高效液相色谱-紫外光谱分析氢醌-双(β-羟乙基)醚

建立了高效液相色谱-紫外光谱法测定聚氨酯扩链剂氢醌-双(β-羟乙基)醚(HQEE)工业品中HQEE主含量和对苯二酚残留的方法。在氰基柱上,以甲醇-水-1%乙酸溶液(体积比10∶50∶40)为流动相,流速1.0 mL/min时,HQEE、对苯二酚及其他相关杂质得到良好分离,紫外光谱285 nm检测。方法简便、快捷,结果准确可靠,在工业生产中可有效地指导HQEE合成过程的质量控制。     

基于分类回归树分析的遥感影像土地利用／覆被分类研究

以专家知识和经验为基础,综合影像光谱信息和其他辅助信息进行分类的基于知识的遥感影像解译方法,是提高遥感影像分类精度,实现自动解译的有效途径之一。然而,知识的获取一直是其得以广泛应用的“瓶颈”问题。以江苏省江宁试验区土地利用/覆被分类为例,利用分类回归树分析(CART)从训练样本数据集中发现分类规则,集成遥感影像的光谱特征、纹理特征和空间分布特征进行分类实验,并与传统的监督分类和逻辑通道分类方法进行比较。结果表明,基于CART的分类方法的精度基本在80%以上,与另两种方法相比,有了较大的提高,而且该算法复杂性低,效率高。由此说明,利用CART算法构建决策树获取的分类规则是合理的。它可以快速、有效地获取大量分类规则,是促进基于知识的遥感影像分类方法在土地利用/覆被分类中广泛应用的一项有效手段。     

Spectra and vegetation index variations in moss soil crust in different seasons,and in wet and dry conditions

Similar to vascular plants, non-vascular plant mosses have different periods of seasonal growth. There has been little research on the spectral variations of moss soil crust (MSC) over different growth periods. Few studies have paid attention to the difference in spectral characteristics between wet MSC that is photosynthesizing and dry MSC in suspended metabolism. The dissimilarity of MSC spectra in wet and dry conditions during different seasons needs further investigation. In this study, the spectral reflectance of wet MSC, dry MSC and the dominant vascular plant (Artemisia) were characterized in situ during the summer (July) and autumn (September). The variations in the normalized difference vegetation index (NDVI), biological soil crust index (BSCI) and CI (crust index) in different seasons and under different soil moisture conditions were also analyzed. It was found that (1) the spectral characteristics of both wet and dry MSCs varied seasonally; (2) the spectral features of wet MSC appear similar to those of the vascular plant, Artemisia, whether in summer or autumn; (3) both in summer and in autumn, much higher NDVI values were acquired for wet than for dry MSC (0.6 ∼ 0.7 vs. 0.3 ∼ 0.4 units), which may lead to misinterpretation of vegetation dynamics in the presence of MSC and with the variations in rainfall occurring in arid and semi-arid zones; and (4) the BSCI and CI values of wet MSC were close to that of Artemisia in both summer and autumn, indicating that BSCI and CI could barely differentiate between the wet MSC and Artemisia.     

Synchrotron emission model of RX J1856.5-3754

A plasma emission model is presented interpreting the observational properties of RX J1856.5-3754. In particular, on the basis of the Vlasov’s kinetic equation we study the process of the quasi-linear diffusion (QLD) developed by means of the cyclotron instability. This mechanism provides simultaneous generation of optical and X-ray emission on the light cylinder scales, in one location of the pulsar magnetosphere. It is assumed that the observed X-ray spectrum of this source is generated via the synchrotron mechanism. A different approach of the synchrotron theory is considered, giving a spectral energy distribution that is in a good agreement with the observational data.     

Photometric observations and orbital period variations of HS 0705 + 6700 and NY Vir

We present photometric observations of two post-common-envelope stars, NY Vir (=PG 1336-018) and HS 0705 + 6700. The V band CCD observation of NY Vir was performed by a 40 cm telescope at Ege University Observatory and the R band observations of HS 0705 + 6700 were performed by 100 cm telescope at TÜB?TAK National Observatory. The new light curves were analyzed by the WD code and the physical parameters of stars were determined. We obtained new mid-eclipse timings for HS 0705 + 6700 and combined them with those previously published data. The analysis of the O-C residuals yields a period of about 8.06 ± 0.28 yr and an amplitude of 98.5 s for the system HS 0705 + 6700, which is attributed to the third star physically bounded to the evolved eclipsing pair. A mass function of 1.2 × 10⁻⁴ M_⊙ for the third star is obtained. The existence of a third star is also confirmed by the light curve analysis, indicating light contribution of about 0.043 at phase 0.25 in R-bandpass of the eclipsing pair. Using mass-luminosity relationship of the low mass stars we estimate a mass of 0.12 M_⊙ with an orbital inclination of about 20°. The O-C residuals obtained for the system NY Vir were represented by a downward parabola which indicates orbital period decrease in the system. Using the coefficient of quadratic term we calculate a rate of orbital period decrease of about dP/dt = −4.09 × 10⁻⁸days yr⁻¹. The period decrease we have measured in NY Vir may be explained by angular momentum loss from the binary system.     

基于FPGA的便携式BPC定时接收机设计

介绍了一种基于FPGA的便携式低频时码接收机系统的设计方案。该接收机的特点是体积小,功耗低,方便户外工作人员携带。描述了该接收机的硬件系统结构,给出了软件算法。硬件结构中,使用了ALTERA公司的EP2C70F672C8芯片,软件部分在QuartusⅡ开发环境下完成。系统测试结果表明,按本方案设计的接收机集成度高,可靠性好,易扩展,易升级,具有一定的实用价值。     

Soil erosion and sediment transport in Tanzania: Part I – sediment source tracing in three neighbouring river catchments

Water bodies in Tanzania are experiencing increased siltation, which is threatening water quality, ecosystem health, and livelihood security in the region. This phenomenon is caused by increasing rates of upstream soil erosion and downstream sediment transport. However, a lack of knowledge on the contributions from different catchment zones, land-use types, and dominant erosion processes, to the transported sediment is undermining the mitigation of soil degradation at the source of the problem. In this context, complementary sediment source tracing techniques were applied in three Tanzanian river systems to further the understanding of the complex dynamics of soil erosion and sediment transport in the region. Analysis of the geochemical and biochemical fingerprints revealed a highly complex and variable soil system that could be grouped in distinct classes. These soil classes were unmixed against riverine sediment fingerprints using the Bayesian MixSIAR model, yielding proportionate source contributions for each catchment. This sediment source tracing indicated that hillslope erosion on the open rangelands and maize croplands in the mid-zone contributed over 75% of the transported sediment load in all three river systems during the sampling time-period. By integrating geochemical and biochemical fingerprints in sediment source tracing techniques, this study demonstrated links between land use, soil erosion and downstream sediment transport in Tanzania. This evidence can guide land managers in designing targeted interventions that safeguard both soil health and water quality.     

Splash detachment of sand particles under varying contact stress field of wind-driven raindrop impact

The effects of wind-driven rain (WDR) on sand detachment were studied under various raindrop obliquities. Results suggested a significant reduction in compressive stress on sand surfaces for a two-dimensional experimental set-up in a wind tunnel. During experiments, sand particles in splash cups were exposed to both wind-free rain (WFR) and WDR driven by horizontal winds of 6.4, 8.9 and 12.8 m s⁻¹ and rainfall intensities of 50, 60, 75 and 90-mm h⁻¹ to assess the sand detachment rate (D, in g m⁻² s⁻¹). The effects of sand moisture state (dry and wet) on the detachment of different-sized particles (0.20–0.50 and 0.50–2.00 mm, respectively) were also tested. Factorial analysis of variance showed that shear and compressive stress components evaluated by horizontal and vertical kinetic energy flux terms (KE_x and KE_y, respectively, in J m⁻² s⁻¹) along with their vector sum (KE_r, in J m⁻² s⁻¹) explained the variation in D. Neither sand size nor sand moisture was statistically significant alone although binary interactions of KE_r, KE_x and KE_y with the sand size and three-way interaction of KE_x, sand size and moisture were statistically significant. These results can be explained by size-dependent variation in sand compressibility and surface friction related to the total stress field developed by a given partition of shear and compressive stresses of wind-driven oblique raindrops (KE_x/KE_y). Further analysis of the variation of the unit sand detachment rate (D_u = D/KE_r = g J⁻¹) with rain inclination (α, in degrees) better revealed the effect of WDR obliquity on D_u that further changed with sand size class and moisture state. Finally, the difference in the resulting stress field differentiable by the oblique raindrop trajectories of the experiment over sand surface significantly affected the non-cohesive particle detachment rates, to some extent interacted with size-dependent compressibility and interface shear strength of sand grains.     

四川理县蒲溪乡边坡变形监测及降雨影响分析

四川省阿坝州理县蒲溪乡河坝村后山边坡属于老滑坡区,2014年6月以来,出现地表拉裂、鼓胀、下挫及挡墙剪切错断等现象,并不断加剧恶化,严重威胁当地民众安全。为预防滑坡灾害,当地政府在边坡前修建防护坝。为评估该防护工程效果,获取6个新建GNSS观测点实时变形观测数据,运用灰色关联法,明确降水变率是造成该区形变的主要因素,进而采用边坡变形量行业常用GM(1, 1)模型,预测可能的边坡形变量,并与GNSS观测点实测值对比,结果表明,在防护坝建成1年7个月后,边坡变形速率逐渐减缓,防护工程治理效果显现。     

固定铝log(Q/K)图解在温泉中的应用

为探讨常规和固定铝log(Q/K)图解法对温泉系统是否有效 ,采用WATCH程序 ,对江西 3个温度较高的温泉 ,即庐山温泉、汤湖温泉和横泾温泉 ,进行了探测性的研究 .采用常规log(Q/K)图解法计算时 ,由于参加计算的 4个水样的铝含量均未检出 ,计算结果显示只有不含铝的矿物玉髓和方解石相交于温度 1 0 0℃附近 ,热储总体上没有达到平衡 .在采用了固定铝log(Q/K)图解法并同时考虑冷水的稀释作用计算后 ,中低温地热系统中常见的蚀变矿物如浊沸石、纤蛇纹石、萤石和玉髓均显示了较好的收敛性 ,收敛的温度大致在 1 0 0～ 1 4 0℃ .并且上述矿物组合可见于某些温泉的深部钻孔中 ,计算结果与实际地质情况相吻合 .结果表明固定铝log(Q/K)图解法可以恢复温泉系统的热平衡状态