Ra or Ra/Ba dating of Holocene volcanic rocks: application to Mt. Etna and Merapi volcanoes

This paper shows how ²²⁶Ra–²³⁰Th disequilibria can be used to date Holocene volcanic rocks from some well selected volcanoes. A systematic study of these disequilibria on historical or well-dated volcanic samples is indeed first required to test the applicability of this method. Two examples are described here to illustrate its potential. In the case of Mt. Etna, the good correlation observed between (²²⁶Ra)₀ activities at the time of eruption and Th contents in lava flows from the last two millennia [M. Condomines, J.C. Tanguy, V. Michaud, Magma dynamics at Mt. Etna: constraints from U–Th–Ra–Pb radioactive disequilibria and Sr isotopes in historical lavas, Earth Planet. Sci. Lett. 132 (1995) 25–41] is used to infer the ages of several newly analysed lava flows. The calculated ages are in good agreement with those deduced from the archaeomagnetic curve describing the variation of the geomagnetic field direction in southern Italy [J.C. Tanguy, I. Bucur, J.F.C. Thompson, Geomagnetic secular variation in Sicily and revised ages of historic lavas from Mt. Etna, Nature 318 (1985) 453–455, J.C. Tanguy, M. Le Goff, V. Chillemi, A. Paiotti, C. Principe, S. La Delfa, G. Patane, Variation séculaire de la direction du champ géomagnétique enregistrée par les laves de l'Etna et du Vésuve pendant les deux derniers millénaires, C. R. Acad. Sci. Paris 329 (1999) 557–564, J.C. Tanguy, M. Le Goff, C. Principe, S. Arrighi, V. Chillemi, A. Paiotti, S. La Delfa, G. Patane, Archaeomagnetic dating of Mediterranean volcanics of the last 2100 years: validity and limits. Earth Planet. Sci. Lett. 211 (2003) 111–124]. We also present a whole set of new U-series data on historical, recent, and older samples from Merapi (Indonesia), and show that the (²²⁶Ra)/Ba ratio has probably maintained a quasi-steady state value during at least the past four millennia, and can be used to infer the (²²⁶Ra)₀/Ba ratio of old volcanics at the time of eruption, and thus their ages. Comparison with ¹⁴C ages available on three samples [R. Gertisser, J. Keller, Temporal variations in magma composition at Merapi volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity, J. Volcanol. Geotherm. Res. 123 (2003) 1–23] shows an excellent agreement. These dating methods, based on the post-eruptive decrease of ²²⁶Ra excesses can be confidently used to date young rocks on both volcanoes, an important step to infer their recent eruptive history and magmatic evolution. It also opens the possibility to extend the geomagnetic field variation curve back into the past few millennia. The promising results obtained in this work should encourage new systematic U-series studies to test the applicability of such methods to other permanently active volcanoes showing ²²⁶Ra excesses.     

油气田上方某些化探新指标与油气埋深的关系之研究（二）

试验研究了油气田上方壤中某些气元素，Ba及铁，铜等元素与油气藏的关系，结果显示这些元素对油气藏有明显的指示作用，可作为指标油气藏的存在及埋深的新指标。     

黄土高原南部全新世黄土-古土壤 序列若干元素分布特征及意义*

选择黄土高原南部的XJN,XMC和JYC全新世剖面为研究对象。通过对地层中Ca,Ba,Rb和Sr元素分布的研究,发现Ba/Sr和Rb/Sr比值在不同地层中含量差异十分明显,并与成土作用强度显著正相关,可作为良好的气候替代指标;表生环境中Rb和Ba较稳定,Sr和Ca元素十分活跃,易于迁移,其中Ca的迁移能力高于Sr元素;从XJN→XMC→JYC剖面,Rb和Ba元素含量增加,而Sr和Ca元素含量降低,这与区域环境差异有关;全新世中期暖湿的亚热带气候主要出现关中盆地地区,六盘山以西则是暖温带气候。     

灵台风尘堆积中钙质结核的地球化学研究

通过对甘肃灵台风成黄土－古土壤－红粘土序列中钙质结核的野外分布及形态特征观察,并对主元素和微量元素进行化学分析,发现结核中氧化物活动给分和惰性组分含量的比值在剖面中自下而上逐渐变大,反映了结核形成时其上覆土层所经历的淋溶程度逐渐增强;而ＭｇＯ含量校正后的ＭｇＯ／Ｃａｏ比值则逐渐减小,批示结核形成时环境温度逐渐降低。灵台剖面自下而上不同层位结核中Ｓｒ／Ｂａ比值及ＣａＣＯ３含量的变化同氧化物含量及比值     

Evolution of Çamlık fissure-ridge travertines in the Başkale basin (Van,Eastern Anatolia)

Fissure-ridge travertines (FRTs) are of great importance for the determination and comparison of tectonic deformation in a region. The coeval development of these travertines with active fault zones supplies significant information about regional dynamics in terms of deformation pattern and evolution. In this paper, the characteristics of FRTs of the Ba?kale basin (eastern Turkey) and responsible regional tectonism are discussed for the first time. The Ba?kale basin is located between the Ba?kale Fault Zone (BFZ) characterised by Çaml?k fault and I??kl?–Zirani? fault. It is located between dextral Yüksekova Fault Zone and southern end of dextral Guilato–Siahcheshmeh–Khoy Fault system (Iran). Various morphological features indicating recent activity are exposed along the BFZ, including offsetting rivers, fissure-ridge travertine and fault scarps. The Çaml?k fissure-ridge travertine composing of three different depositions is observed along the eastern edge of the BFZ with approximately parallel orientations. The Çaml?k fissure-ridge travertine has been formed and developed on fault zone related to strike-slip or oblique movements. We explain how kinematic changes of faults can influence the fissure-ridge development.     

胶州湾北部水域 叶绿素-a含量和初级生产力

据1995年3月至11月胶州湾北部水域内调查资料 ,分析叶绿素-a含量和初级生产力的分布,月变化和日变化以及同环境因子的关系。叶绿 素-a含量的月变幅为1．194～10．715mg/m3,平均值为3.386mg/m3。初级生产力月变 幅为68.85～1417.41mg.C/m2.d,平均值为353.01mg.C/m2.d。叶绿素-a含量和初 级生产力均以8月>9月gt;5月gt;3月gt;11月。     

Approaches to equilibrium in the distribution of trace elements among the principal minerals in a high-grade metamorphic terrane

X-ray fluorescence, instrumental neutron activation, and particle-induced X-ray emission methods were used to determine the distribution of numerous trace elements among garnet (Grt), Ca-pyroxene (Cpx), hornblende (Hbl), biotite (Bt), plagioclase (Pl) and K-feldspar (Kf) in a high-grade metamorphic terrane within the Grenville Province of the Canadian Shield. Results are presented as distribution formulae, e.g. Sr: Kf 1.1 Pl 16 Hbl 2.2 Cpx 1.0 Bt 1.2 Grt Sc: Hbl 1.1 Cpx 1.0 Grt 7.8 Bt 22 Pl 2.6 Kf V: Hbl 1.15 Bt 2.07 Cpx 6.0 Grt (1.4% CaO)>1 (Pl, Kf) Zn: Bt 1.6 Hbl 1.62 Cpx 2.9 Grt 10 Pl Ga: Bt 1.2 Hbl 1.2 Pl 2.5 Cpx 1.3 Grt where numbers are distribution ratios, e.g. ppm Sr in Hbl/ppm Sr in Cpx=2.2. Examples of inter-element similarities and differences are (a) both Rb and Cs are concentrated in biotite relative to K-feldspar, but for Rb the ratio is 2.3 and for Cs it is 16, (b) the distribution formulae for seven lanthanides are similar except for the position of garnet, e.g. Ce: Hbl 2.7 Cpx 2.8 Pl 1.1 Bt 11 Kf 16 Grt Yb: Grt 2.8 Hbl 2.7 Cpx 9 Pl 1.0 Bt 7 Kf and (c) all of Sr, eight lanthanides, Zr, V and Cr are concentrated in hornblende relative to Ca-pyroxene by a factor that lies in the narrow range of 2.2–3.1. There is a larger variation (departure from the mean) in some distribution ratios than in others. Thus the mean ratios (Hbl/Cpx) for each of six elements and in parentheses the percentage relative standard deviation are Zn 1.62 (8.6), V 2.38 (12), Cr 2.42 (18), Sr 2.7 (28), Ba 2.9 (36) and Ni 1.66 (38). We suggest that variation of this kind is the result of differences from place to place in the magnitude of deformation and recrystallization (which facilitated the rearrangement of atoms), combined with rates of lattice and crystal-boundary diffusion that are unique for the various elements, thus permitting some trace elements to approach equilibrium more closely than others.     

青海大通断裂带初步研究

青海大通断裂带是青藏高原北部压性盆地带内的一条NE向断裂,构成西宁盆地与大通城关盆地的边界。该断裂带主要由麻子营-庙沟断裂(F1)和老爷山-南门峡断裂(F2)2条次级断裂段构成,沿该断裂带有明显垂直断错的地貌现象。野外调查表明,断裂具有长期活动特征,基岩中发育10余米宽的断层破碎带,且沿断裂带一些地段有岩脉侵入。断裂最新活动表现为寒武纪地层逆冲到早第四纪砖红色砾石层之上,沿断层面发育数厘米厚的断层泥。但断层带上覆坡积黄土未被断错。断层泥测年(ESR)结果为(610±61)kaBP;上覆黄土测年(OSL)结果为(14.6±1.5)kaBP。根据测年结果和地质地貌现象判定该断裂带在中更新世有过明显活动。大通盆地内部地层以长轴NW向的褶皱变形为主,根据断层与褶皱变形的关系认为,在NEE向区域挤压应力作用下NE向的大通断裂是断层两侧褶皱带之间不同段落压缩不均匀而形成的横向撕裂。这一特征可能代表了青藏高原东北部一系列NE向断裂的共同特征。这些NE向断裂规模不大,被围限在活动块体内部,与褶皱和压性盆地轴向近垂直     

Trace Determination of Strontium and Barium in River Waters by Inductively Coupled Plasma-Atomic Emission Spectrometry Using an Ultrasonic Nebulizer

Inductively coupled plasma-atomic emission spectrometry in conjunction with an ultrasonic nebulizer was employed for the determination of Sr and Ba in river waters at parts per billion (μg l⁻¹) levels without pre-concentration. The ultrasonic nebulizer, equipped with a desolvation system, enhanced the analytical sensitivity by ten to twenty fold compared to conventional pneumatic nebulizers. The detection limits for Sr and Ba, ascertained from blanks and reference samples made in 0.05% NaCl solution, were 0.045 μg l⁻¹ and 0.16 μg l⁻¹ respectively. The accuracy of measurements, based on analyses of solutions of reference materials (G-2 and W-1) and multielement commercial standards (Merck®), was ± 10%. Replicate analyses of samples and reference samples showed measurement precision to be to be better than ± 5%, which is adequate considering that the concentration of Sr and Ba in river waters varies by one to two orders of magnitude.     

柴达木盆地西部新生代的构造-热演化研究

利用磷灰石裂变径迹(AFTA)参数和镜质体反射率动力学模型对柴达木盆地西部地区的构造-热演化进行系统分析,通过对10个构造部位16口井的单井热历史模拟分析了该区新生代的热演化状况.研究表明柴达木盆地西部地区的地温梯度在第三纪以来随着盆地的演化逐渐减小,但在第四纪以来变化不大或有增加的趋势;热流的变化与地温梯度的变化不同,随地史的演化逐渐增加.该区热流的这种变化与构造演化密切相关,盆地第三纪末(N32)以后发生的新构造运动(有人称喜马拉雅运动第三幕)是造成现今地温分布状况的根本原因.本研究得到的地温数据可为盆地新一轮的资源评价提供基础数据和理论依据.