Paradise (and Herrin) lost: Marginal depositional settings of the Herrin and Paradise coals, Western Kentucky coalfield

This is the fourth installment in a series of papers on the Asturian (Westphalian D) disrupted mire margins, termed the “ragged edge” in previous papers, and limestone distributions in the Herrin–Baker coal interval in the Western Kentucky extension of the Illinois Basin. New data, indicating in-situ peat development and marine influence, collected from the first in-mine exposure of this interval are presented. Borehole data from the region are examined in the context of “ragged edge” exposures and a carbonate platform depositional model for this portion of the Illinois Basin is presented. This shows that deposition of the sequence was influenced both by the underlying sediments and by a marine transgression. The former influence is seen in variations in coal and limestone thickness over sandstone-filled channels versus over shale bayfill deposits. The latter is marked by the progressive upwards loss of coal benches (i.e., the bottom bench of both coals is the most extensive and the Herrin coal is more extensive than the overlying Paradise coal) and by marine partings in both coals. Further, the brecciated margins seen in both coal seams are similar to brecciated peats encountered along the Everglades margins of Southwest Florida. Overall coal distributions are similar to both those along the Everglades margins and those along a transect from the Belize coast to Ambergis Caye.     

Shallow-burial dolomite cement: a major component of many ancient sucrosic dolomites

Dolomite cement is a significant and widespread component of Phanerozoic sucrosic dolomites. Cements in dolomites that were never deeply buried are limpid, have planar faces (non‐saddle forms), often distinct zonation in cathodoluminescence and form syntaxial overgrowths on crystals facing pores. Five samples of sucrosic dolomites, interpreted as having had mostly lime‐mudstone or wackestone precursors in four carbonate aquifers, provide insights into the abundance of planar cements in sucrosic dolomites. Such cement comprises 11% to 45% (32% mean) of peritidal to sub‐tidal dolomites on an outcrop in the Edwards aquifer (Early Cretaceous) of central Texas; 19% to 33% (25% mean) of ramp dolomites in the Hawthorn Group (Oligo‐Miocene) and 50% to 70% in shelf dolomites of the Avon Park Formation (Eocene) in the Upper Floridan aquifer of sub‐surface peninsular Florida; 18% to 45% (32+% mean) of sub‐tidal shelf dolomites in quarry sections of the Burlington‐Keokuk Formation (Early Mississippian) in south‐eastern Iowa; and 18% to 76% (50% mean) in shallow cores and outcrops of outer‐shelf dolomites from the Gambier Limestone (Oligo‐Miocene) of South Australia. Backstripping the cement phases revealed by cathodoluminescence colour photomicrographs documents the effects of cements on textural coarsening, pore‐space reduction, induration and general ‘maturation’ of these dolomites. Most pre‐Holocene dolomites are multiphase crystalline rocks composed of: (i) seed crystals or ‘cores’; (ii) crystal cortices that concentrically enlarged the cores; and (iii) free‐space, syntaxial precipitates of limpid cement around the crystals. Remaining CaCO₃ grains and micrite can be replaced by dolomite, but typically they are dissolved between stages (ii) and (iii), creating systems of intercrystal and mouldic pores typical of sucrosic dolomites. Networks of cement overgrowths, aided by water‐filled pore systems under hydrostatic to lithostatic pressure, are judged to slow or prevent compaction in sucrosic dolomites. It can be argued that cortex growth involves both replacement of CaCO₃ particles and microcementation of their interparticle pores. This interpretation, and the abundance of cements in so many dolomites, would obviate the controversy over the volumetrics of ‘replacement dolomitization’. Limpid, planar and syntaxial dolomite cements of early diagenetic origin are interpreted to have precipitated from clear pore waters, at low temperatures (<30 to 35 °C) and shallow burial depths (<100 m), in water‐saturated networks of dolomite ‘silt’ and ‘sand’. Cements in many dolomites in island and continental–aquifer systems appear to result from event‐driven processes related to sea‐level highstands. Cementation events can follow ‘replacement dolomitization’ events by time intervals ranging from geologically ‘instantaneous’ to tens of million years.     

The response of two Tethyan carbonate platforms to the early Toarcian (Jurassic) oceanic anoxic event: environmental change and differential subsidence

Chemostratigraphic analyses (⁸⁷Sr/⁸⁶Sr, δ¹³C_carb) of limestones from two Jurassic platform‐carbonate sequences in Italy (Trento and Campania–Lucania Platforms) illustrate previously established trends found in pelagic sediments and skeletal carbonates from biostratigraphically well‐calibrated sections elsewhere in Europe. Chemostratigraphic correlations between the platform‐carbonate successions and appropriate intervals from well‐dated reference sections allow the application of high‐resolution stratigraphy to these shallow‐water peritidal carbonates and, furthermore, elucidate the facies response to the Early Toarcian Oceanic Anoxic Event (OAE). Lower Jurassic (Toarcian) levels of the western Trento Platform (Southern Alps, Northern Italy) contain spiculitic cherts that appear where rising carbon‐isotope values characterize the onset of the OAE: a palaeoceanographic phenomenon interpreted as driven by increased nutrient levels in near‐surface waters. There is a facies change to more clay‐rich facies at the level of the abrupt negative carbon‐isotope excursion, also characteristic of the OAE, higher in the section. The Campania–Lucania Platform (Southern Apennines, Southern Italy) records a change to more clay‐rich facies where carbon‐isotope values begin to rise at the beginning of the OAE but the negative excursion, higher in the section, occurs within oolitic facies. Although, in both examples, the Early Toarcian OAE can be recognized by a change to more clay‐rich lithologies, this facies development is diachronous and in neither case did the platform drown. Although the Trento Platform, in the south‐west sector studied here, was adversely affected by the OAE, it did not drown definitively until Late Aalenian time; the Campania–Lucania Platform persisted throughout the Jurassic and Cretaceous. Differential subsidence rates, which can be calculated using comparative chemostratigraphy, are identified as a crucial factor in the divergent behaviour of these two carbonate platforms: relatively fast in the case of the Trento Platform; relatively slow in the case of the Campania–Lucania Platform. It is proposed that where water depths remained as shallow as a few metres during the OAE (Campania–Lucania Platform), dissolved oxygen levels remained high, nutrient levels relatively low and conditions for carbonate secretion and precipitation remained relatively favourable, whereas more poorly ventilated and/or more nutrient‐rich waters (Trento Platform) adversely influenced platform growth where depths were in the tens of metres range. The stage was thus set for drowning on the more rapidly subsiding western margin of the Trento Plateau and a pulse of oolite deposition post‐dating the OAE was insufficient to revitalize the carbonate factory.     

Platform-induced clay-mineral fractionation along a northern Tethyan basin-platform transect: implications for the interpretation of Early Cretaceous climate change (Late Hauterivian-Early Aptian)

High-resolution clay-mineral analyses were performed on upper Hauterivian to lower Aptian sediments along a platform-to-basin transect through the northern Tethyan margin from the Neuchâtel area (Switzerland), to the Vocontian Trough (France) in order to investigate links between climate change, carbonate platform evolution, and fractionation patterns in clay minerals during their transport.During the Hauterivian, the northern Tethyan carbonate platform developed in a heterozoan mode, and the associated ramp-like topography facilitated the export of detrital material into the adjacent basin, where clay-mineral assemblages are dominated by smectite and kaolinite is almost absent, thereby suggesting dry-seasonal conditions. During the Late Hauterivian Balearites balearis ammonite zone, a change to a more humid climate is documented by the appearance of kaolinite, which reaches up to 30% of the clay fraction in sediments in the Vocontian Trough. This prominent change just preceded the Faraoni Oceanic Anoxic Event and the onset of the demise of the Helvetic Carbonate Platform, which lasted to the late early Barremian.From the Late Barremian onwards, the renewed growth of the northern Tethyan carbonate platform in a photozoan mode and the associated development of a marginally confined platform topography fractionated the clay-mineral assemblages exported into hemipelagic settings: kaolinite particles were preferentially retained in proximal, platform settings, due to their size and their relatively high specific weight. In the inner platform environment preserved in the Swiss Jura, an average of 32% of kaolinite in the clay fraction is observed during the latest Barremian–earliest Aptian, whereas clay-mineral assemblages of coeval sediments from deeper depositional settings are dominated by smectite and show only minor amounts of kaolinite.This signifies that besides palaeoclimate conditions, the morphology and ecology of the carbonate platform had a significant effect on the distribution and composition of clay assemblages during the Late Hauterivian–Early Aptian along the northern Tethyan margin.     

Development of carbonate platforms on an extensional (rifted) margin: the Valanginian–Albian record of the Prebetic of Alicante (SE Spain)

Within the upper Valanginian to upper Albian deposits of the easternmost part of the Prebetic Zone of the Betic Cordillera (Iberian Peninsula), seven lithostratigraphic formations made up of shallow-water carbonate and carbonate-siliciclastic sediments and of outer-platform hemipelagic sediments have been recognized. These formations were deposited in the most distal part of a platform that developed on the Southern Iberian Continental Palaeomargin. The geodynamic context was a margin affected by extensional or transtensional faults that produced tilted blocks. The interval studied records three major second-order transgressive-regressive facies cycles: (I) A late Valanginian to earliest Aptian cycle, mostly represented by hemipelagic and condensed sedimentation, with the development of a tectonically controlled high without sedimentation that separated two sectors with different sedimentary evolution and that ended with an episode of shallow-water carbonate platform development; (II) An earliest to latest Aptian cycle, with a transgressive phase represented by a retrogradational shallow-water carbonate platform capped by a drowning event leading to hemipelagic sedimentation, which was affected by an anoxic event (OAE 1a); the regressive phase is represented by progradation and aggradation of shallow-water carbonate deposits. Finally (III) a latest Aptian to early-late Albian cycle that records the expansion of mixed platform deposits in the entire area, ending with a phase of shallow-water carbonate platform development. Extensional tectonics leading to spatial and temporal changes in subsidence patterns is envisaged as the main control on sedimentation at a local scale, resulting in notable lateral changes in thickness as the main signature. Tectonics exerted a strong control on the distribution of sedimentary environments only during Cycle I. At a higher order, sea-level fluctuations are responsible for sequential organization, and environmental factors determined shallow-water carbonate platform development and demise, as well as oceanic anoxic events. The relevant continuity of the stratigraphic record in the distal part of the Prebetic platform has led to the recognition of events related to cycle boundaries, which result mainly from a combination of tectonics and sea-level changes.     

The time-space distribution of Eocene to Miocene magmatism in the central Peruvian polymetallic province and its metallogenetic implications

Eocene to late Miocene magmatism in the central Peruvian high-plain (approx. between Cerro de Pasco and Huancayo; Lats. 10.2–12°S) and east of the Cordillera Occidental is represented by scattered shallow-level intrusions as well as subaerial domes and volcanic deposits. These igneous rocks are calc-alkalic and range from basalt to rhyolite in composition, and many of them are spatially, temporally and, by inference, genetically associated with varied styles of major polymetallic mineralization. Forty-four new ⁴⁰Ar–³⁹Ar and three U/Pb zircon dates are presented, many for previously undated intrusions. Our new time constraints together with data from the literature now cover most of the Cenozoic igneous rocks of this Andean segment and provide foundation for geodynamic and metallogenetic research.The oldest Cenozoic bodies are of Eocene age and include dacitic domes to the west of Cerro de Pasco with ages ranging from 38.5 to 33.5 Ma. South of the Domo de Yauli structural dome, Eocene igneous rocks occur some 15 km east of the Cordillera Occidental and include a 39.34 ± 0.28 Ma granodioritic intrusion and a 40.14 ± 0.61 Ma rhyolite sill, whereas several diorite stocks were emplaced between 36 and 33 Ma. Eocene mineralization is restricted to the Quicay high-sulfidation epithermal deposit some 10 km to the west of Cerro de Pasco.Igneous activity in the earliest Oligocene was concentrated up to 70 km east of the Cordillera Occidental and is represented by a number of granodioritic intrusions in the Milpo–Atacocha area. Relatively voluminous early Oligocene dacitic to andesitic volcanism gave rise to the Astabamba Formation to the southeast of Domo de Yauli. Some stocks at Milpo and Atacocha generated important Zn–Pb (–Ag) skarn mineralization. After about 29.3 Ma, magmatism ceased throughout the study region. Late Oligocene igneous activity was restricted to andesitic and dacitic volcanic deposits and intrusions around Uchucchacua (approx. 25 Ma) and felsic rocks west of Tarma (21–20 Ma). A relationship between the Oligocene intrusions and polymetallic mineralization at Uchucchacua is possible, but evidence remains inconclusive.Widespread magmatism resumed in the middle Miocene and includes large igneous complexes in the Cordillera Occidental to the south of Domo de Yauli, and smaller scattered intrusive centers to the north thereof. Ore deposits of modest size are widely associated with middle Miocene intrusions along the Cordillera Occidental, north of Domo de Yauli. However, small volcanic centers were also active up to 50 km east of the continental divide and include dacitic dikes and domes, spatially associated with major base and precious metal mineralization at Cerro de Pasco and Colquijirca. Basaltic volcanism (14.54 ± 0.49 Ma) is locally observed in the back-arc domain south of Domo de Yauli approximately 30 km east of the Cordillera Occidental.After about 10 Ma intrusive activity decreased throughout Central Perú and ceased between 6 and 5 Ma. Late Miocene magmatism was locally related to important mineralization including San Cristobal (Domo de Yauli), Huarón and Yauricocha.Overall, there is no evidence for a systematic eastward migration of the magmatic arc through time. The arc broadened in the late Eocene to early Oligocene, and thereafter ceased over wide areas until the early Miocene, when magmatism resumed in a narrow arc. A renewed widening and subsequent cessation of the arc occurred in the late middle and late Miocene. The pattern of magmatism probably reflects two cycles of flattening of the subduction in the Oligocene and late Miocene. Contrasting crustal architecture between areas south and north of Domo de Yauli probably account for the differences in the temporal and aerial distribution of magmatism in these areas.Ore deposits are most abundant between Domo de Yauli and Cerro de Pasco and were generally emplaced in the middle and late Miocene during the transition to flat subduction and prior to cessation of the arc. Eocene to early Oligocene mineralization also occurred, but was restricted to a broad east–west corridor from Uchucchacua to Milpo–Atacocha, indicating a major upper-plate metallogenetic control.     

Shrinking Sphere Kinetics for Batch Dissolution of Mixed Particles of a Single Substance at High Under-Saturation: Validation with Sodium Chloride, but with Biogenic Silica in Mind

The cubic equation recently derived for the increase in concentration of a solute with time, as the solid dissolves in batch according to the shrinking sphere model at high under-saturation, is extended to dissolutions of mixtures of differently sized particles. This problem needs to be solved if batch dissolutions are to play their part in the proposed amelioration of global warming and associated climate change by accelerated ‘re-burial’ of excess CO₂ in ocean sediment. The upgraded model was tested using sodium chloride dissolved in 50% aqueous propanone, whence the model fitted two separate runs with 500 and 212 μm, and 212 and 38 μm, diameter crystals, respectively. The key to simulating dissolution in this way lies in the dissolutions being independent of each other. It is further shown that although this condition was implicit in the recent derivation of the cubic equation, it was not recognised at the time. The work should be applicable to any batch dissolution of mixed particles at high under-saturation, and hence, may find use in many industrial and laboratory dissolutions. Simulations show how agglomerated mixtures can yield a straight line on the plot of ln(1 − C/C _T) versus time, as was reported to occur recently with sodium chloride taken ‘straight from the bottle’. It is shown that this probably explains why exponential dissolutions may have seemed appropriate to the dissolution of biogenic silica in earlier literature. This study suggests that a new round of biogenic silica dissolutions, but with sieved samples, would be worthwhile, with the likelihood that shrinking sphere behaviour might well be found to characterise the kinetics. The opportunity is taken to investigate a number of aspects of the shrinking sphere model not generally discussed before, e.g. the graph for the change in surface area with time. The limitations of using cubic salt crystals with the shrinking sphere model are discussed.     

Flowpath structure in a limestone aquifer: multi-borehole logging investigations at the hydrogeological experimental site of Poitiers, France

Since 2002, a new hydrogeological experimental site (HES) has been developed in Poitiers, France. The overall research objective related to this site is to improve the understanding of flow and solute transport in carbonate aquifers. The benchmarking of various types of numerical models against the HES field data is one of the main research projects supported by three national scientific programs. Within this framework, the purpose of this report is to synthesize existing knowledge about both aquifer geology and flowpath structure, based on core analysis and well logging. The combined use of core-hole data, borehole logs and outcrop data provide valuable information about lithostratigraphy and fracturing. The comparison of flow-meter data with borehole images indicates that flowpaths in the HES aquifer are strongly constrained within (1) subhorizontal karstic structures and (2) subvertical fractures. The presence of karstic levels appears to be conditioned by the stratigraphy and are unevenly developed in the HES. The vertical interconnectivity between the three karstic levels seems to result from fractures occurrence in this limestone formation. Following the observations, data and interpretations, a conceptual model of the Dogger aquifer is proposed.

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Résumé  La vocation première du Site Expérimental Hydrogéologique (SEH) de Poitiers, France, est de fournir des données pertinentes-y compris des chroniques ou expériences long terme-pour la caractérisation, la quantification et la modélisation des transferts d’eau et de solutés dans les aquifères carbonatés. Depuis 2002, les investigations menées sur le SEH ont permis de recueillir une importante quantité de données concernant un aquifère calcaire captif de 100 m d’épaisseur. Ces données servent actuellement de support à un exercice de modélisation comparée (benchmark) soutenu par trois programmes scientifiques nationaux. Dans le cadre de ce projet, l’objectif ici est de synthétiser les connaissances actuelles relatives à la géologie et la structure des écoulements dans l’aquifère du Dogger. La structure lithostratigraphique et la fracturation de l’aquifère sont analysées à partir des carottes de forages, des affleurements, et des diagraphies de puits. L’analyse croisée des données de débitmétrie verticale et des imageries de parois des forages indique que les écoulements sont principalement associés à des structures karstiques subhorizontales et des fractures subverticales. Les niveaux karstiques sont irrégulièrement répartis sur le SEH mais apparaissent fortement corrélés avec des niveaux stratigraphiques précis. La connectivité hydraulique des différents niveaux karstiques semble liée à la fracturation des calcaires.

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Resumen  Desde 2002, se desarrolló en Potiers, Francia, un sitio experimental hidrogeológico (SEH). El objetivo general de la investigación relacionada a este sitio es mejorar el entendimiento del flujo y transporte de solutos en acuíferos calcáreos. El punto de referencia de varios tipos de modelos numéricos utilizando los datos del SEH es uno de los principales proyectos de investigación financiados por tres programas científicos nacionales. Dentro de este marco, el propósito de este reporte es sintetizar el conocimiento existente tanto acerca de la geología como de la estructura de los caminos de flujo, basado en el análisis de testigos y perfiles de pozos. El uso combinado de testigos, perfiles de pozos e datos de afloramientos provee información valiosa acerca de la litoestratigrafía y el fracturamiento. La comparación de datos de medidores de flujo con imágenes de pozos indica que los caminos de flujo en el acuífero del SEH están fuertemente condicionados por (1) estructuras cársticas subhorizontales, y (2) fracturas subverticales. La presencia de niveles cársticos pareciera estar condicionada por la estratigrafía y estar desarrollada en forma no igualmente distribuida dentro del SHE. La interconectividad vertical entre tres niveles cársticos sería el resultado de la ocurrencia de fracturas en la formación de las calizas. En base a las observaciones, los datos e interpretaciones, se propone un modelo conceptual del acuífero Dogger.

     

Spectroscopic characterization of geological materials from the United Arab Emirates

Throughout the United Arab Emirates, the sand differs in color and composition, depending on its source. This study reports the collection of 70 sediment samples from coastal district areas of seven emirates in the United Arab Emirates, namely, Abu Dhabi, Dubai, Sharjah, Ajman, Umm Al Quwain, Ras Al-Khaimah, and Fujairah for the purposes of spectroscopic characterization and color justification. The compositions of these naturally occurring sand samples obtained were tested using different spectroscopic techniques. The techniques included both destructive instrumentation as scanning electron microscopy with energy dispersive X-ray analysis and X-ray powder diffraction and nondestructive instrumentation as confocal Raman microscopy. It was concluded that the sand can acquire various colors ranging from white to black due to the presence of certain chemical compounds.     

我国碳酸盐岩储层CO2地质储存潜力与适宜性

文章系统收集并分析了我国各盆地地层、大地构造、油田地质、水文地质数据,研究了我国各盆地碳酸盐岩地层空间分布和孔隙度特性,做出了《全国盆地碳酸盐岩分布面积分级图》、《全国盆地碳酸盐岩厚度分级图》、《全国盆地碳酸盐岩孔隙度分级图》、《全国盆地碳酸盐岩二氧化碳地质储存潜力分级图》。逐一对全国各沉积盆地内800～5 000 m深度区间各地质时代形成的碳酸盐岩储层的CO2储存能力进行了计算。通过层次分析法确定各评价指标权重,制做出全国盆地E级碳酸盐岩储层CO2地质储存适宜性评价结果表,绘制出《全国盆地碳酸盐岩储层CO2储存适应性评价图》。对全国盆地CO2储存进行了适宜性评价,剔除了不适宜CO2地质储存的沉积盆地,选出适宜的沉积盆地以供下一阶段继续研究。