of Jinan, these problems have greatly affected the safety of water supply. Based on the analysis of hydrogeological condition in eastern suburbs of Jinan, this thesis discusses the causes of carbon tetrachloride pollution and hydrochemical variation with hydrogeochemical theories so as to protect the precious karst groundwater and Jinan spring water. It is found that through research and analysis that there are mainly two causes of carbon tetrachloride pollution and hydrochemical variation: the vulnerability of karst water in this area; the other being the serious pollution in this area caused by remaining pollution sources of the last century.     

Response to the Lomagundi-Jatuli Event in the southwestern margin of the Yangtze Plate: Evidence from the carbon and oxygen isotopes of the Paleoproterozoic Yongjingshao Formation

The Lomagundi-Jatuli Event (LJE) refers to the significant positive carbon isotope excursion in seawater constituents that occurred immediately after the increase in atmospheric oxygen content during the Paleoproterozoic (2.22–2.06 Ga). The δ¹³C values of 46 dolostone samples collected from the Paleoproterozoic Yongjingshao Formation varied in the range of 0.05 ‰–4.95 ‰ (V-PDB; maximum: 4.95‰) in this study, which may be related to the multicellular eukaryotes in the Liangshan Formation in the Yimen Group. They are much higher than the δ¹³C values of marine carbonates (?1.16‰ on average). The δ¹³C values of other formations in the Paleoproterozoic Yimen Group are negative. The notable positive carbon isotope anomalies of the Yongjingshao Formation indicate the response to the LJE at the southwestern margin of the Yangtze Block, which is reported for the first time. Furthermore, they are comparable to the δ¹³C values of carbonates in the Dashiling Formation of the Hutuo Group in the Wutaishan area in the North China Craton, the Wuzhiling Formation of the Songshan Group in the Xiong’ er area, Henan Province, and the Dashiqiao Formation of the Liaohe Group in the Guanmenshan area, Liaoning Province. Therefore, it can be further concluded that the LJE is a global event. This study reveals that LJE occurred in Central Yunnan at 2.15–2.10 Ga, lasting for about 50 Ma. The macro-columnar, bean-shaped, and microfilament fossils and reticular ultramicrofossils of multicellular eukaryotes in this period were discovered in the Liangshan Formation of the Yimen Group. They are the direct cause for the LJE and are also the oldest paleontological fossils ever found. The major events successively occurring in the early stage of the Earth include the Great Oxygenation Event (first occurrence), the global Superior-type banded iron formations (BIFs), the Huronian glaciation, the Great Oxygenation Event (second occurrence), the explosion of multicellular eukaryotes, the positive carbon isotope excursion, and the global anoxic and selenium-rich sedimentary event. The authors think that the North China Craton and the Yangtze Craton were possibly in different tectonic locations of the same continental block during the Proterozoic.©2023 China Geology Editorial Office.     

Brief review on climate change and tropical peatlands

In 2008, the very extensive tropical peats were estimated to be about 182 million ha spanning South America, Asia and Africa. About 20.3%(36.9 million ha) of this area exist in Asia. Peats are classified based on their degree of decomposition, namely Fibrists, Hemists, Saprists and Folists. This makes them different in characteristics. The activities of microorganisms vary in different types of peat due to, for example, the sapric layer of well humified peat can provide water and food to microorganisms during heat stress. In another scenario, deeper peat is older and typically has lower levels of labile carbon to provide substrate for microbes compared to surface peat. A complete understanding of the microbial communities in different layers of peat is essential as microorganisms play major roles in peat decomposition and are important to ecosystem processes. These peats are a very important global carbon(C)store or reserve and could severely impact climate change if not managed well. Peatlands can store as much as 40 to 90 Gt C. Mis-management of peats could severely impact the environment particularly the emission of carbon into the atmosphere. For instance, clearing of peatlands using fire has been reported to release an estimated 88 t C ha~(-1) to the atmosphere. There are several factors which influence the environmental consequences of tropical peat especially in relation to climate change. The main influences are:(i) changes in temperature,(ii) changes in precipitation or rainfall,(iii) changes in atmospheric composition, and(iv) fire and haze. This paper is a brief review on these four influences in relation to climate change. It is apparent from the brief review that there is a need for continued short and long-term research to better understand tropical peats and how they affect our climate. This will hopefully provide the basis for predicting better what could happen under various scenarios.     

Do drifts deposited adjacent to carbonate platforms record the signal of global carbon isotopic values?

This study investigates the δ¹³C values of Middle Miocene–Modern drift deposits and periplatform sediments in the Maldives and compares these data with the global δ¹³C values derived from bulk oceanic sediments and foraminifera. This comparison reveals that while the δ¹³C values of the early Miocene periplatform sediments in the Maldives appear to track the global record of δ¹³C values, including increases associated with the Oligocene–Miocene boundary as well as the variations within the Monterey Event, the correlation with the Monterey Event may be coincidental. It is suggested that variations in δ¹³C values do not reflect changes in oceanic dissolved inorganic carbon, but instead pulses of sediment arising from platform progradation that contribute carbonates with elevated δ¹³C values derived from the adjacent shallow‐water atolls. This conclusion is supported both by correlations between the seismic sequence architecture and the δ¹³C values which document progradation of ¹³C‐rich platform sediments, and also by the continuation of the interval of ¹³C‐rich sediments past the end of the Monterey Event at 13 Ma within the drift.     

Seasonality of bedrock weathering chemistry and CO2 consumption in a small watershed, the White River, Vermont

The draw down of CO₂ from the atmosphere during mineral weathering plays a major role in the global budget of this greenhouse gas. Silicate minerals remove twice the CO₂ of carbonate minerals per mole of calcium in runoff during weathering. Bedrock weathering chemistry was investigated in the White River watershed of northeastern USA to investigate whether there are seasonal differences in carbonate and silicate weathering chemistry. Geographic Information Systems analyses of bedrock geology were combined with major element concentrations in river waters to gain an understanding of the consistency of mineral weathering during three seasons. The percent of carbonate mineralogy comprising the bedrock in tributaries of the White River varied from less than 5% to 45% by area. A mass balance calculation using major element concentrations in waters was applied to estimate the seasonal relationships between bedrock geology and bicarbonate flux. In all tributaries and the main stem of the White River the highest calculated percent of bicarbonate from carbonate mineral weathering was measured in the late fall. The results suggest that carbonate and silicate bedrock weathering processes are seasonally controlled. Thus single season sampling could not accurately represent an entire year's geochemical budget. In the White River, water samples obtained solely during the summer would consistently underestimate the total yearly source of bicarbonate from carbonate bedrock weathering. The same sample set would also provide data that would lead to an underestimation of the yearly atmospheric CO₂ draw down by bedrock weathering in the watershed. For example at four of the seven locations studied there was an almost two-fold difference between summer and spring calculated atmospheric CO₂ consumption rates.     

Rethinking Net-Zero systems,spaces, and societies: “Hard” versus “soft” alternatives for nature-based and engineered carbon removal

Carbon removal – also known as negative emissions technologies, or greenhouse gas removal – represents a core pillar of post-Paris climate policy, signaling for enhancing and constructing carbon sinks to balance emissions sources on route to ambitious temperature targets. We build on Amory Lovins’ “hard” and “soft” alternatives for energy pathways to illuminate how foundational experts, technologists, and policy entrepreneurs think about different modes of resource inputs, infrastructure and livelihoods, and decision-making, regarding ten nature-based and engineered carbon removal approaches. Based on 90 original interviews, we show that hard and soft paths reflect different conceptions of systems, spaces, and societal involvement. We highlight that pathways depend on diverging concepts of economies-of-scale (capturing carbon at the largest possible scale, versus catalyzing systemic co-benefits) and carbon management (a waste product within conventional climate governance, versus diverse end-uses and values to be diversely governed). Our analysis further emphasizes two key uncertainties: whether renewables can be upscaled to allow synergies rather than tradeoffs between carbon removal and more widespread energy demands, and whether carbon certification can expand spatially to navigate long supply chains, and conceptually to incentivize diverse co-benefits. Experts remain motivated by antecedent concerns over land-use management and extractive industries, and that exploitative systems will – without guardrails – be replicated by inertia.     

Oxidative Ce3+ sequestration by fungal manganese oxides with an associated Mn(II) oxidase activity

Sequestration of Ce³⁺ by biogenic manganese oxides (BMOs) formed by a Mn(II)-oxidizing fungus, Acremonium strictum strain KR21-2, was examined at pH 6.0. In anaerobic Ce³⁺ solution, newly formed BMOs exhibited stoichiometric Ce³⁺ oxidation, where the molar ratio of Ce³⁺ sequestered (Ce_seq) relative to Mn²⁺ released (Mn_rel) was maintained at approximately two throughout the reaction. A similar Ce³⁺ sequestration trend was observed in anaerobic treatment of BMOs in which the associated Mn(II) oxidase was completely inactivated by heating at 85 °C for 1 h or by adding 50 mM NaN₃. Aerobic Ce³⁺ treatment of newly formed BMO (enzymatically active) resulted in excessive Ce³⁺ sequestration over Mn²⁺ release, yielding Ce_seq/Mn_rel > 200, whereas heated or poisoned BMOs released a significant amount of Mn²⁺ with lower Ce³⁺ sequestration efficiency. Consequently, self-regeneration by the Mn(II) oxidase in newly formed BMO effectively suppressed Mn²⁺ release and enhanced oxidative Ce³⁺ sequestration under aerobic conditions. Repeated treatments of heated or poisoned BMOs under aerobic conditions confirmed that oxidative Ce³⁺ sequestration continued even after most Mn oxide was released from the solid phase, indicating auto-catalytic Ce³⁺ oxidation at the solid phase produced through primary Ce³⁺ oxidation by BMO. From X-ray diffraction analysis, the resultant solid phases formed through Ce³⁺ oxidation by BMO under both aerobic and anaerobic conditions consisted of cerianite with crystal sizes of 5.00–7.23 Å. Such nano-sized CeO₂ (CeO_2,BMO) showed faster auto-catalytic Ce³⁺ oxidation than that on well-crystalized cerianite under aerobic conditions, where the normalized pseudo-first order rate constants for auto-catalytic Ce³⁺ oxidation on CeO_2,BMO was two orders of magnitude higher. Consequently, we concluded that Ce³⁺ contact with BMOs sequesters Ce³⁺ through two oxidation paths: primary Ce³⁺ oxidation by BMOs produces nano-sized crystalline cerianite, and subsequent auto-catalytic Ce³⁺ oxidation efficiently occurs using dissolved oxygen as the oxidizing agent. Pretreatment of newly formed BMOs with La³⁺ solution resulted in decreased rate constants for primary Ce³⁺ oxidation by BMO due to site blocking by La³⁺ sorption. The results presented herein increase our understanding of the role of BMO in oxidative Ce³⁺ sequestration process(es) through enzymatic and abiotic paths in natural environments and provide supporting evidence for the potential application of BMOs towards the recovery of Ce³⁺ from contaminated waters.     

Forest offsets and the California compliance market: Bringing an abstract ecosystem good to market

Improved Forest Management (IFM) projects under the California cap-and-trade market allow production of new, non-traditional commodities: forest carbon offsets. Earlier analyses have considered forest offsets generated through tree planting in the Global South, as vehicles for sustainable development. However, the California IFM program is testing offset production in new geographic and forest management contexts: with offsets produced and consumed within the US on working (timber producing) forests. With data drawn from California IFM project design documents and in-depth interviews with carbon project developers, this study traces the development, sale, and maintenance of forest offsets, in order to map access to benefits along the commodity chain. Results reveal that the cost and complexity of rendering biological services ‘real’ for market legitimacy are reducing benefits to marginal landowners, who lack needed capital, knowledge, and technology to bring offsets to market. An important insight of this study is that the state has maintained power over program participation and offset supply through control of the forest offset methodology, creating a production process largely mediated by the state, adding risk and uncertainty to market participation. Findings provide an empirical example of neoliberal nature and offer broader lessons on governance and benefit distribution for ecosystem service commodity chains.