全新世黄土剖面Li/Ba值变化及其古气候意义

对陕西华县老官台全新世黄土和古土壤剖面的化学分析表明:Li和Ba两种化学元素含量受后期风化成壤作用的控制而发生分离,Li在风化剖面中残留而相对富集,表现为残留富集的特点;而Ba在整个剖面中的变化相当显著,随成壤强度的增强而大量淋失,导致其含量急剧减少,表现为极强的活动性。所以Li/Ba值能较好地反映风尘沉积物在后期经历的风化成壤强度。由于控制风尘沉积物成壤过程的主导因素是降水量的多少,而影响黄土高原及周边地区降水量的主导因素是东亚季风环流,因此Li/Ba值变化实际上反映了东亚季风系统的变化。Li/Ba值是再现古气候环境变化的良好替代指标,这在其与磁化率和Rb/Sr值良好的对应关系中得到有力的证实。     

浙江八面山萤石矿床稀土元素地球化学特征及成因探讨

对浙江八面山萤石矿床中不同类型萤石矿石和围岩样品的稀土元素的系统分析表明,细粒萤石矿石的ΣREE〈39×10-6,LREE为14.36×10-6～34.24×10-6,HREE0.96×10-6～2.04×10-6,Y〈3×10-6;巨晶萤石矿石中的ΣREE3.62×10-6～20.81×10-6,LREE2.71×10-6～17.67×10-6,HREE0.24×10-6～1.49×10-6;而围岩花岗岩的ΣREE460.29×10-6,LREE225.97×10-6,HREE91.32×10-6,Y＆gt;140×10-6;沉积岩中的ΣREE20.22×10-6、LREE16.11×10-6、HREE1.61×10-6。矿石与围岩中沉积岩的稀土总量、轻稀土、重稀土和Y的含量接近,与花岗岩的稀土总量、轻稀土、重稀土和Y元素含量相差悬殊。萤石矿石的稀土分布型式主要为轻稀土富集型,（La/Yb）N通常多数大于8,在8.07～17.26间,δEu值在0.45～1.30,δCe在0.89～1.14间,Ce、Eu基本不显异常。矿石与围岩的稀土地球化学研究显示,八面山萤石矿床为受地层、岩体与断裂共同控制＂三位一体＂的低温热液型矿床。     

Barium anomaly preceding K/T boundary: possible causes and implications on end Cretaceous events of K/T sections in Cauvery basin (India), Israel, NE-Mexico and Guatemala

Maastrichtian–Danian strata of the Cauvery basin as well as selected sections of NE-Mexico, Guatemala and Israel record Ba anomalies, away from the Cretaceous/Tertiary boundary (KTB) in addition to common occurrences of geochemical and stable isotopic anomalies across the KTB. Ba anomalies were recorded in monotonous shallow marine sandstones of the Cauvery basin (south India) which contain minor amounts of Ba-orthoclase. Barium anomalies were observed also in shallow marine carbonates in sections of Israel, NE-Mexico and Guatemala. Calculation of excess Ba with reference to PAAS (Post-Archaen Average Australian Shale), comparison of coeval geochemical anomalies, depositional pattern and associated petrographic and mineralogical features of the Cauvery basin revealed that while a first Ba peak was related to detrital influx, the second Ba peak was coincident with sea level fall which in turn may have been influenced by emission of volatile hydrocarbons and resultant climatic changes. In view of intrinsic involvement of Ba in various geochemical processes and occurrence of Ba anomalies in K/T sites distributed around the world (NE-Mexico, Guatemala and Israel), it is suggested that probable causes of such widespread Ba-anomalies should be taken into consideration while analyzing end Cretaceous events. These observations support the views espoused by many workers who have stated that the K/T boundary was also accompanied by many non-catastrophic events that might have contributed to environmental stress on marine fauna, as a result of which selective multi-stage extinctions occurred.     

南极阿德雷岛湖泊沉积物Sr/Ba与B/Ga比值特征

测试了南极企鹅聚集区阿德雷岛湖泊沉积物Sr、Ba、B、Ga的垂向含量变化,阿德雷岛湖泊沉积物元素平均含量为:Sr为1 069.36±422.10 mg/kg,Ba为213.84±39.48 mg/kg,B为6.89±3.79 mg/kg,Ga为16.65±3.91 mg/kg,阿德雷岛湖泊沉积物Sr/Ba比值为4.92±1.53,B/Ga比值为0.43±0.26,Sr/Ba比值远大于1.0,而B/Ga比值小于3.3,这表明在特殊的生态环境下Sr/Ba比值不能用来判别沉积物的沉积相,南极阿德雷岛湖泊沉积的Sr/Ba比值异常是通过企鹅生物地球化学过程沉积改造而引起的,受到企鹅粪沉积影响.     

南海北部珊瑚Ba/Ca比值的季节变化及其环境意义

利用等离子体普技术分析了取自海南岛南部沿岸的现代演珊瑚高分辨率的Ｂａ／Ｃａ。结果表明,该珊瑚的Ｂａ／Ｃａ比值具有明显的双峰态的季节变化,其中春季和秋季Ｂａ／Ｃａ比值较镐,而冬、夏两季则较低。海南岛南部及邻近地区季节降雨的变化所控制的原Ｂａ输入是这些珊瑚Ｂａ／Ｃａ比值变化的重要控制因素,而该区夏季相对较镐的表层海水生产力可能也对其有重要影响。     

锰掺杂对Ba(Zr,Ti)O3陶瓷压电与介电性能的影响

采用氧化物固相反应法制备了锰掺杂改性的Ba(Zr_0.06Ti_0.94)O₃陶瓷.研究了锰的掺杂量对Ba(Zr_0.06Ti_0.94)Mn_xO₃ (BZTM)陶瓷的结构、介电和压电性能的影响.实验发现,当锰含量x<0.5 mol%时进入晶格,使材料压电性能提高,损耗减小,表现出受主掺杂的特性;当锰含量x>0.5 mo     

渤海湾百年来沉积物Li/Ba 和Rb/Sr 协同变化的地球化学特征与环境指示作用

通过对渤海湾两根柱状沉积物中Li、Rb、Sr、Ba以及Li/Ba和Rb/Sr的系统研究,阐明了百年来沉积物中Li、Rb、Sr、Ba的垂直变化特征,发现了在不同年代沉积物中Li/Ba和Rb/Sr具有的协同变化规律,揭示了沉积物Li/Ba和Rb/Sr作为近海区域性环境演变可能的指示作用。结果表明,在0~20 cm沉积层间,Li、Rb在A2和A6柱中均有随深度增加而增加的趋势,Sr和Ba随着深度的增加而降低;近百年来,渤海湾沉积物A2和A6柱中Li/Ba和Rb/Sr垂直变化表现出惊人的协同变化特征,Li/Ba和Rb/Sr在近河口的A2柱中,基本呈现随深度的增加而增加的趋势,而在远离河口区域的A6柱中,其结果是0~15 cm段(1963~2008年),Li/Ba和Rb/Sr随深度的增加而增加,15 cm以下(1900~1963年)则基本稳定,在海洋过程作用下该区域沉积物Li/Ba和Rb/Sr变化发生在45 a时间段内;沉积物中Li/Ba反映沉积物从河流进入海湾沉积过程中的变化,Rb/Sr反映来源沉积物的化学风化历史并指示来源区的气候环境变迁过程。A2沉积柱的20~22 cm(20世纪30年代)和10~12 cm(20世纪60年代),Li/Ba出现极小值,与1939年和1963年的海河流域大洪水相契合,在0~12 cm段,两柱样Rb/Sr随着深度的降低有明显减小的趋势,对应20世纪70年代初至2008年这一区域百年来气温升高并持续高温的时段。     

The overabundance of s-process elements in Ba stars through wind accretion

The lack of self consistency in the current wind accretion models is pointed out. Taking account of δr ≠ 0, the modification equations of orbital parameters are re-deduced. Combined with wind accretion scenarios, calculations of nucleosynthesis for intrinsic AGB stars are first used to calculate s-process enrichments of Ba stars. Comparisons are also made between the predictions of calculations and the observations. It is found that predictions from the model for the standard case are an upper limit to the observations. Better agreements are obtained either by increasing the wind velocity or reducing the accretion rate.     

Evolution of Çamlık fissure-ridge travertines in the Başkale basin (Van,Eastern Anatolia)

Fissure-ridge travertines (FRTs) are of great importance for the determination and comparison of tectonic deformation in a region. The coeval development of these travertines with active fault zones supplies significant information about regional dynamics in terms of deformation pattern and evolution. In this paper, the characteristics of FRTs of the Ba?kale basin (eastern Turkey) and responsible regional tectonism are discussed for the first time. The Ba?kale basin is located between the Ba?kale Fault Zone (BFZ) characterised by Çaml?k fault and I??kl?–Zirani? fault. It is located between dextral Yüksekova Fault Zone and southern end of dextral Guilato–Siahcheshmeh–Khoy Fault system (Iran). Various morphological features indicating recent activity are exposed along the BFZ, including offsetting rivers, fissure-ridge travertine and fault scarps. The Çaml?k fissure-ridge travertine composing of three different depositions is observed along the eastern edge of the BFZ with approximately parallel orientations. The Çaml?k fissure-ridge travertine has been formed and developed on fault zone related to strike-slip or oblique movements. We explain how kinematic changes of faults can influence the fissure-ridge development.