TiO2光催化降解微污染水中腐殖酸的研究

为探讨TiO2光催化法处理微污染水中腐殖酸的规律,利用悬浮状的TiO2颗粒在紫外光的照射下催化降解含有腐殖酸污染物的水样,设计正交试验研究pH值、TiO2的投加量、腐殖酸溶液初始浓度、曝气量和温度等对腐殖酸降解效果的影响及规律。结果表明:pH=3.5时,TiO2的投加量为1.0 g/L、曝气量为0.12 m3/h、温度为18℃时,最佳有机物降解效果为96.83%;TiO2光催化法对微污染水中的腐殖酸能够有效降解。     

华东稻麦轮作农田CH4、N2O和NO排放特征

利用同步自动观测系统对华东稻麦轮作农田的CH4、N2O和NO排放进行了长期连续观测,分析了这3种气体排放的季节特征及决定因素,结果表明,华东稻麦轮作农田的CH4、N2O和NO排放具有完全不同的季节变化形式。CH4的排放发生在水稻生长期,其他阶段排放不明显,土壤水分状况是决定整个轮作周期内CH4排放变化的主要因素。N2O排放具有"冬季无,水田少,旱地多"的季节变化特点,尤其以旱地阶段的排放为主,土壤水分状况和温度共同决定着N2O排放的季节变化形式。NO排放具有"冬季无,水田很少,春季旱地多于秋季旱地"的季节分布特点,轮作周期内97.3%±0.6%的NO排放都发生在除冬季以外的旱地阶段,NO排放的季节变化形式由土壤水分状况和温度共同决定。大多数情况下稻田CH4和N2O排放呈互为消长的关系,但在烤田期间,二者却有时甚至同时出现高排放。在N2O日平均排放通量小于5 mg.m-2.h-1时,稻麦轮作农田的N2O和NO排放呈明显的互为消长关系,但大于5 mg.m-2.h-1时,N2O排放很强,同时NO排放也很强。     

翁田台地电场观测受干扰的因素分析

海南省文昌翁田台地电场数据质量自2019年3月开始下降,地电场数据质量下降主要表现为日相关系数偏低、北南向长极距与短极距数据曲线呈反向变化、绝缘度趋向于零等情况.2019年3月—2020年10月,我们分别对观测室装置系统、室外外线路、连接口等逐一进行详细的排查工作和电极、电缆的对比实验工作,最终确定影响因素为电极故障和...     

Short-period Jupiter family comets after Stardust

The NASA Stardust mission has provided for laboratory study an extensive data set of cometary dust of known provenance (from comet 81P/Wild 2) yielding detailed insights into the composition of the comet. Combined with the results of data from other missions to short-period Jupiter family comets (JFC), this has greatly deepened the understanding of such objects. If depressions on the surface of comet 81P/Wild 2 are all taken as evidence of impact cratering, their number suggests a long occupancy in the outer region of the Solar System. The dust from comet 81P/Wild 2 has been shown to be heavily deficient in pre-Solar grains and rich in materials formed at high temperatures in the inner Solar System. Although it is too early to know if this is typical of JFC, it does argue for rapid and thorough mixing of materials in the disk on timescales related to comet formation, and may also suggest outward migration of small icy bodies after their formation. Thus, instead of providing mainly new knowledge of the pre-Solar materials expected to be rich in comets, Stardust and comet 81P/Wild 2 have instead focussed attention on large-scale transport processes during the critical period when cometary parent bodies were forming in the early Solar System.     

X-ray spectral evolution of the extragalactic Z source LMC X-2

We present the results obtained by a detailed study of the extragalactic Z source LMC X-2, using broad-band Suzaku data and a large (∼750 ks) data set obtained with the proportional counter array (PCA) onboard the Rossi X-ray Timing Experiment ( RXTE ). The PCA data allow the study of the complete spectral evolution along the horizontal, normal and flaring branches of the Z track. Comparison with previous studies shows that the details of spectral evolution (like the variation of Comptonizing electron temperature) are similar to those of GX 17+2 but unlike those of Cyg X-2 and GX 349+2. This suggests that Z sources are a heterogeneous group, with perhaps LMC X-2 and GX 17+2 being members of a subclass. However, non-monotonic evolution of the Compton y parameter seems to be generic to all sources. The broad-band Suzaku data reveal that the case in which the additional soft component of the source is modelled as disc blackbody emission is strongly preferred over the one where it is taken to be a blackbody spectrum. This component, as well as the temperature of seed photons, does not vary when the source goes into flaring mode, and the entire variation can be ascribed to the Comptonizing cloud. The bolometric unabsorbed luminosity of the source is constrained to be  ∼2.23 × 10³⁸ erg s⁻¹  , which, if the source is Eddington-limited, implies a neutron star mass of  1.6 M_⊙  . We discuss the implications of these results.     

Decompression and H<Subscript>2</Subscript>O exsolution driven crystallization and fractionation: development of a new model for low-pressure fractional crystallization in calc-alkaline magmatic systems

Magma ascent, decompression-induced H₂O exsolution and crystallization is now recognized as an important process in hydrous subduction zone magmas. During the course of such a process calculations suggest that the ascent rate of a degassing and crystallizing mafic magma will be greater than crystal settling velocities. Thus, any crystals formed as a consequence of volatile exsolution will remain suspended in the magma. If the magma erupts before the percentage of suspended crystals reaches the critical crystallinity value for mafic magma (~55 vol.%) it will produce the commonly observed crystal rich island arc basalt lava. If the magma reaches its critical crystallinity before it erupts then it will stall within the crust. Extension of compaction experiments on a 55 vol.% sand-Karo syrup suspension at different temperatures (and liquid viscosities) to the likely viscosities of interstitial andesitic to dacitic liquid within such a stalled magma suggest that small amounts (up to ~10%) can be expelled on a time scale of 1–10 years. The expelled liquid can create a new intermediate to silicic body of magma that is related to the original mafic magma via fractional crystallization. The short time scale for liquid expulsion indicate that decompression-induced H₂O exsolution and crystallization can be an important mechanism for fractional crystallization. Based on this assumption a general model of decompression-induced crystallization and fractionation is proposed that explains many of the compositional, mineralogical and textural features of Aleutian (and other andesites).     

On the swelling potential of compacted high plasticity clays

We conducted a study of the spatial distributions of seismicity and earthquake hazard parameters for Turkey and the adjacent areas, applying the maximum likelihood method. The procedure allows for the use of either historical or instrumental data, or even a combination of the two. By using this method, we can estimate the earthquake hazard parameters, which include the maximum regional magnitude Mˆ_max, the activity rate of seismic events and the well-known bˆ value, which is the slope of the frequency-magnitude Gutenberg-Richter relationship. These three parameters are determined simultaneously using an iterative scheme. The uncertainty in the determination of the magnitudes was also taken into consideration. The return periods (RP) of earthquakes with a magnitude M ≥ m are also evaluated. The whole examined area is divided into 24 seismic regions based on their seismotectonic regime. The homogeneity of the magnitudes is an essential factor in such studies. In order to achieve homogeneity of the magnitudes, formulas that convert any magnitude to an M_S-surface scale are developed. New completeness cutoffs and their corresponding time intervals are also assessed for each of the 24 seismic regions. Each of the obtained parameters is distributed into its respective seismic region, allowing for an analysis of the localized seismicity parameters and a representation of their regional variation on a map. The earthquake hazard level is also calculated as a function of the form Θ = (Mˆ_max,RP_6.0), and a relative hazard scale (defined as the index K) is defined for each seismic region. The investigated regions are then classified into five groups using these parameters. This classification is useful for theoretical and practical reasons and provides a picture of quantitative seismicity. An attempt is then made to relate these values to the local tectonics.     

鄂尔多斯盆地长9油层组石油运聚规律研究

鄂尔多斯盆地长9油层组是一个新发现的含油层。迄今为止,有关长9油层组石油运聚成藏机理尚不清楚,特别是对石油运聚规律缺乏认识。该问题的解决会进一步完善鄂尔多斯盆地中生界延长组石油成藏理论;同时,对长9油层组石油勘探开发具有重要的指导作用。我们对长9油层组石油来源、油气输导体系、油气运移路径和油气运移动力等油气运聚条件特征及其不同地区差异进行了研究,结果表明,长9油层组原油主要来自长7烃源岩,只有在志丹局部地区来自长7和长9烃源岩;长9油层组石油的纵向运移路径是由上向下运移;孔隙型输导体和断层、构造裂隙输导体是长9油层组石油运移的主要输导体;盆地长7油层组普遍存在高过剩压力带,长7与长9油层组之间存在较大的流体压力差,因此长7油层组生成的油气在高过剩压力驱动下可以向下运移,进入储层物性相对好的长9砂体聚集成藏。同时,建立了3种长9油层组油气运聚模式,讨论了长9油层组油气运聚机理     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).